IP Library Granted Patent US 12,420,472
Granted Patent B2
US 12,420,472 · App. 16/362,450 · Granted Sep 23, 2025

Additive manufacture of hierarchically porous materials with high resolution

Inventors: Siwei Liang (Dublin, CA); Theodore F. Baumann (Discovery Bay, CA); Eric B. Duoss (Dublin, CA); Christopher M. Spadaccini (Oakland, CA); Marcus A. Worsley (Hayward, CA); Cheng Zhu (Livermore, CA)
Assignee: Lawrence Livermore National Security, LLC
B29C64/106B29C64/209B33Y70/00B33Y70/10C08K3/22C08L53/00C08L61/02B33Y10/00B33Y80/00
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Quick Facts
Patent No.
US 12,420,472
App. No.
16/362,450
Granted
Sep 23, 2025
Kind
B2
Abstract

In one embodiment, an ink includes a polymer precursor, a copolymer, a catalyst, and a solvent. In another embodiment, a product includes a three-dimensional printed structure having ligaments, where an average diameter of the ligaments is in a range of about 10 microns to about 500 microns.

Claims (26)

1. An ink, comprising:

a polymer precursor, wherein the polymer precursor is a formaldehyde resin;

a copolymer, wherein a ratio by weight of the polymer precursor to the copolymer is in a range from about 1:1 to about 1:11;

a catalyst; and

a solvent,

wherein the ink is physically characterized as being extrudable into self-supporting ligaments.

2. The ink as recited in claim 1 , further comprising a precursor of a ceramic component.

3. The ink as recited in claim 2 , comprising an additional component, wherein the additional component is selected from the group consisting of: silicon oxide, titanium oxide, and nickel oxide.

4. The ink as recited in claim 2 , wherein the precursor of the ceramic component is tetraethoxyl silane (TEOS).

5. The ink as recited in claim 1 , wherein the formaldehyde resin is selected from the group consisting of: phenol formaldehyde resin, urea formaldehyde resin, resorcinol formaldehyde, and melamine formaldehyde resin.

6. The ink as recited in claim 1 , wherein the copolymer is at least one copolymer selected from the group consisting of: a triblock copolymer and a non-block copolymer.

7. The ink as recited in claim 1 , wherein the catalyst is an acid catalyst.

8. The ink as recited in claim 1 , wherein the catalyst is a base catalyst.

9. The ink as recited in claim 1 , wherein a concentration of the catalyst is in a range of about 1 weight % to about 2 weight % of a total weight of the ink.

10. The ink as recited in claim 1 , wherein the polymer precursor is different than the copolymer.

11. The ink as recited in claim 1 , wherein the ink is physically characterized as being formable into a gel when the ink is immersed in a second solvent.

12. The ink as recited in claim 1 , wherein the ink is substantially free of particles.

13. The ink as recited in claim 1 , wherein the ink is physically characterized as being formable into a gel having a bicontinuous structure including a continuous water-rich phase and a resol-rich phase upon the ink being immersed in a second solvent.

14. The ink as recited in claim 2 , wherein a ratio of the ceramic component to the polymer precursor is about 1:1.

15. The ink as recited in claim 1 , wherein the solvent includes water.

16. The ink as recited in claim 15 , wherein the solvent includes an organic co-solvent.

17. The ink as recited in claim 16 , wherein the organic co-solvent is selected from the group consisting of: ethanol, methanol, and isopropanol.

18. A method for forming a three dimensional structure using the ink as recited in claim 1 , the method comprising:

printing a three-dimensional structure using the ink;

immersing the printed three-dimensional structure in a second solvent for forming a gel; and

drying the printed three-dimensional structure.

Assignments (2)
CONFIRMATORY LICENSE Recorded Apr 6, 2020
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 052324/0894 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2020
From: LIANG, SIWEI; BAUMANN, THEODORE F.; DUOSS, ERIC B.; SPADACCINI, CHRISTOPHER M.; WORSLEY, MARCUS A.; ZHU, CHENG
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 052011/0661 →
Continuity (1)
Related Publication 20200298466A1 · Sep 24, 2020
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