MRAM etching processes
View Patent ↗Various embodiments of the invention relate to etching processes used in fabrication of MTJ cells in an MRAM device. The various embodiments can be used in combination with each other. The first embodiment adds a hard mask buffer layer between a hard mask and a top electrode. The second embodiment uses a multilayered etching hard mask. The third embodiment uses a multilayered top electrode structure including a first Cu layer under a second layer such as Ta. The fourth embodiment is a two-phase etching process used for the bottom electrode to remove re-deposited material while maintaining a more vertical sidewall etching profile. In the first phase the bottom electrode layer is removed using carbonaceous reactive ion etching until the endpoint. In the second phase an inert gas and/or oxygen plasma is used to remove the polymer that was deposited during the previous etching processes.
1. A method of fabricating a memory cell comprising:
depositing a stack of layers for a memory device including a memory element and a bottom electrode;
depositing a top electrode layer;
depositing a first hard mask layer over the top electrode layer;
depositing a second hard mask layer over the first hard mask layer, the second hard mask layer being a material having a low etching rate in a selected top electrode etching ambient;
patterning a photoresist pad on a selected location on the second hard mask layer leaving an exposed area;
performing a first etching process using a selected hard mask etching ambient to remove exposed areas of the first and second hard mask layers; and
performing a second etching process using the selected top electrode etching ambient to remove exposed areas of the top electrode layer.
2. The method of claim 1 wherein the selected hard mask etching ambient is a carbon fluoride system.
3. The method of claim 1 wherein the first hard mask layer is silicon oxide, silicon nitride, or titanium nitride.
4. The method of claim 1 wherein the second hard mask layer is a borazinic film, aluminum oxide, copper, or aluminum.
5. The method of claim 1 wherein the first top electrode layer is tantalum.
6. The method of claim 1 wherein depositing the top electrode layer further comprises:
depositing a first top electrode layer of copper on an upper layer of the memory element; and
depositing a second top electrode layer of a selected metal other than copper on the first top electrode layer.