IP Library Granted Patent US 12,521,935
Granted Patent B2
US 12,521,935 · App. 16/674,246 · Granted Jan 13, 2026

Method for minimizing stress-related deformations in 3D printed and sintered parts

Inventors: Gregory Thomas Mark (Brookline, MA); Rick Bryan Woodruff (Somerville, MA)
Assignee: MARKFORGED, INC
B29C64/118B22F1/10B22F1/142B22F3/1025B22F10/18B33Y10/00B33Y70/00B22F10/12B22F10/14B22F10/385B22F10/80B22F12/10B22F12/20B22F12/53
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,521,935
App. No.
16/674,246
Granted
Jan 13, 2026
Kind
B2
Abstract

A method for printing three-dimensional parts includes building a three-dimensional part by printing counter-wound slices. By winding adjacent slices in alternating directions, offsetting stored torques can be produced for each printed slice. The stored torques then neutralize one another during the debinding and sintering process, reducing part twists and deformations.

Claims (13)

1 . A method for building a green part with a deposition-based additive manufacturing system, the method comprising the steps of:

depositing a first layer of the green part in a first winding direction along at least one first toolpath, the first layer including a polymer and a powdered sinterable metal, each first toolpath in the first layer being deposited in the first winding direction and producing a tendency to twist about a vertical axis; and

depositing a second layer of the green part in a second winding direction opposite to the first winding direction and along at least one second toolpath, the second layer including the polymer and the powdered sinterable metal, each second toolpath in the second layer being deposited in the second winding direction,

wherein depositing the second layer of the green part includes depositing the second layer of the green part in the second winding direction such that, when the polymer is removed from the first layer and the second layer permitting the first and second layers to relax, a directional stress in the second layer offsets a directional stress in the first layer offsetting the tendency to twist about the vertical axis.

2 . The method of claim 1 , further comprising debinding the polymer of the green part to form a shape-retaining brown part and sintering the shape-retaining brown part to densify the shape-retaining brown part.

3 . The method of claim 2 , further comprising neutralizing, during the sintering of the shape-retaining brown part, the directional stress in the first layer with the directional stress in the second layer as the shape-retaining brown part relaxes.

4 . The method of claim 3 , comprising depositing a ceramic powder release material onto the build plate before depositing the first layer of the green part.

5 . The method of claim 1 , comprising depositing a third layer of the green part in the first winding direction in a pattern that follows at least one third toolpath in the third layer of the part, the third layer being adjacent to the second layer.

6 . The method of claim 5 , wherein depositing the third layer in the pattern that follows the at least one third toolpath produces a directional stress in the third layer, producing a tendency to twist about the vertical axis and offsetting the directional stress in the second layer.

7 . The method of claim 1 , comprising depositing a fourth layer in the second winding direction in a pattern that follows at least one fourth toolpath in the fourth layer of the part, the fourth layer being adjacent to the third layer.

8 . The method of claim 7 , wherein depositing the fourth layer in the pattern that follows the at least one fourth toolpath produces a directional stress in the fourth layer, producing a tendency to twist about the vertical axis offsetting the directional stress in the third layer.

9 . The method of claim 1 , wherein depositing the first layer of the green part along the at least one first toolpath forms an outer perimeter of the first layer.

10 . The method of claim 9 , wherein depositing the second layer of the green part along the at least one second toolpath forms an outer perimeter of the second layer.

