IP Library Granted Patent US 9,253,883
Granted Patent B2
US 9,253,883 · App. 14/082,600 · Granted Feb 2, 2016

Stretchable polymer thick film silver conductor for highly permeable substrates

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Quick Facts
Patent No.
US 9,253,883
App. No.
14/082,600
Granted
Feb 2, 2016
Kind
B2
Abstract

This invention is directed to a polymer thick film conductor composition. The polymer thick film (PTF) conductor composition may be used in applications where significant stretching is required, particularly on highly permeable substrates. A particular type of substrate which is suitable is a woven polyester coated with polyamide. An electrical circuit containing a conductor formed from the composition and a process to make such a circuit are provided.

Claims (25)

1. An electrical circuit on a wearable garment, the electrical circuit comprising:

(i) a conductor formed from a polymer thick film conductor composition comprising:

(a) 30 to 70 wt % silver flakes;

(b) 20 to 50 wt % first organic medium comprising 10 to 50 wt % thermoplastic urethane resin dissolved in a first organic solvent, wherein the weight percent (wt %) of the thermoplastic urethane resin is based on the total weight of the

(c) organic medium; and

(d) 5 to 20 wt % second organic medium comprising 10 to 50 wt % thermoplastic polyhydroxyether resin dissolved in a second organic solvent wherein the weight percent of the thermoplastic polyhydroxyether resin is based on the total weight of the organic medium;

wherein the ratio of the weight of the first organic medium to the weight of the second organic medium is in the range from 2.3 to 3.7, wherein the weight percent of the silver flakes, the first organic medium and the second organic medium are based on the total weight of the polymer thick film conductor composition; and

(ii) a polyamide-coated woven polyester substrate, wherein the polymer thick film conductor composition is deposited on the polyamide-coated woven polyester substrate and is then dried to form the conductor on the polyamide-coated woven polyester substrate.

2. The electrical circuit of claim 1 , wherein said thermoplastic urethane resin is a linear hydroxyl polyurethane.

3. The electrical circuit of claim 1 , wherein said thermoplastic urethane resin is a polyester-based copolymer.

4. The electrical circuit of claim 1 , wherein said permeable substrate is a woven polyester coated with polyamide.

5. The electrical circuit of claim 1 , wherein said ratio of the weight of the first organic medium to the weight of the second organic medium is about 3:1.

6. A process for making an electrical circuit on a wearable garment, the electrical circuit comprising a conductor formed from a thick film conductor composition, said process comprising the steps of:

(a) providing a polyamide-coated woven polyester substrate;

(b) providing a polymer thick film conductor composition comprising:

(i) 30 to 70 wt % silver flakes;

(ii) 20 to 50 wt % first organic medium comprising 10 to 50 wt % thermoplastic urethane resin dissolved in a first organic solvent, wherein the weight percent (wt %) of the thermoplastic urethane resin is based on the total weight of the organic medium; and

(iii) 5 to 20 wt % second organic medium comprising 10 to 50 wt % thermoplastic polyhydroxyether resin dissolved in a second organic solvent wherein the weight percent of the thermoplastic polyhydroxyether resin is based on the total weight of the organic medium;

wherein the ratio of the weight of the first organic medium to the weight of the second organic medium is in the range from 2.3 to 3.7 and wherein the weight percent of the silver flakes, the first organic medium and the second organic medium are based on the total weight of the polymer thick film conductor composition;

(c) depositing said polymer thick film conductor composition onto said polyamide-coated woven polyester; and

(d) drying the polymer thick film conductor composition that was deposited in step (c) to form the conductor on the polyamide-coated woven polyester substrate.

7. The process of claim 6 , wherein said thermoplastic urethane resin is a linear hydroxyl polyurethane.

8. The process of claim 6 , wherein said thermoplastic urethane resin is a polyester-based copolymer.

9. The process of claim 6 , wherein said permeable substrate is a woven polyester coated with polyamide.

10. The process of claim 6 , wherein said ratio of the weight of the first organic medium to the weight of the second organic medium is about 3:1.

Assignments (4)
CHANGE OF NAME Recorded Mar 20, 2025
From: DU PONT CHINA LIMITED
To: CELANESE MERCURY HOLDINGS INC.
Reel/Frame 070567/0231 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 20, 2022
From: DUPONT ELECTRONICS, INC.
To: DU PONT CHINA LIMITED
Reel/Frame 062201/0889 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 25, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT ELECTRONICS, INC.
Reel/Frame 049583/0269 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 18, 2013
From: CRITZER, MARK STEVEN; DORFMAN, JAY ROBERT
To: E. I. DU PONT DE NEMOURS AND COMPANY
Reel/Frame 031804/0349 →