IP Library › Granted Patent US 10,118,863
Granted Patent B2
US 10,118,863 · App. 15/607,771 · Granted Nov 6, 2018

Proppant particles formed from slurry droplets and methods of use

Inventors: Benjamin T. Eldred (Houston, TX); Brett A. Wilson (Cypress, TX); Clayton F. Gardinier (Houston, TX); Robert Duenckel (Colorado Springs, CO)
Assignee: CARBO CERAMICS INC.
C04B38/0009C04B33/04C04B35/1115C04B35/62695C04B35/636C09K8/62C09K8/68C09K8/70C09K8/80C04B40/00C04B2235/3217C04B2235/349C04B2235/5436C04B2235/6023C04B2235/95C04B2235/963C09K2200/026Y10T428/2982
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Quick Facts
Patent No.
US 10,118,863
App. No.
15/607,771
Granted
Nov 6, 2018
Kind
B2
Abstract

Proppant particles formed from slurry droplets and methods of use are disclosed herein. The proppant particles can include a sintered ceramic material and can have a size of about 80 mesh to about 10 mesh and an average largest pore size of less than about 20 microns. The methods of use can include injecting a hydraulic fluid into a subterranean formation at a rate and pressure sufficient to open a fracture therein and injecting a fluid containing a proppant particle into the fracture, the proppant particle including a sintered ceramic material, a size of about 80 mesh to about 10 mesh, and an average largest pore size of less than about 20 microns.

Claims (28)

1. A proppant particle comprising a sintered ceramic material and having a size of about 80 mesh to about 10 mesh, an average largest pore size of less than about 20 microns, and a surface roughness of less than about 2 μm.

2. The proppant particle of claim 1 , wherein the sintered ceramic material comprises kaolin.

3. The proppant particle of claim 1 , wherein the sintered ceramic material comprises bauxite.

4. The proppant particle of claim 1 , wherein the sintered ceramic material comprises alumina.

5. The proppant particle of claim 1 , wherein when the proppant particle is subjected to impingement under a gas-entrained velocity of about 260 m/s onto a flat mild steel target, the target experiences an erosivity of about 1 mg/kg to about 100 mg/kg.

6. The proppant particle of claim 1 , wherein the surface roughness is from about 0.8 μm to about 1.6 μm.

7. The proppant particle of claim 1 , wherein the proppant particle has a long-term permeability greater than 130 darcies at a stress of 10,000 psi and a temperature of 250° F., as measured in accord with ISO 13503-5 when the proppant particle has a size of about 20-40 mesh and a specific gravity of about 2.7.

8. The proppant particle of claim 1 , wherein the proppant particle has a long-term permeability greater than 110 darcies at a stress of 14,000 psi and a temperature of 250° F., as measured in accord with ISO 13503-5 when the proppant particle has a size of about 20-40 mesh and a specific gravity of about 3.3.

9. The proppant particle of claim 1 , wherein the proppant particle has an appropriate strength, appropriate strength being defined as a decrease of less than 85% of long term fluid permeability, as measured in accord with ISO 13503-5 at 250° F., of a pack of test particles, the test particles having the same composition and method of making as the proppant particle, when a stress applied to the pack of test particles increases from 2,000 psi to 20,000 psi and the test particles are in the size range of 20-40 mesh and the test particles have a specific gravity above 3.5.

10. The proppant particle of claim 1 , wherein the proppant particle having a size of about 20-40 mesh with a specific gravity above 3.5 loses less than 15% of its long term liquid conductivity at 20,000 psi after being subjected to 5 cycles of cyclic loading under stresses from about 12,000 psi to about 20,000 psi.

11. The proppant particle of claim 1 , wherein the proppant particle in a size range of 20-40 mesh with a specific gravity above 3.5 has an increase in beta factor of less than 0.0005 at 20,000 psi after being subjected to 5 cycles of cyclic loading under stresses from about 12,000 psi to about 20,000 psi.

12. A method of hydraulic fracturing a subterranean formation, comprising: injecting a hydraulic fluid into a subterranean formation at a rate and pressure sufficient to open a fracture therein; and

injecting a fluid containing a proppant particle into the fracture, the proppant particle comprising a sintered ceramic material and having a size of about 80 mesh to about 10 mesh, an average largest pore size of less than about 20 microns, and a surface roughness of less than about 2 μm.

13. The method of claim 12 , wherein the sintered ceramic material comprises kaolin.

14. The method of claim 12 , wherein the sintered ceramic material comprises bauxite.

15. The method of claim 12 , wherein the sintered ceramic material comprises alumina.

16. The method of claim 12 , wherein the surface roughness is from about 0.8 μm to about 1.6 μm.

17. A proppant particle, comprising:

a ceramic material selected from sintered kaolin;

wherein the proppant particle has a size of about 40 mesh to about 20 mesh and a surface roughness of from about 0.8 μm to less than about 2 μm.

18. The proppant particle of claim 17 , wherein the surface roughness is from about 0.8 μm to about 1.6 μm.

19. The proppant particle of claim 17 , further comprising a porosity.

20. The proppant particle of claim 19 , further comprising a standard deviation in pore size of less than 4 μm.

21. A proppant particle comprising a sintered ceramic material and having a spherical shape, a size of about 80 mesh to about 10 mesh, an average largest pore size of less than about 20 microns, and a surface roughness of less than about 2 μm.

22. The proppant particle of claim 21 , wherein the spherical shape is an oblate spheroid.

23. A method of hydraulic fracturing a subterranean formation, comprising:

injecting a hydraulic fluid into a subterranean formation at a rate and pressure sufficient to open a fracture therein; and

injecting a fluid containing the proppant particle of claim 22 into the fracture.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 11, 2017
From: ELDRED, BENJAMIN T.; WILSON, BRETT A.; GARDINIER, CLAYTON F.; DUENCKEL, ROBERT
To: CARBO CERAMICS, INC.
Reel/Frame 042963/0781 →
Continuity (5)
Continuation 14502483 · Sep 30, 2014
Continuation In Part 13608530 · Sep 10, 2012
Continuation In Part 13357141 · Jan 24, 2012
Continuation In Part 13045980 · Mar 11, 2011
Related Publication 20170260104A1 · Sep 14, 2017
Cited By (1)
US 12,473,237