Assignments (2)
SECURITY INTEREST Recorded Dec 4, 2024
From: MARKFORGED, INC.
To: CONTINUOUS COMPOSITES INC.
Reel/Frame 069508/0868 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 27, 2020
From: MARK, GREGORY THOMAS; WOODRUFF, RICK BRYAN
To: MARKFORGED, INC.
Reel/Frame 054180/0486 →
Continuity (16)
Continuation In Part 15976009 · May 10, 2018
Continuation 15831995 · Dec 5, 2017
Continuation 15829486 · Dec 1, 2017
Continuation 15829472 · Dec 1, 2017
Continuation 15829500 · Dec 1, 2017
Provisional Application 62863176 · Jun 18, 2019
Provisional Application 62575219 · Oct 20, 2017
Provisional Application 62545966 · Aug 15, 2017
Provisional Application 62519138 · Jun 13, 2017
Provisional Application 62505081 · May 11, 2017
Provisional Application 62489410 · Apr 24, 2017
Provisional Application 62480331 · Mar 31, 2017
Provisional Application 62442395 · Jan 4, 2017
Provisional Application 62430902 · Dec 6, 2016
Provisional Application 62429711 · Dec 2, 2016
Related Publication 20200114422A1 · Apr 16, 2020
References Cited (390)
US 2844489A · Gemmer · 1958 [cited by applicant]
US 3186957A · Stiles · 1965 [cited by applicant]
US 3837825A · Loxley et al. · 1974 [cited by applicant]
US 4225344A · Fujimori et al. · 1980 [cited by applicant]
US 4550412A · Holcombe et al. · 1985 [cited by applicant]
US 4569862A · Arai et al. · 1986 [cited by applicant]
US 4914255A · Avidan et al. · 1990 [cited by applicant]
US 4963709A · Kimrey, Jr. · 1990 [cited by applicant]
US 5011638A · Pinkhasov · 1991 [cited by applicant]
US 5073526A · Enloe et al. · 1991 [cited by applicant]
US 5160765A · Rotman et al. · 1992 [cited by applicant]
US 5182056A · Spence et al. · 1993 [cited by applicant]
US 5182170A · Marcus et al. · 1993 [cited by applicant]
US 5198159A · Nakamura et al. · 1993 [cited by applicant]
US 5198489A · Sterzel et al. · 1993 [cited by applicant]
US 5204055A · Sachs et al. · 1993 [cited by applicant]
US 5216616A · Masters · 1993 [cited by applicant]
US 5242098A · Hardwick · 1993 [cited by applicant]
US 5257657A · Gore · 1993 [cited by applicant]
US 5286573A · Prinz et al. · 1994 [cited by applicant]
US 5288443A · Lee · 1994 [cited by applicant]
US 5337961A · Brambani et al. · 1994 [cited by applicant]
US 5366679A · Streicher · 1994 [cited by applicant]
US 5387380A · Cima et al. · 1995 [cited by applicant]
US 5496682A · Quadir et al. · 1996 [cited by applicant]
US 5503785A · Crump et al. · 1996 [cited by applicant]
US 5531958A · Krueger · 1996 [cited by applicant]
US 5555481A · Rock et al. · 1996 [cited by applicant]
US 5598200A · Gore · 1997 [cited by applicant]
US 5617911A · Sterett et al. · 1997 [cited by applicant]
US 5669433A · Sterett et al. · 1997 [cited by applicant]
US 5697043A · Baskaran et al. · 1997 [cited by applicant]
US 5738817A · Danforth · 1998 [cited by examiner]
US 5745834A · Bampton et al. · 1998 [cited by applicant]
US 5774779A · Tuchinskiy · 1998 [cited by applicant]
US 5796207A · Safari et al. · 1998 [cited by applicant]
US 5798469A · Nufer · 1998 [cited by applicant]
US 5818149A · Safari et al. · 1998 [cited by applicant]
US 5848350A · Bulger · 1998 [cited by applicant]
US 5900207A · Danforth et al. · 1999 [cited by applicant]
US 5906863A · Lombardi et al. · 1999 [cited by applicant]
US 5997795A · Danforth et al. · 1999 [cited by applicant]
US 6004500A · Safari et al. · 1999 [cited by applicant]
US 6008281A · Yang et al. · 1999 [cited by applicant]
US 6049160A · Safari et al. · 2000 [cited by applicant]
US 6082297A · Pollock et al. · 2000 [cited by applicant]
US 6193922B1 · Ederer · 2001 [cited by applicant]
US 6202734B1 · Sackinger et al. · 2001 [cited by applicant]
US 6344426B1 · Hata et al. · 2002 [cited by applicant]
US 6352669B1 · Cooper et al. · 2002 [cited by applicant]
US 6375874B1 · Russell et al. · 2002 [cited by applicant]
US 6397922B1 · Sachs et al. · 2002 [cited by applicant]
US 6447712B1 · Dogan et al. · 2002 [cited by applicant]
US 6558606B1 · Kulkarni et al. · 2003 [cited by applicant]
US 6589471B1 · Khoshnevis · 2003 [cited by applicant]
US 6682684B1 · Jamalabad et al. · 2004 [cited by applicant]
US 6803003B2 · Rigali et al. · 2004 [cited by applicant]
US 6830643B1 · Hayes · 2004 [cited by applicant]
US 6884486B2 · Estrin et al. · 2005 [cited by applicant]
US 7108827B1 · Hata et al. · 2006 [cited by applicant]
US 7144548B2 · Billiet et al. · 2006 [cited by applicant]
US 7364686B2 · Kritchman et al. · 2008 [cited by applicant]
US 7378052B2 · Harryson · 2008 [cited by applicant]
US 7628857B2 · Kritchman et al. · 2009 [cited by applicant]
US 7942987B2 · Crump et al. · 2011 [cited by applicant]
US 8047251B2 · Khoshnevis · 2011 [cited by applicant]
US 8158255B2 · Yokoyama et al. · 2012 [cited by applicant]
US 8245757B2 · Crump et al. · 2012 [cited by applicant]
US 8523331B2 · Houben · 2013 [cited by applicant]
US 8586493B2 · Kaga et al. · 2013 [cited by applicant]
US 8721032B2 · Kuznetsov et al. · 2014 [cited by applicant]
US 8871355B1 · Mears et al. · 2014 [cited by applicant]
US 9027378B2 · Crump et al. · 2015 [cited by applicant]
US 9126365B1 · Mark et al. · 2015 [cited by applicant]
US 9126367B1 · Mark et al. · 2015 [cited by applicant]
