Group III nitride LED structures with improved electrical performance
Group III nitride light emitting diode (LED) structures with improved electrical performance are disclosed. A Group III nitride LED structure includes one or more n-type layers, one or more p-type layers, and an active region that includes a plurality of sequentially arranged barrier-well units. In certain embodiments, doping profiles of barrier layers of the barrier-well units are configured such that a doping concentration in some barrier-well units is different than a doping concentration in other barrier-well units. In certain embodiments, a doping profile of a particular barrier layer is non-uniform. In addition to active region configurations, the doping profiles and sequence of the n-type layers and p-type layers are configured to provide Group III nitride structures with higher efficiency, lower forward voltages, and improved forward voltage performance at elevated currents and temperatures.
1. A light emitting diode (LED), comprising:
an n-type GaN layer;
a superlattice structure;
a spacer layer arranged between the superlattice structure and the n-type GaN layer, the spacer layer comprising a first sublayer that is in direct contact with the superlattice structure and a second sublayer that is in direct contact with the n-type GaN layer, and the first sublayer has a higher n-type doping concentration than the second sublayer to provide a single step doping profile for the entire spacer layer; and
an active region on the superlattice structure such that the superlattice structure is arranged between the active region and the spacer layer, the active region comprising a plurality of sequentially arranged barrier-well units, wherein each barrier-well unit comprises an Al a In b Ga 1-a-b N barrier layer and an In c Ga 1-c N well layer;
wherein the plurality of sequentially arranged barrier-well units comprises a first barrier-well unit and a plurality of second barrier-well units; and
wherein an Al a In b Ga 1-a-b N barrier layer of the first barrier-well unit comprises a higher n-type doping concentration than an n-type doping concentration of each Al a In b Ga 1-a-b N barrier layer of the plurality of second barrier-well units.
2. The LED of claim 1 , wherein in the Al a In b Ga 1-a-b N barrier layer, 0≤a≤0.50 and 0≤b≤0.10, and in the In c Ga 1-c N well layer, c>0.05 and c>2·b.
3. The LED of claim 1 , wherein the first barrier-well unit is arranged between the n-type GaN layer and the plurality of second barrier-well units.
4. The LED of claim 1 , wherein the first sublayer is arranged between the second sublayer and the n-type GaN layer.
5. The LED of claim 1 , wherein the superlattice structure is arranged between the spacer layer and the first barrier-well unit.
6. The LED of claim 1 , wherein the Al a In b Ga 1-a-b N barrier layer of the first barrier-well unit comprises an n-type doping concentration that is at least two times higher than an n-type doping concentration of each Al a In b Ga 1-a-b N barrier layer of the plurality of second barrier-well units.
7. The LED of claim 1 , wherein the Al a In b Ga 1-a-b N barrier layer of the first barrier-well unit comprises an n-type doping concentration that is at least five times higher than an n-type doping concentration of each Al a In b Ga 1-a-b N barrier layer of the plurality of second barrier-well units.
8. The LED of claim 1 , wherein the Al a In b Ga 1-a-b N barrier layer of the first barrier-well unit comprises an n-type doping concentration within a range of from (i) at least two times higher than an n-type doping concentration of each Al a In b Ga 1-a-b N barrier layer of the plurality of second barrier-well units to (ii) no more than ten times higher than an n-type doping concentration of each Al a In b Ga 1-a-b N barrier layer of the plurality of second barrier-well units.
9. The LED of claim 1 , further comprising:
an Al g In h Ga 1-g-h N cap layer, wherein 0<g<1, 0≤h<1, and g+h<1;
a p-type In j Ga 1-j N layer, wherein 0≤j<1; and
a p-type Al k In m Ga 1-k-m N layer, wherein 0<k<1, 0≤m<1, and k+m<1;
wherein the Al g In h Ga 1-g-h N cap layer is arranged between the active region and the p-type In j Ga 1-j N layer; and
wherein the p-type In j Ga 1-j N layer is arranged between the Al g In h Ga 1-g-h N cap layer and the p-type Al k In m Ga 1-k-m N layer.
10. The LED of claim 9 , further comprising a p-type GaN layer, wherein the p-type Al k In m Ga 1-k-m N layer is arranged between the p-type In j Ga 1-j N layer and the p-type GaN layer.
11. The LED of claim 10 , wherein the p-type GaN layer comprises:
a first p-type GaN sublayer with a first p-type doping concentration;
a second p-type GaN sublayer with a second p-type doping concentration;
a third p-type GaN sublayer with a third p-type doping concentration; and
a fourth p-type GaN sublayer with a fourth p-type doping concentration;
wherein the fourth p-type doping concentration is about equal to the second p-type doping concentration;
wherein the first p-type doping concentration is in a range of from about 1% to about 20% of the fourth p-type doping concentration; and
wherein the third p-type doping concentration is in a range of from about 25% to about 75% of the fourth p-type doping concentration.
12. The LED of claim 10 , wherein the p-type GaN layer comprises:
a first p-type GaN sublayer with a first p-type doping concentration;
a second p-type GaN sublayer with a second p-type doping concentration; and
a third p-type GaN sublayer with a third p-type doping concentration;
wherein the first p-type doping concentration and the second p-type doping concentration are in a range of from about 5% to about 35% of the third p-type doping concentration.
13. The LED of claim 12 , wherein in the p-type In j Ga 1-j N layer, j>0.
14. The LED of claim 1 , wherein at least one barrier-well unit, but fewer than all barrier-well units, of the plurality of sequentially arranged barrier-well units additionally comprises an Al e In f Ga 1-e-f N interface layer, wherein e>0, and wherein e≥f.
15. The LED of claim 1 , wherein at least one Al a In b Ga 1-a-b N barrier layer of the plurality of sequentially arranged barrier-well units comprises a lower boundary, an upper boundary, and an n-type doping concentration that is non-uniform between the upper boundary and the lower boundary, with a maximum n-type doping concentration located between the upper boundary and the lower boundary.
16. The LED of claim 15 , wherein:
the at least one Al a In b Ga 1-a-b N barrier layer of the plurality of sequentially arranged barrier-well units comprises a thickness extending between the lower boundary and the upper boundary;
the thickness is divisible into a lower third proximate to the lower boundary, an upper third proximate to the upper boundary, and a middle third arranged between the lower third and the upper third; and
the maximum n-type doping concentration is located within the middle third.