Systems and methods for improved metal recovery using ammonia leaching
Systems and methods for basic leaching are provided. In various embodiments, a method is provided comprising leaching a slurry comprising a copper bearing material and an ammonia leach medium, adding copper powder to the slurry, separating the slurry into a pregnant leach solution and solids, and performing a solvent extraction on the pregnant leach solution to produce an loaded aqueous stream.
1. A method comprising:
leaching a slurry comprising a metal bearing material and an ammonia leach medium, wherein the metal bearing material comprises copper and cobalt;
adding a reducing agent to the slurry, wherein the reducing agent comprises a dendritic copper powder, and wherein the reducing agent is added to the slurry such that a stoichiometric ratio of copper to cobalt is greater than 0.5; and
separating the slurry into a pregnant leach solution and solids; and performing a solvent extraction on the pregnant leach solution to produce a loaded aqueous stream.
2. The method of claim 1 , wherein the stoichiometric ratio of copper to cobalt is between about 4 and about 12.
3. The method of claim 2 , wherein the stoichiometric ratio of copper to cobalt is about 8.
4. The method of claim 1 , further comprising: producing a cobalt precipitate from a raffinate produced by the solvent extraction; and subjecting the cobalt precipitate to a metal recovery process.
5. The method of claim 4 , further comprising adding ammonium hydrosulfide to the raffinate produced by the solvent extraction.
6. The method of claim 1 , subjecting the loaded aqueous stream to electrowinning.
7. The method of claim 1 , further comprising wet grinding the metal bearing material prior to the leaching.
8. The method of claim 1 , further comprising adding sulfur dioxide gas to the slurry.
9. The method of claim 8 , further comprising adding air to the slurry.
10. The method of claim 1 , wherein the solvent extraction comprises subjecting the pregnant leach solution to a copper specific extracting reagent.
11. The method of claim 1 , wherein the solvent extraction comprises scrubbing an organic phase with a weak acid.
12. The method of claim 11 , wherein the weak acid is carbonic acid.
13. The method of claim 12 , wherein the carbonic acid is added through dissolving carbon dioxide in water.
14. The method of claim 1 , wherein the leaching is performed in an anoxic environment.