US 9149988B2 · Mark et al. · 2015 [cited by applicant]
US 9327448B2 · Shah et al. · 2016 [cited by applicant]
US 9370896B2 · Mark · 2016 [cited by applicant]
US 9399323B1 · Lu et al. · 2016 [cited by applicant]
US 9403725B2 · Khoshnevis · 2016 [cited by applicant]
US 9545669B2 · Åklint et al. · 2017 [cited by applicant]
US 9643281B1 · Memmen et al. · 2017 [cited by applicant]
US 9744722B2 · Rodgers · 2017 [cited by examiner]
US 9815118B1 · Schmitt et al. · 2017 [cited by applicant]
US 9833839B2 · Gibson et al. · 2017 [cited by applicant]
US 10183442B1 · Miller · 2019 [cited by applicant]
US 11173550B2 · Mark · 2021 [cited by applicant]
US 20010050448A1 · Kubo et al. · 2001 [cited by applicant]
US 20020015654A1 · Das et al. · 2002 [cited by applicant]
US 20020108949A1 · Gedevanishvili et al. · 2002 [cited by applicant]
US 20020165304A1 · Mulligan et al. · 2002 [cited by applicant]
US 20020171177A1 · Kritchman et al. · 2002 [cited by applicant]
US 20030180636A1 · Kanga et al. · 2003 [cited by applicant]
US 20030185698A1 · Wang et al. · 2003 [cited by applicant]
US 20030205573A1 · Okumura et al. · 2003 [cited by applicant]
US 20040182202A1 · Geving et al. · 2004 [cited by applicant]
US 20040183055A1 · Chartier et al. · 2004 [cited by applicant]
US 20040187714A1 · Napadensky et al. · 2004 [cited by applicant]
US 20040207124A1 · Kritchman et al. · 2004 [cited by applicant]
US 20040239009A1 · Collins et al. · 2004 [cited by applicant]
US 20050058837A1 · Farnworth et al. · 2005 [cited by applicant]
US 20050123433A1 · Li et al. · 2005 [cited by applicant]
US 20050242473A1 · Newell et al. · 2005 [cited by applicant]
US 20050249627A1 · Wang et al. · 2005 [cited by applicant]
US 20060251536A1 · Kelly · 2006 [cited by applicant]
US 20070003426A1 · Lu et al. · 2007 [cited by applicant]
US 20080039312A1 · Natsuhara et al. · 2008 [cited by applicant]
US 20080179433A1 · Pfeffer et al. · 2008 [cited by applicant]
US 20080206561A1 · Yokoyama et al. · 2008 [cited by applicant]
US 20080211124A1 · Zagagi et al. · 2008 [cited by applicant]
US 20080248277A1 · Yokoyama et al. · 2008 [cited by applicant]
US 20080277841A1 · Natsuhara et al. · 2008 [cited by applicant]
US 20090039570A1 · Clark · 2009 [cited by applicant]
US 20090148813A1 · Sun et al. · 2009 [cited by applicant]
US 20090314391A1 · Crump et al. · 2009 [cited by applicant]
US 20100028645A1 · Maguire et al. · 2010 [cited by applicant]
US 20100034983A1 · Fuwa et al. · 2010 [cited by applicant]
US 20100193998A1 · Crump et al. · 2010 [cited by applicant]
US 20100294571A1 · Belnap et al. · 2010 [cited by applicant]
US 20110070394A1 · Hopkins · 2011 [cited by examiner]
US 20110176277A1 · Kaga et al. · 2011 [cited by applicant]
US 20110176952A1 · Kruzhanov et al. · 2011 [cited by applicant]
US 20120018926A1 · Mannella et al. · 2012 [cited by applicant]
US 20120087823A1 · Joshi et al. · 2012 [cited by applicant]
US 20130011603A1 · Yasukochi · 2013 [cited by applicant]
US 20130075957A1 · Swanson et al. · 2013 [cited by applicant]
US 20130112366A1 · Mottin et al. · 2013 [cited by applicant]
US 20140251481A1 · Kroll et al. · 2014 [cited by applicant]
US 20140265032A1 · Teicher et al. · 2014 [cited by applicant]
US 20140271961A1 · Khoshnevis · 2014 [cited by applicant]
US 20140291886A1 · Mark et al. · 2014 [cited by applicant]
US 20140300017A1 · Wighton et al. · 2014 [cited by applicant]
US 20140371895A1 · Sadusk et al. · 2014 [cited by applicant]
US 20150035209A1 · Shah et al. · 2015 [cited by applicant]
US 20150056317A1 · Chen · 2015 [cited by applicant]
US 20150066178A1 · Stava · 2015 [cited by applicant]
US 20150080495A1 · Heikkila · 2015 [cited by applicant]
US 20150084222A1 · Heston et al. · 2015 [cited by applicant]
US 20150093465A1 · Page · 2015 [cited by applicant]
US 20150125334A1 · Uetani et al. · 2015 [cited by applicant]
US 20150145168A1 · Rodgers et al. · 2015 [cited by applicant]
US 20150145169A1 · Liu et al. · 2015 [cited by applicant]
US 20150165687A1 · Ho et al. · 2015 [cited by applicant]
US 20150165691A1 · Mark et al. · 2015 [cited by applicant]
US 20150183167A1 · Molinari et al. · 2015 [cited by applicant]
US 20150197862A1 · Engel et al. · 2015 [cited by applicant]
US 20150202825A1 · Cordingley · 2015 [cited by applicant]
US 20150239179A1 · Goto et al. · 2015 [cited by applicant]
US 20150266092A1 · Andersson et al. · 2015 [cited by applicant]
US 20150273577A1 · Vader et al. · 2015 [cited by applicant]
US 20150273582A1 · Crump et al. · 2015 [cited by applicant]
US 20150283298A1 · Kaplan et al. · 2015 [cited by applicant]
US 20150306664A1 · Klint et al. · 2015 [cited by applicant]
US 20150336219A1 · Bruck et al. · 2015 [cited by applicant]
US 20160009027A1 · Martin · 2016 [cited by applicant]
US 20160022383A1 · Abels et al. · 2016 [cited by applicant]
US 20160023373A1 · Demuth et al. · 2016 [cited by applicant]
US 20160024293A1 · Nestle et al. · 2016 [cited by applicant]
US 20160039006A1 · Amstutz et al. · 2016 [cited by applicant]
US 20160052166A1 · Hartmann · 2016 [cited by applicant]
US 20160061381A1 · Kotliar · 2016 [cited by applicant]
US 20160075084A1 · Sakura · 2016 [cited by applicant]
US 20160089720A1 · Kamakura et al. · 2016 [cited by applicant]
