Surface morphology of non-polar gallium nitride containing substrates
View Patent ↗Optical devices such as LEDs and lasers are discloses. The devices include a non-polar gallium nitride substrate member having an off-axis non-polar oriented crystalline surface plane. The off-axis non-polar oriented crystalline surface plane can be up to about −0.6 degrees in a c-plane direction and up to about −20 degrees in a c-plane direction in certain embodiments. In certain embodiments, a gallium nitride containing epitaxial layer is formed overlying the off-axis non-polar oriented crystalline surface plane. In certain embodiments, devices include a surface region overlying the gallium nitride epitaxial layer that is substantially free of hillocks.
1. A method of forming an optical device, said method comprising:
growing by MOCVD at least one gallium- and nitrogen-containing epitaxial layer over a crystalline surface plane of a gallium- and nitrogen-containing substrate, said at least one epitaxial layer comprising:
at least one light emitting layer configured to emit luminescence substantially free from a double-peak emission spectrum; and
a surface region being substantially free from hillocks,
wherein said crystalline surface plane is substantially oriented along the (30-3-1) direction.
2. The method of claim 1 , wherein growing said at least one epitaxial layer comprises growing said light-emitting layer at a temperature ranging from about 700 Degrees Celsius to about 1200 Degrees Celsius.
3. The method of claim 1 , wherein growing said at least one epitaxial layer comprises growing said light-emitting layer in a carrier gas selected from a group comprising H 2 , N 2 , and a mixture of H 2 and N 2 .
4. The method of claim 1 , wherein said growing said at least one epitaxial layer comprises growing said at least one epitaxial layer at an atmospheric pressure.
5. The method of claim 4 , wherein said atmospheric pressure is within a range from about 700 Torr to about 800 Torr.
6. The method of claim 1 , wherein said at least one light-emitting layer comprises at least one quantum well having a thickness of at least 3 nm.
7. The method of claim 1 , wherein said at least one light-emitting layer comprises at least one quantum well having a thickness of at least 5 nm.
8. The method of claim 1 , wherein at least 90% of said surface region is free from hillocks.
9. The method of claim 1 , wherein said optical device is one of a laser and a light emitting diode.
10. The method of claim 1 , wherein growing said at least one epitaxial layer comprises growing multiple gallium- and nitrogen-containing epitaxial layers comprising n-type regions, p-type regions, and at least one quantum well.