Silazane-containing materials for light emitting diodes
LEDs comprising polysilazane/polysiloxane copolymers and curable compositions containing same are disclosed. Methods of providing thermal and UV degradation resistance to said LED's, as well as increased luminous flux, is provided.
1. A method comprising
contacting at least one LED element with a curable mixture of at least one silazane and at least one polysiloxane; and
curing the curable mixture to provide an optically transparent cured mixture, wherein the cured mixture is a copolymer of the at least one silazane and the at least one polysiloxanes having the formula I or II:
wherein R 1 , R 2 , R 3 , R 4 , and R 5 are the same or different and are each independently hydrogen or an optionally substituted alkyl, aryl, or (trialkoxysilyl)alkyl radical; a and b are mole amounts of repeating unit, and a≠0;
exposing the cured mixture to UV light from the at least one LED elements; and
preventing or eliminating discoloration of the cured mixture as measured by a change in percent transmission at 400 nm and/or 450 nm of less than 10 percent after 120 hours.
2. The method of claim 1 , wherein the cured mixture has an index of refraction of between 1.41 and 1.55.
3. The method of claim 1 , further comprising: exposing the at least one LED element to temperature of about 230° C. to about 280° C.; and reducing or eliminating cracking and discoloration of the cured mixture.
4. The method of claim 1 , further comprising: improving the luminous flux of the at least one LED element at least 1 percent compared to a substantially similar LED element coated with a polysilazane coating or a polysiloxane coating of substantially similar refractive index.
5. The method of claim 1 , wherein the at least one silazane of the curable mixture is polysilazane.
6. The method of claim 5 , wherein the polysilazane contains one or more of reactive groups selected from the group consisting of Si—H, amine, alkylamine, hydroxy, alkoxy, thiol, vinyl, acrylate, acrylamide, and halogen.
7. The method of claim 1 , wherein the at least one polysiloxane of the curable mixture contains one or more of reactive groups selected from the group consisting of Si—H, amine, alkylamine, hydroxy, alkoxy, thiol, vinyl, acrylate, acrylamide, and halogen.
8. The method of claim 1 , wherein the at least one polysiloxane of the curable mixture is hydroxy-terminated, alkoxyl-terminated, or alkylamine.
9. The method of claim 1 , wherein the optically transparent cured mixture is a chemical reaction product of the at least one polysiloxane and the at least one silazane.
10. The method of claim 1 , further comprising depositing one or more optically transparent layers on the optically transparent cured mixture, the one or more layers comprising, independently or in combination, a polymethylsiloxane layer, a polyphenylsiloxane layer, or a polyphenylmethylsiloxane layer.
11. The method of claim 1 , wherein the optically transparent cured mixture further comprises one or more of each of a phosphor, a spectral-notch filtering material, and a reflective/refractive material.
12. The method of claim 10 , wherein the one or more optically transparent layers further comprises one or more of each of a phosphor, a spectral-notch filtering material, and light diffusing particles.
13. The method of claim 1 , further comprising the step of forming the curable mixture or the cured mixture into an optical element.
14. The method of claim 1 , wherein the cured mixture encapsulates the at least one LED element.