US 20160096327A1 · Fry et al. · 2016 [cited by applicant]
US 20160108483A1 · Meyer et al. · 2016 [cited by applicant]
US 20160229128A1 · Dayagi et al. · 2016 [cited by applicant]
US 20160236293A1 · Chang et al. · 2016 [cited by applicant]
US 20160238324A1 · Butcher et al. · 2016 [cited by applicant]
US 20160243619A1 · Gothait et al. · 2016 [cited by applicant]
US 20160245710A1 · Twelves, Jr. et al. · 2016 [cited by applicant]
US 20160256925A1 · Heikkila · 2016 [cited by applicant]
US 20160271696A1 · Kamakura · 2016 [cited by applicant]
US 20160311165A1 · Mark et al. · 2016 [cited by applicant]
US 20160311167A1 · Gunther et al. · 2016 [cited by applicant]
US 20160332236A1 · Stoyanov · 2016 [cited by applicant]
US 20170021452A1 · Tanaka et al. · 2017 [cited by applicant]
US 20170028475A1 · Heikkila · 2017 [cited by applicant]
US 20170028651A1 · Versluys et al. · 2017 [cited by applicant]
US 20170113413A1 · Iwase et al. · 2017 [cited by applicant]
US 20170129012A1 · Ishida et al. · 2017 [cited by applicant]
US 20170129173A1 · Mantell et al. · 2017 [cited by applicant]
US 20170173692A1 · Myerberg et al. · 2017 [cited by applicant]
US 20170173868A1 · Mark · 2017 [cited by applicant]
US 20170196666A1 · Bohm et al. · 2017 [cited by applicant]
US 20170232674A1 · Mark · 2017 [cited by applicant]
US 20170252973A1 · Clark et al. · 2017 [cited by applicant]
US 20170297097A1 · Gibson et al. · 2017 [cited by applicant]
US 20170297100A1 · Gibson et al. · 2017 [cited by applicant]
US 20170297102A1 · Chin et al. · 2017 [cited by applicant]
US 20170297111A1 · Myerberg et al. · 2017 [cited by applicant]
US 20170312822A1 · Kimblad · 2017 [cited by applicant]
US 20170326789A1 · Kimblad et al. · 2017 [cited by applicant]
US 20170334137A1 · Nystrom · 2017 [cited by examiner]
US 20170334140A1 · Andersson et al. · 2017 [cited by applicant]
US 20170355138A1 · Mark · 2017 [cited by applicant]
US 20180000138A1 · Kelleher et al. · 2018 [cited by applicant]
US 20180001381A1 · Kimblad et al. · 2018 [cited by applicant]
US 20180071819A1 · Connor et al. · 2018 [cited by applicant]
US 20180134029A1 · Myerberg et al. · 2018 [cited by applicant]
US 20180154437A1 · Mark · 2018 [cited by applicant]
US 20180154439A1 · Mark · 2018 [cited by applicant]
US 20180154574A1 · Mark · 2018 [cited by applicant]
US 20180154580A1 · Mark · 2018 [cited by applicant]
CN 101422963A · 2009 [cited by applicant]
CN 101642809 · 2010 [cited by applicant]
CN 101642809A · 2010 [cited by applicant]
CN 203876241 · 2014 [cited by applicant]
CN 203876241U · 2014 [cited by applicant]
CN 104416903A · 2015 [cited by applicant]
CN 104582939A · 2015 [cited by applicant]
CN 204772942 · 2015 [cited by applicant]
CN 204772942U · 2015 [cited by applicant]
CN 105108154A · 2015 [cited by applicant]
CN 105408091A · 2016 [cited by applicant]
CN 105705319 · 2016 [cited by applicant]
CN 105705319A · 2016 [cited by applicant]
DE 19538257A1 · 1996 [cited by applicant]
DE 10311446A1 · 2004 [cited by applicant]
DE 102007033715A1 · 2009 [cited by applicant]
EP 0479219A1 · 1992 [cited by applicant]
EP 0764487 · 1997 [cited by applicant]
EP 0764487A1 · 1997 [cited by applicant]
EP 1400340A1 · 2004 [cited by applicant]
EP 1486318A2 · 2004 [cited by applicant]
EP 2359964A1 · 2011 [cited by applicant]
EP 2857179A1 · 2015 [cited by applicant]
EP 3067186A1 · 2016 [cited by applicant]
EP 3117982A1 · 2017 [cited by applicant]
GB 2302836 · 1997 [cited by applicant]
GB 2302836A · 1997 [cited by applicant]
GB 2532470A · 2016 [cited by applicant]
JP 2003212561 · 2003 [cited by applicant]
JP 2003212561A · 2003 [cited by applicant]
JP 2009236375A · 2009 [cited by applicant]
JP 2015131479A · 2015 [cited by applicant]
JP 2016065284A · 2016 [cited by applicant]
JP 7146757B2 · 2022 [cited by applicant]
KR 20140069021A · 2014 [cited by applicant]
KR 101762667B1 · 2017 [cited by applicant]
RU 2288073C2 · 2006 [cited by examiner]
WO 2004009281A1 · 2004 [cited by applicant]
WO 2004050323 · 2004 [cited by applicant]
WO 2004050323A1 · 2004 [cited by applicant]
WO 2009032228A2 · 2009 [cited by applicant]
WO 2009039159A2 · 2009 [cited by applicant]
WO 2013010108 · 2013 [cited by applicant]
WO 2013010108A1 · 2013 [cited by applicant]
WO 2014152798A1 · 2014 [cited by applicant]
WO 2014204570A2 · 2014 [cited by applicant]
WO 2015007966A1 · 2015 [cited by applicant]
WO 2015056230A1 · 2015 [cited by applicant]
WO 2015177348A1 · 2015 [cited by applicant]
WO 2015185502A1 · 2015 [cited by applicant]
WO 2016003275A1 · 2016 [cited by applicant]
WO 2016004985A1 · 2016 [cited by applicant]
WO 2016079193A1 · 2016 [cited by applicant]
WO 2016079495A1 · 2016 [cited by applicant]
WO 2016081499A1 · 2016 [cited by applicant]
WO 2016109111A1 · 2016 [cited by applicant]
WO 2016113213A1 · 2016 [cited by applicant]
WO 2016118151A1 · 2016 [cited by applicant]
WO 20160124432A1 · 2016 [cited by applicant]
WO 2016139287A1 · 2016 [cited by applicant]
WO 2017059866A2 · 2017 [cited by applicant]
WO 2017152142A1 · 2017 [cited by applicant]
WO 2017180314A1 · 2017 [cited by applicant]
WO 2018017330A1 · 2018 [cited by applicant]
WO 2018102021A1 · 2018 [cited by applicant]
WO 2018189062A1 · 2018 [cited by applicant]
