Prepreg, laminate, and production methods therefor, as well as printed circuit board and semiconductor package
Provided is a prepreg capable of attaining thermal expansion coefficient reduction and elastic modulus increase without increasing the filling ratio of an inorganic filler therein and/or without using a resin having a low thermal expansion coefficient, and thereby capable of reducing warpage thereof. Specifically, provided is a prepreg containing glass fibers and a thermosetting resin composition, and containing a layer of plural glass fiber filaments aligned to run nearly parallel to each other in one direction. Also provided are a production method for the prepreg, a laminate containing the prepreg and its production method, a printed circuit board containing the laminate, and a semiconductor package having a semiconductor device mounted on the printed circuit board.
1. A prepreg for forming a laminate used in a semiconductor package, the prepreg comprising glass fibers and a thermosetting resin composition, which contains a layer of plural glass fiber filaments aligned to run nearly parallel to each other in one direction,
wherein the prepreg does not contain a glass fiber bundle of 50 or more glass fiber filaments bundled, or contains such glass fiber bundles, but the content thereof is 10% by volume or less relative to the total amount of the glass fibers in the prepreg, and
wherein the prepreg has a property that, when a plurality of the prepregs are provided in layers in a laminate that contains a layer of plural glass fiber filaments aligned to run nearly parallel to each other in one direction, and a layer of plural glass fiber filaments aligned to run nearly parallel to each other in the other one direction different from the previous one direction, the laminate has a bending elastic modulus at 25° C. of 35 GPa or more.
2. The prepreg according to claim 1 , wherein the content of the glass fibers is 60 to 75% by volume relative to the entire prepreg.
3. The prepreg according to claim 1 , having a thickness of 100 μm or less.
4. The prepreg according to claim 1 , wherein the prepreg does not contain a glass fiber bundle of 50 or more glass fiber filaments bundled, or contains such glass fiber bundles, but in which the content thereof is 5% by volume or less relative to the total amount of the glass fibers in the prepreg.
5. The prepreg according to claim 1 , wherein the prepreg does not contain a glass fiber bundle of 50 or more glass fiber filaments bundled, or contains such glass fiber bundles, but in which the content thereof is 2% by volume or less relative to the total amount of the glass fibers in the prepreg.
6. The prepreg according to claim 1 , wherein the prepreg does not contain a glass fiber bundle of 100 or more glass fiber filaments bundled.
7. The prepreg according to claim 1 , wherein the prepreg does not contain a glass fiber bundle of 50 or more glass fiber filaments bundled.
8. The prepreg according to claim 1 , wherein the plural glass fiber filaments are glass fiber filaments prepared by opening glass fiber bundles.
9. The prepreg according to claim 1 , wherein the content of the glass fibers is 50 to 75% by volume relative to the entire prepreg.
10. The prepreg according to claim 9 , wherein the thermosetting resin composition does not contain an inorganic filler, or contains an inorganic filler but the content thereof is 12% by volume or less in the thermosetting resin composition.
11. The prepreg according to claim 1 , wherein the thermosetting resin composition does not contain an inorganic filler, or contains an inorganic filler but the content thereof is 12% by volume or less in the thermosetting resin composition, and the thermosetting resin composition does not contain a thermoplastic elastomer.
12. A laminate comprising the prepreg of claim 1 , which contains:
a layer of plural glass fiber filaments aligned to run nearly parallel to each other in one direction, and a layer of plural glass fiber filaments aligned to run nearly parallel to each other in the other one direction different from the previous one direction.
13. The laminate according to claim 12 , wherein the other one direction different from the previous one direction is another one direction nearly perpendicular to the previous one direction.
14. The laminate according to claim 12 , which is such that, in the cross section in the thickness direction of the laminate, the upper half and the lower half divided at the center thereof are nearly in plane symmetry.
15. A printed circuit board comprising the laminate of claim 1 .
16. A semiconductor package with a semiconductor device mounted on the printed circuit board of claim 15 .