IP Library Granted Patent US 10,424,726
Granted Patent B2
US 10,424,726 · App. 15/857,318 · Granted Sep 24, 2019

Process for improving photoresist pillar adhesion during MRAM fabrication

Inventors: Elizabeth Dobisz (Fremont, CA); Pradeep Manandhar (Fremont, CA)
Assignee: Spin Memory, Inc.
H01L43/12G03F7/0035G03F7/0751H01L21/0274H01L27/222
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Quick Facts
Patent No.
US 10,424,726
App. No.
15/857,318
Granted
Sep 24, 2019
Kind
B2
Abstract

A method for improving photo resist adhesion to an underlying hard mask layer. The method includes a cleaning step that includes applying tetramethylammonium hydroxide (TMAH) to coat a hard mask layer of a wafer. The method further includes puddle developing the wafer for a first desired amount of time, and rinsing the wafer in running water for a second desired amount of time. The method further includes spin drying the wafer, and baking the wafer for a third desired amount of time. The method concludes with the proceeding of subsequent photolithographic processes on the wafer.

Claims (38)

1. A method for improving photo resist adhesion to an underlying hard layer, comprising:

cleaning the surface of the hard layer by applying tetramethylammonium hydroxide (TMAH) to coat a hard mask layer of the wafer;

puddle developing the wafer for a first desired amount of time;

rinsing the wafer for a second desired amount of time;

spin drying the wafer;

baking the wafer for a third desired amount of time; and

proceeding with subsequent photolithographic processes on the wafer, which fabricates pillars therein.

2. The method of claim 1 , wherein the first desired amount of time is approximately 2 minutes.

3. The method of claim 1 , wherein the second desired amount of time is approximately 1 minute.

4. The method of claim 1 , wherein the third desired amount of time is approximately 5 minutes.

5. The method of claim 1 , wherein the rinsing uses running water and the water is deionized water.

6. The method of claim 1 , further comprising cooling on a chilled plate for approximately one minute subsequent to the baking.

7. The method of claim 1 , further comprising treating the wafer with hexamethyldisilazane (HMDS) subsequent to the baking.

8. The method of claim 1 , wherein the underlying hard mask layer is tantalum nitride (TaN).

9. A method for improving photo resist pillar adhesion to a wafer, the method comprising:

cleaning a surface of tantalum nitride hard layer by applying tetramethylammonium hydroxide (TMAH) to coat the tantalum nitride hard layer of the wafer;

puddle developing the wafer for a first desired amount of time;

rinsing the wafer in running water for a second desired amount of time;

spin drying the wafer;

baking the wafer for a third desired amount of time; and

proceeding with subsequent photolithographic processes on the wafer.

10. The method of claim 9 , wherein the first desired amount of time is approximately 2 minutes.

11. The method of claim 9 , wherein the second desired amount of time is approximately 1 minute.

12. The method of claim 9 , wherein the third desired amount of time is approximately 5 minutes.

13. The method of claim 9 , wherein the water is deionized water.

14. The method of claim 9 , further comprising treating the wafer with hexamethyldisilazane (HMDS) subsequent to the baking.

15. The method of claim 9 , wherein the wafer is treated with hexamethyldisilazane (HMDS) subsequent to the baking.

16. A method for manufacturing an MRAM device, the method comprising:

applying tetramethylammonium hydroxide (TMAH) to coat a tantalum nitride hard layer of a wafer;

submerging the wafer in a dish of TMAH for a first desired amount of time;

rinsing the wafer in running water for a second desired amount of time;

spin drying the wafer;

baking the wafer for a third desired amount of time; and

proceeding with subsequent photolithographic processes on the wafer.

17. The method of claim 16 wherein the applying is a cleaning process and wherein the first desired amount of time is approximately 2 minutes.

18. The method of claim 17 , wherein the second desired amount of time is approximately 1 minute.

19. The method of claim 18 , wherein the third desired amount of time is approximately 5 minutes.

20. The method of claim 16 , wherein the water is deionized water.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 11, 2021
From: SPIN (ASSIGNMENT FOR BENEFIT OF CREDITORS), LLC
To: INTEGRATED SILICON SOLUTION, (CAYMAN) INC.
Reel/Frame 057473/0319 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 20, 2021
From: SPIN MEMORY, INC.
To: SPIN (ASSIGNMENT FOR THE BENEFIT OF CREDITORS), LLC
Reel/Frame 056927/0038 →
CHANGE OF NAME Recorded Jun 10, 2019
From: SPIN TRANSFER TECHNOLOGIES, INC.
To: SPIN MEMORY, INC.
Reel/Frame 049421/0501 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 28, 2017
From: DOBISZ, ELIZABETH; MANANDHAR, PRADEEP
To: SPIN TRANSFER TECHNOLOGIES, INC.
Reel/Frame 044995/0720 →
Continuity (1)
Related Publication 20190207100A1 · Jul 4, 2019