IP Library Granted Patent US 9,006,093
Granted Patent B2
US 9,006,093 · App. 13/928,666 · Granted Apr 14, 2015

Non-volatile memory (NVM) and high voltage transistor integration

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Quick Facts
Patent No.
US 9,006,093
App. No.
13/928,666
Granted
Apr 14, 2015
Kind
B2
Abstract

A method of making a semiconductor structure includes forming a select gate stack on a substrate. The substrate includes a non-volatile memory (NVM) region and a high voltage region. The select gate stack is formed in the NVM region. A charge storage layer is formed over the NVM region and the high voltage region of the substrate. The charge storage layer includes charge storage material between a bottom layer of dielectric material and a top layer of dielectric material. The charge storage material in the high voltage region is oxidized while the charge storage material in the NVM region remains unoxidized.

Claims (43)

1. A method of making a semiconductor structure comprising:

forming a select gate stack on a substrate, the substrate including a non-volatile memory (NVM) region and a high voltage region, the select gate stack being formed in the NVM region;

forming a charge storage layer over the NVM region and the high voltage region of the substrate, the charge storage layer including charge storage material; and

oxidizing the charge storage material in the high voltage region while the charge storage material in the NVM region remains unoxidized.

2. The method of claim 1 further comprising:

depositing a protective layer over the NVM region before oxidizing the charge storage material.

3. The method of claim 1 further comprising:

depositing a layer of conductive gate material over the NVM region and the high voltage region; and

depositing a protective layer over the conductive gate material in the NVM region before oxidizing the charge storage material through the conductive gate material in the high voltage region.

4. The method of claim 1 wherein the charge storage material includes one of a group consisting of: discrete charge storage elements and a layer of conductive film.

5. The method of claim 1 , wherein the substrate further includes a logic region, the method further comprising:

depositing a material used for a portion of the select gate stack in the NVM region and the logic region;

forming a memory cell including the select gate stack in the NVM region;

forming a high voltage transistor in the high voltage region; and

forming a logic transistor in the logic region after forming the memory cell and the high voltage transistor and after removing the material used for the select gate stack in the logic region.

6. The method of claim 1 wherein the charge storage layer with the oxidized charge storage material is used as a gate dielectric for a high voltage transistor in the high voltage region.

7. The method of claim 1 where the oxidizing the charge storage material comprises:

implanting oxygen in the charge storage layer in the high voltage region; and

exposing the charge storage layer to heat.

8. The method of claim 5 wherein the memory cell is a split gate memory cell.

9. The method of claim 5 , wherein:

the memory cell is configured to operate at voltages between 0 and 18 Volts;

the high voltage transistor is configured to operate at voltages between 0 and 18 Volts; and

the logic transistor is configured to operate at voltage between 0 and 3 Volts.

10. The method of claim 3 further comprising:

forming a control gate for a memory cell from the layer of conductive gate material in the NVM region; and

forming a control gate for a high voltage device cell from the layer of conductive gate material in the high voltage region.

11. A method of making a semiconductor structure comprising:

growing a select gate dielectric over a major surface of a substrate;

depositing a select gate material over the select gate dielectric;

patterning a select gate stack in a non-volatile memory (NVM) region of the substrate while removing the select gate dielectric and the select gate material in a high voltage region of the substrate and retaining the select gate dielectric and the select gate material in a logic region of the substrate;

depositing a charge storage layer over the NVM region, the high voltage region, and the logic region;

forming a protective layer over the charge storage layer in the NVM region; and

oxidizing the charge storage layer in the high voltage region and the logic region while the protective layer prevents the charge storage layer from oxidizing in the NVM region.

12. The method of claim 11 further comprising:

depositing a control gate material over the charge storage layer before the forming the protective layer and the oxidizing the charge storage layer.

13. The method of claim 11 further comprising:

patterning the control gate material and the charge storage layer in the NVM region to form a control gate partially overlapping the select gate stack.

14. The method of claim 13 further comprising:

patterning the control gate material and the oxidized charge storage layer in the high voltage region to form a gate for a high voltage device.

15. The method of claim 14 further comprising:

removing the select gate dielectric and the select gate material in the logic region of the substrate; and

forming a gate stack in the logic region after the removing the select gate dielectric and the select gate material in the logic region.

Assignments (20)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
MERGER Recorded Jan 3, 2017
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
Reel/Frame 041144/0363 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
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SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
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PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
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PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
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PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
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SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
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SUPPLEMENT TO IP SECURITY AGREEMENT Recorded Sep 20, 2013
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To: CITIBANK, N.A., AS COLLATERAL AGENT
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SUPPLEMENT TO IP SECURITY AGREEMENT Recorded Sep 20, 2013
From: FREESCALE SEMICONDUCTOR, INC.
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SUPPLEMENT TO IP SECURITY AGREEMENT Recorded Sep 20, 2013
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From: HONG, CHEONG MIN; KANG, SUNG-TAEG; YATER, JANE A.
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