RU-2288073, machine translation. (Year: 2006). [cited by examiner]
“3D printed PM filled filaments could replace MIM”, Materials Today, Apr. 14, 2015, www.materialstoday.com/metal-procesing/news/3d-printed-pm-filled-filaments-could-replace-mim/. [cited by applicant]
“AMUG: XJet Presenting NanoParticle Jetting Metal 3D Printing Process to Large Crowd”, 3DPrint.com, Apr. 6, 2016, https://3dprint.com/128448/amug-xjet-metal-3d-printer/. [cited by applicant]
“Caution Advised on 3D Printed Metal Proposal”, The Molding Blog, Apr. 14, 2015, http://www.themoldingblog.com/2015/04/14/proceed-with-caution-on-3d-printed-metal-parts/. [cited by applicant]
“ColorFabb beta tests new PLA Bronze & BambooFill filament for 3D printers”, 3ders.org, May 12, 2014, http://www.3ders.org/articles/20140512-colorfabb-beta-testing-new-pla-bronze-bamboofill-filament-for-3d-printers.html. [cited by applicant]
“ExOne:Digital Part Materialization/Industrial 3D Printing”, YouTube, https://www.youtube.com/channel/UC2AGWEWI1iF0mCeggzUyqNA [retrieved from the Internet on Jun. 6, 2018]. [cited by applicant]
“Filament lets you 3D print pure metal objects with your desktop 3D printer”, 3ders.org, Jun. 30, 2016, http://www.3ders.org//articles/20160630-filamet-lets-you-3d-print-pure-metal-objects-with-your-desktop-3d-printer.h… [cited by applicant]
“How can I avoid YSZ green ceramic material from sticking to the crucible during sintering?”, ResearchGate, https://www.researchgate.net/post/How_can_I_avoid_YSZ_green_ceramic_material_from_sticking_to_the_crucible_duri… [cited by applicant]
“Matterfab's 3D Metal Printer”, YouTube, published on Jul. 18, 2014, https://www.youtube.com/watch?v=wRXymDoYoWQ. [cited by applicant]
“Metal Injection Molding Turns the Volume Up, and Down”, Photo Labs, Inc., 2014 (4 pages). [cited by applicant]
“Modules of Furnace,” Published on Apr. 6, 2015, https://www.youtube.com/watch?v=zWk48KhQEec. [cited by applicant]
“PM and MIM—Touching Your Life, Part 1”, YouTube, published on Mar. 22, 2013, https://www.youtube.com/watch?v=0o_PiLJK0W0. [cited by applicant]
“PM and MIM—Touching Your Life, Part 2”, YouTube, published on Mar. 22, 2013, https://www.youtube.com/watch?v=shA65PATHxs. [cited by applicant]
“Ricoh makes metal injection molding obsolete with new highly efficient metal 3D printer”, 3ders.org, Jun. 24, 2016, http://www.3ders.org/articles/20160624-ricoh-makes-metal-injection-molding-obsolete-with-new-highly-ef… [cited by applicant]
“Ricoh's new method metal 3D printer, coating material particles with resin in advance”, MONOist, 2016, http://monoist.atmarkit.co.jp/mn/articles/1606/24/news057.html#l_sp_160624dms_ricoh_02.jpg. [cited by applicant]
“Separator Powder Sheets”, C12 Advanced Technologies, LLC, http://www.c12materials.com/separatorpowdersheets.html [retrieved from the Internet on Jun. 4, 2018]. [cited by applicant]
“Setter-Plates / Kiln Furniture” Data Sheet, Kerafol, Jul. 20, 2017. [cited by applicant]
“Sinterhad Filaments—3D Printing Products for Today's Emerging Industrial Additive Manufacturing Markets,” May 5, 2015, https://web.archive.org/web/20150505052938/http://sinterhardfilaments.com:80/. [cited by applicant]
“Sinterhard Filaments—Introduction,” May 6, 2015, https://web.archive.org/web/201505060055339/http://sinterhardfilaments.com:80/?page_id=9. [cited by applicant]
“Sinterhard,” Published on Apr. 6, 2015, https://www.youtube.com/watch?v=wHVP7vPqOGk&t+560s. [cited by applicant]
“Toll Debinding & Sintering Services,” DSH Technologies, LLC, Oct. 31, 2015, web archived at: https://web.archive.org/web/20151031133248/http://www.dshtech.com:80/tolldebinding.htm. [cited by applicant]
“Two-material/two-color powder metal injection molding”, Metal Injection Molding Handbook, A volume in Woodhead Publishing Series in Metals and Surface Engineering, 2012, Chapter 14, p. 343. [cited by applicant]
“XJet Demos Metal Jet 3D Printing Live at RAPID 2016”, Engineering.com, May 24, 2016, https://www.engineering.com/3DPrinting/3DPrintingArticles/ArticleID/12207/XJet-Demos-Metal-Jet-3D-Printing-Live-at-RAPID-2016.aspx. [cited by applicant]
“Xjet to develop world's first direct 3D metal jetting system for custom metal manufacturing”, 3ders.org, Nov. 10, 2015, http://www.3ders.org/articles/20151109-xjet-to-develop-worlds-first-direct-3d-metal-printing-jetti… [cited by applicant]
“XJet Website”, XJet, Mar. 2016, https://webarchive.org/web/20160307151914/http://www.xjet3d.com/technology. [cited by applicant]
U.S. Appl. No. 62/322,760 Specification, filed Apr. 14, 2016 (Year: 2016). [cited by applicant]
U.S. Appl. No. 62/432,298 Specification, filed Dec. 9, 2016 (Year: 2016). [cited by applicant]
U.S. Appl. No. 62/473,372 Specification, filed Mar. 18, 2017 (Year: 2017). [cited by applicant]
Adames, J. M., “Characterization of Polymeric Binders for Metal Injection Molding (MIM) Process,” A Dissertation Presented to the Graduate Faculty of the University of Akron, Dec. 2007, pp. 237. [cited by applicant]
Agarwala et al., “Fused Deposition of Ceramics and Metals: An Overview”, Center for Ceramic Research, Rutgers University; AlliedSignal Research and Technology, 1996, pp. 385-389. [cited by applicant]
