Pre-lithiation of electrode materials in a semi-solid electrode
Embodiments described herein relate generally to electrochemical cells having pre-lithiated semi-solid electrodes, and particularly to semi-solid electrodes that are pre-lithiated during the mixing of the semi-solid electrode slurry such that a solid-electrolyte interface (SEI) layer is formed in the semi-solid electrode before the electrochemical cell formation. In some embodiments, a semi-solid electrode includes about 20% to about 90% by volume of an active material, about 0% to about 25% by volume of a conductive material, about 10% to about 70% by volume of a liquid electrolyte, and lithium (as lithium metal, a lithium-containing material, and/or a lithium metal equivalent) in an amount sufficient to substantially pre-lithiate the active material. The lithium metal is configured to form a solid-electrolyte interface (SEI) layer on a surface of the active material before an initial charging cycle of an electrochemical cell that includes the semi-solid electrode.
1. A method of manufacturing a pre-lithiated semi-solid anode, the method comprising:
preparing a semi-solid anode mixture comprising 20% to 90% by volume of an anode active material, 0% to 25% by volume of a conductive material, a liquid electrolyte, and a lithium metal and/or lithium-containing material and/or lithium metal equivalent; and
storing the semi-solid anode mixture in a dry environment for a duration sufficient to pre-lithiate the semi-solid anode mixture prior to its incorporation into an electrochemical cell.
2. The method of claim 1 , wherein the storage duration is sufficient to form a solid-electrolyte interface (SEI) layer on a surface area of the active material.
3. The method of claim 1 , wherein the semi-solid anode mixture further comprises a high capacity material.
4. The method of claim 1 , wherein the anode active material includes at least one of graphite, hard carbon, cobalt oxide, iron oxide, tin, silicon, antimony, aluminum, titanium oxide, an alloy thereof, an oxide thereof, or combinations thereof.
5. A method of manufacturing an electrochemical cell, the method comprising:
assembling a cell stack, the assembling including:
preparing a semi-solid anode mixture comprising 20% to 90% by volume of an active material, 0% to 25% by volume of a conductive material, and a liquid electrolyte;
applying the semi-solid anode mixture onto a lithium-bearing substrate;
placing a separator membrane atop the semi-solid anode mixture; and
placing a cathode atop the separator membrane; and
storing the cell stack in a dry environment for a duration sufficient to pre-lithiate the semi-solid anode mixture prior to cycling.
6. The method of claim 5 , wherein the storage duration is sufficient to form a solid-electrolyte interface (SEI) layer on a surface area of the active material.
7. The method of claim 5 , wherein the semi-solid anode mixture further comprises a high capacity material.
8. The method of claim 5 , the assembling further including:
preparing a cathode mixture comprising:
a further active material;
a further conductive material;
a further electrolyte; and
lithium in an amount sufficient to increase the stability of the cathode, and forming the cathode from the cathode mixture.
9. The battery cell according to claim 8 , wherein the semi-solid electrode is an anode, the battery cell further comprising a semi-solid cathode having a thickness of greater than about 250 microns.