Silicon oxide selective dry etch process
Systems and methods for processing a workpiece are provided. In one example, a method includes exposing the workpiece to a first gas mixture when the workpiece is at a first temperature to conduct a doped silicate glass etch process. The first gas mixture can include hydrofluoric acid (HF) vapor. The doped silicate glass etch process at least partially removes the doped silicate glass layer at a first etch rate that is greater than a second etch rate associated with removal of the at least one second layer. The method can include heating the workpiece to a second temperature. The second temperature is greater than the first temperature. The method can include exposing the workpiece to a second gas mixture when the workpiece is at a second temperature to remove a residue from the workpiece.
1. A method for etching a doped silicate glass layer on a workpiece, wherein the workpiece comprises the doped silicate glass layer and at least one second layer, the second layer being a different material than the doped silicate glass layer, and the method comprising:
placing the workpiece on a workpiece support in a processing chamber;
generating a mixture from a plasma in a remote plasma chamber from a process gas comprising hydrogen containing precursors and fluorine containing precursors;
exposing the workpiece to the mixture when the workpiece is at a first temperature;
increasing a temperature of the workpiece to a second temperature by heating the workpiece using a heat source;
exposing the workpiece to the mixture generated from the plasma in the remote plasma chamber during increasing of the workpiece to the second temperature;
exposing the workpiece to the mixture generated in the remote plasma chamber when the workpiece is at the second temperature;
removing the workpiece from the processing chamber.
2. The method of claim 1 , wherein the doped silicate glass is borosilicate glass, and boron concentration is between about 1% and about 10%.
3. The method of claim 1 , wherein the doped silicate glass is phosphosilicate glass, and phosphorus concentration is between about 1% and about 10%.
4. The method of claim 1 , wherein the doped silicate glass is borophosphosilicate glass, boron concentration is between about 1% and about 10%, and phosphorus concentration is between about 1% and about 10%.
5. The method of claim 1 , wherein the first temperature is in a range of about 20° C. to about 200° C.
6. The method of claim 1 , wherein the first temperature is about 30° C. to about 90° C.
7. The method of claim 1 , wherein the second temperature is about 150° C. to about 400° C.
8. The method of claim 1 , wherein the second temperature is about 150° C. to about 250° C.
9. The method of claim 1 , wherein the at least one second layer is titanium nitride.
10. The method of claim 1 , wherein the at least one second layer is silicon nitride.
11. The method of claim 1 , wherein the at least one second layer is silicon.
12. The method of claim 1 , wherein the at least one second layer is undoped silicate glass.
13. The method of claim 1 , wherein exposing the workpiece to the mixture when the workpiece is at a first temperature occurs when the workpiece is at a first vertical position.
14. The method of claim 13 , wherein exposing the workpiece to the mixture when the workpiece is at the second temperature occurs at a second vertical position.
15. The method of claim 1 , wherein the second vertical position is closer to a separation grid separating the processing chamber from the remote plasma chamber.
16. The method of claim 1 , wherein the plasma is generated using an inductively coupled plasma source.
17. The method of claim 1 , wherein the heat source comprises one or more heating elements located in the workpiece support.
18. The method of claim 1 , wherein the heat source comprises one or more lamps.
19. The method of claim 1 , wherein the heat source comprises the remote plasma chamber.
20. A method for etching a doped silicate glass layer on a workpiece, wherein the workpiece comprises a doped silicate glass layer and at least one second layer, the second layer being a different material than the doped silicate glass layer, and the method comprising:
placing the workpiece on a workpiece support in a processing chamber;
generating a mixture from a plasma in a remote plasma chamber from a process gas comprising hydrogen containing precursors and fluorine containing precursors;
exposing the workpiece to the mixture when the workpiece is at a first vertical position relative to the remote plasma chamber;
exposing the workpiece to the mixture generated in the remote plasma chamber when the workpiece is at a second vertical position relative to the remote plasma chamber;
removing the workpiece from the processing chamber.