Agarwala, M. et al., “Structural quality of parts processed by fused deposition”, Rapid Prototyping Journal, vol. 2, No. 4, 1996, pp. 4-19. [cited by applicant]
Agarwala, M.K., “Fused Deposition of Ceramics (FDC) for Structural Silicon Nitride Components”, Center for Ceramic Research and Dept. of Mechanical Engineering, Rutgers—The State University; AlliedSignal Inc., 1996, pp.… [cited by applicant]
Agrawal, Dinesh , “Microwave Sintering of Ceramics, Composites, Metals, and Transparent Materials”, Journal of Materials Education vol. 19(4.5 & 6), 1997, 9 Pages. [cited by applicant]
Asiabanpour, B. et al., “Advancements in the SIS process”, Texas State University, University of Southern California, Aug. 13, 2003, pp. 25-38. [cited by applicant]
Attia, U. et al., “A review of micro-powder injection moulding as a microfabrication technique”, Journal of Micromechanics and Microengineering, 21, (2011) 043001, 22 pages. [cited by applicant]
Burkhardt, Carlo et al., “Fused Filament Fabrication (FFF) of 316L Green Parts for the MIM process”, World PM2016-AM-Deposition Technologies 2016, 7 Pages. [cited by applicant]
Clancy, R. et al., “Fused Deposition of Ceramics: Progress Towards a Robust and Controlled Process for Commercialization”, AlliedSignal, Inc. Research and Technology, 2008, pp. 185-194. [cited by applicant]
Clemens Lieberwirth, Arne Harder and Hermann Seitz, “Extrusion Based Additive Manufacturing of Metal Parts”, Journal of Mechanics Engineering and Automation 7 (2017) 79-83. [cited by applicant]
Deckers, J. et al., “Additive Manufacturing of Ceramics: A Review”, Journal of Cermaic Science and Technology; vol. 5, No. 4, 2014, pp. 245-260. [cited by applicant]
Garcia, Javier H., “Development of Binder Systems Based on CAB for Power Injection Moulding (PIM) and Micro Power Injection Moulding (u-PIM) of Zircon and Invar Powers”, Jan. 27, 2013, 305 Pages. [cited by applicant]
Gibson et al. “Additive Manufacturing Technologies,” Spring Science+Business Media, LLC 2010, (Year: 2010). [cited by applicant]
Griffith, Michelle L. et al., “Freeform Fabrication of Ceramics via Stereolithography”, J.Am. Ceram. Soc., 79 [10] 2601-608, Mar. 1996, 8 pages. [cited by applicant]
Hartkop, David , “MiniMetalMaker—3D print with metal clay”, https://www.indiegogo.com/projects/minimetalmaker-3d-print-with-metal-clay#/2015, 3 pages. [cited by applicant]
Haselhuhn, A. et al., “In situ formation of substrate release mechanisms for gas metal arc weld metal 3-d printing”, 2015, pp. 50-59. [cited by applicant]
Haselhuhn, A. et al., “Substrate Release Mechanisms for Gas Metal Arc Weld 3-D Aluminum Metal Printing”, 3D Printing & Additive Manufacturing, 1(4), 2014, pp. 204-209. [cited by applicant]
Hidy, G. “Chapter 1 Introduction”, aerosols, an industrial and environmental science, 1984, 1-16 pages. [cited by applicant]
Hildreth, O. et al., “Dissolvable Metal Supports for 3D Direct Metal Printing”, 3D Printing and Additive Manufacturing, vol. 3, No. 2, 2016, pp. 91-97. [cited by applicant]
Hiller, J., “Digital Materials: Voxel Design, Rapid Assembly, Structural Properties, and Design Methods”, A Dissertation Prestented to the Faculty of the Graduate School of Cornell University, 2011. [cited by applicant]
Jafari, M.A. et al., “A novel system for fused deposition of advanced multiple ceramics”, Rapid Prototyping Journal, vol. 6, No. 3, 2000, pp. 161-174. [cited by applicant]
Jakus, Adam E. et al., “Metallic Architectures from 3D-Printed Powder-Based Liquid Inks”, Adv. Funct. Mater, DOI: 10.1002/adfm.201503921, 2015 pp. 6985-6995. [cited by applicant]
Khoshnevis, B. et al., “SIS—A New SFF Method Based on Powder Sintering”, University of Southern California, 2003, pp. 440-447. [cited by applicant]
“Fused quartz”, Wikipedia, Jan. 24, 2020, https://en.wikipedia.org/wiki/Fused_quartz. (Year: 2020). [cited by applicant]
Baojun Zhu et al: “Mathematical model for condensed-solvent debinding process of PIM”, Journal of Materials Processing Technology, vol. 142, No. 2, Nov. 1, 2003 (Nov. 1, 2003), pp. 487-492, XP055569090, NL, ISSN: 0924-0… [cited by applicant]
Cocco et al. “Introduction to Fluidization” AICHE Nov. 2014 p. 21-29 (Year: 2014). [cited by applicant]
Extended European Search Report from corresponding Euorpean Application No. 20206034.9 dated Mar. 26, 2021. [cited by applicant]
U.S. Appl. No. 62/395,289, filed Sep. 15, 2016, priority document for US 2018/0071819 (Year: 2016). [cited by applicant]
U.S. Appl. No. 62/407,318, filed Oct. 12, 2016, priority document for US 2018/0071819 (Year: 2016). [cited by applicant]
Klar. Powder Metallurgy. Metals Handbook Desk Edition, Second Edition. ASM International. 1998. 876-891. (Year: 1998). [cited by applicant]
Kollenberg, W. 2014. “Ceramics and Multi-Material 3D Printing.” Keramische Zeitschrift 4: 233-6 [English Abstract on front of the Patent]. [cited by applicant]
Kollenberg, W., “Keramik und Multi-Material 3D-Druck”, Keramische Zeitschrift, Apr. 2014, pp. 233-236. [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Apr. 10, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/119473… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Apr. 11, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/119640… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Apr. 14, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/119809… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Apr. 20, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/120008… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Apr. 24, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/120907… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Apr. 26, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/121058… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Apr. 26, 2015, 2nd Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/1… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Apr. 28, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/121290… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Apr. 30, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/121498… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Apr. 30, 2015, 2nd Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/1… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Apr. 9, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/1190938. [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Aug. 17, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/132670… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Aug. 29, 2016 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/166740… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Jan. 6, 2016 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/1459873. [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Jul. 24, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/130422… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Jul. 4, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/1259628. [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Jun. 10, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/post/125949… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Oct. 26, 2015 Update, https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-filaments-for-3d-printing/posts/13948… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Oct. 9, 2015, https://web.archive.org/web/20151009063620/https://www.kickstarter.com/projects/1093108121/sinterhard-metal-filled-fi… [cited by applicant]
Kovacs, B., “Sinterhard Metal or Ceramic Filled Filaments for 3D Printing—Kickstarter,” Oct. 9, 2015, Update Summary, https://web.archive.org/web/20151009063620/https://www.kickstarter.com/projects/1093108121/sinterhard… [cited by applicant]
Krassenstein, Brian , “Mini Metal Maker, Affordable Metal Clay 3D Printer, Relaunches on Indiegogo to Fund Mass Production”, https://3dprint.com/48292/mini-metal-maker-3d-print/, 2013, 6 Pages. [cited by applicant]
Kukla, Christian et al., “Effect of Particle Size on the Properties of Highly-Filled Polymers for Fused Filament Fabrication”, NPL—Jul. 20, 2016, 5 pages. [cited by applicant]
Kukla, Christian et al., “Properties for PIM Feedstocks Used in Fused Filament Fabrication”, World PM2016-AM—Deposition Technologies 2016, 5 Pages. [cited by applicant]
Kumar, S. et al., “Composites by rapid prototyping technology”, Materials and Design 31, 2010, pp. 850-856. [cited by applicant]
Lee et al., ed. “Production sintering practices,” ASM Handbook, vol. 7, ASM International, 1998, 468-503, (Year: 1998). [cited by applicant]
Lieberwirth, C. et al., “Extrusion Based Additive Manufacturing of Metal Parts”, Journal of Mechanics Engineering and Automation 7, 2017, pp. 79-83. [cited by applicant]
Lombardi, J. et al., “Issues Associated with EFF & FDM Ceramic Filled Feedstock Formulation”, Advanced Ceramics Research, Inc.; University of Arizona, Arizona Materials Laboratories, 1997, pp. 457-464. [cited by applicant]
Martens, T. et al., “Direct Sinter Bonding of Metal Injection-Molded Parts to Solid Substrate Through Use of Deformable Surface Microfeatures”, Journal of Micro and Nano-Manufacturing, Mar. 2013, vol. 1 (9 pages). [cited by applicant]
McMains S. et al, “Rapid Prototyping of Solid-Three Dimensional Parts”, Computer Science Division, Department of Electrical Engineering and Computer Science, 1995, 61 pages. [cited by applicant]
McNulty, T. et al., “Development of a Binder Formulation for Fused Deposition of Ceramics”, Rutgers University, Department of Ceramic and Materials Engineering, 1998, pp. 613-620, https://sffsymposium.engr.utexas.edu/Ma… [cited by applicant]
Michaels, S., “Production of Metal Parts Using the Three Dimensional Printing Process”, Massachusetts Institute of Technology, Department of Mechanical Engineering, 1993 (88 pages). [cited by applicant]
Molitch-Hou, Michael, XJet Releases New Metal and Ceramic 3D Printers, Engineering.com, Nov. 11, 2017, https://www.engineering.com/3DPrinting/3DPrintingArticles/ArticleID/15986/XJet-Releases-New-Metal-and-Ceramic-3D-Pri… [cited by applicant]
Nickels, Liz, “Crowdfunding metallurgy,” Metal Power Report, vol. 71, No. 5, Sep./Oct. 2016, Special Feature, pp. 324-327. [cited by applicant]
Nishiyabu, K., “Powder space holder metal injection molding (PSH-MIM) of micro-porous metals”, Woodhead Publishing Limited, 2012, pp. 349-390. [cited by applicant]
O'Neal, Bridget, “Aluminum & Steel 3D Printer Filaments on Their Way—Sinterhard Launces Kickstarter Campaign”, Apr. 7, 2015, https://3dprint.com/56373/sinterhard-kickstarter/. [cited by applicant]
Onagoruwa, S., Bose, S., and Bandyopadhyay, A. 2001. “Fused Deposition of Ceramics (FDC) and Composites.” In Proc. SFF, 224-31. [cited by applicant]
Park, Mansoo et al., “Accelerated sintering in phase-separating nanostructured alloys”, Nature Communications | 6:6858 | DOI: 10.1038/ncomms7858 |www.nature.com/naturecommunications Apr. 22, 2015, 6 pages. [cited by applicant]
Peterson, K. et al., “Macro-Meso-Microsystems Integration in LTCC: LDRD Report”, Sandia Report, Sandia National Laboratories, Mar. 2007 (90 pages). [cited by applicant]
Peterson, K.A. et al., “Novel Microsystem Applications with New Techniques in Low-Temperature Co-Fired Ceramics”, International Journal of Applied Ceramic Technology, vol. 2, No. 5, 2005, pp. 345-363. [cited by applicant]
Petros, M., “The Extension of Selective Inhibition Sintering (SIS) to High Temperature Alloys”, A Dissertation Presented to the Faculty of the USC Graduate School, University of Southern California, Aug. 2016 (121 pages… [cited by applicant]
Ponche et al., “A new global approach to design for additive manufacturing”, Virtual and Physical Prototyping, Taylor & Francis, 2012 7 (2), pp. 93-105. [cited by applicant]
Porter, “Effects of binder systems for metal injection moulding,” Master's Thesis, Lulea University of Technology, 2003, (Year: 2003). [cited by applicant]
Riecker, S. et al., “Fused Deposition Modeling-Opportunities for Cheap Metal AM”, World PM2016-AM—Deposition Technologies, 2016, 6 Pages. [cited by applicant]
Scheithauer, U., Slawik, T., Schwarzer, E., Richter, H.-J., Moritz, T., and Michaelis, A. 2015. “Additive Manufacturing of Metal-Ceramic-Composites by Thermoplastic 3D-Printing (3DTP).” Journal of Ceramic Science and Te… [cited by applicant]
Seluga, K., “Three Dimensional Printing by Vector Printing of Fine Metal Powders”, Massachusetts Institute of Technology, Department of Mechanical Engineering, Aug. 2001, pp. 1-96. [cited by applicant]
Shah, Ramille N. et al., “3D-Printing of Energy Devices Using Particle-Based Inks”, Northwestern University, Querrey Institute for BioNanotechnology Institute for Sustainability and Energy at Northwestern Aug. 2014, 5 P… [cited by applicant]
Specification Sheet: Alloy 17-4PH. Sandmeyer Steel Company. Apr. 2018. (Year: 2018). [cited by applicant]
Stanimirovic, Z. et al., “Ceramic Injection Molding, Some Critical Issues for Injection Molding”, Dr. Jian Wang (Ed.), ISBN: 978-953-51-0297-7, InTech (2012), pp. 131-148, Available from: http://www.intechopen.com/books… [cited by applicant]
Stanimirovic, Z. et al., “Ceramic Injection Molding, Some Critical Issues for Injection Molding,” Published online 23, Mar. 2012, pp. 131-149. [cited by applicant]
Tay, B.Y. et al., “Solid freeform fabrication of ceramics”, International Materials Reviews, vol. 48, No. 6, 2003, pp. 341-370. [cited by applicant]
Taylor, Shannon L. et al., “Iron and Nickel Cellular Structures by Sintering of 3D-Printed Oxide or Metallic Particle Inks”, Advanced Engineering Materials, DOI: 10.1002/adem.201600365, Sep. 16, 2016, 8 pages. [cited by applicant]
Torabi, P. et al., “Selective Inhibition Sintering; The Process for Consumer Metal Additive Manufacturing,” Mary Ann Liebert, Inc., vol. 1, No. 3, 2014, pp. 152-155. [cited by applicant]
Van Biezen, Michel, Mechanical Engineering: Trusses, Bridges & Other Structures (1 of 34) What is a Truss? YouTube, Published Jan. 20, 2016. https://www.youtube.com/watch?v=AXI_CoLAHm4. (Year: 2016). [cited by applicant]
Wang, H. et al., “Modifying Polyacetal Binder Based Feedstock to Improve Quality of MIM Parts”, Materials Technology Laboratory, CANMET, Department of Natural Resources Canada, 1987, pp. 18-45 to 18-55. [cited by applicant]
Wang, H. et al., “Modifying Polyacetal Binder Based Feedstock to Improve Quality of MIM Parts,” Metal Powder Industries Federation, American Powder Metallurgy Institute Internationa, 1997, pp. 18-55. [cited by applicant]
Williams, C., “Design and Development of a Layer-Based Additive Manufacturing Process for the Realization of Metal Parts of Designed Mesostructure”, Georgia Institute of Technology, Apr. 2008 (422 pages). [cited by applicant]
Wu et al., “Solid freeform fabrication of metal components using fused deposition of metals”, Materials and Design, 23 (2002), pp. 97-105. [cited by applicant]
Yoo, H., “Reactive Binders for Metal Parts Produced by Three Dimensional Printing”, Massachusetts Institute of Technology, Department of Mechanical Engineering, May 1997, pp. 1-106. [cited by applicant]
Zaleski, Andrew, “Why 3D-Printing Companies Should be Watching This Startup”, Dec. 1, 2015, http://fortune.com/2015/12/01/3d-printing-metals-xjet/. [cited by applicant]
Zhang, J. et al., “Selective Separation Sintering (SSS) a New Layer Based Additive Manufacturing Approach for Metals and Ceramics”, University of Southern California, Department of Industrial and Systems Engineering, 20… [cited by applicant]
U.S. Appl. No. 62/322,760 Specification, 30 pages, filed Apr. 14, 2016 (Year: 2016). [cited by applicant]