Ferroelectric field effect transistors having enhanced memory window and methods of making the same
A ferroelectric transistor includes a semiconductor channel comprising a semiconductor material, a strained and/or defect containing ferroelectric gate dielectric layer located on a surface of the semiconductor channel, a source region located on a first end portion of the semiconductor channel, and a drain region located on a second end portion of the semiconductor channel.
1. A ferroelectric transistor, comprising:
a strained single crystalline semiconductor layer;
a strained ferroelectric gate dielectric layer located on a top surface of the strained single crystalline semiconductor layer;
a gate electrode located on the strained ferroelectric gate dielectric layer;
a source region and a drain region embedded within or in contact with the strained single crystalline semiconductor layer and laterally spaced apart from each other by a semiconductor channel located within the strained single crystalline semiconductor layer and underlying the strained ferroelectric gate dielectric layer; and
a substrate semiconductor layer comprising a first single crystalline semiconductor material and having a first in-plane average lattice constant;
wherein:
the strained single crystalline semiconductor layer comprises a second single crystalline semiconductor material, in epitaxial alignment with the substrate semiconductor layer, and having a second in-plane average lattice constant that is different from the first in-plane average lattice constant; and
at least a predominant fraction of an entire volume of the strained ferroelectric gate dielectric layer contacting the strained single crystalline semiconductor layer is in epitaxial alignment with the strained single crystalline semiconductor layer.
2. The ferroelectric transistor of claim 1 , further comprising a single crystalline buffer semiconductor layer located between, and epitaxially aligned to each of, the substrate semiconductor layer and the strained single crystalline semiconductor layer, and having a variable in-plane lattice constant that changes as a function of a vertical distance from the substrate semiconductor layer.
3. The ferroelectric transistor of claim 1 , wherein a portion of the strained ferroelectric gate dielectric layer overlying the strained single crystalline semiconductor layer is single crystalline, and is epitaxially aligned to the strained single crystalline semiconductor layer.
4. The ferroelectric transistor of claim 1 , wherein:
each of the substrate semiconductor layer and the strained single crystalline semiconductor layer comprises silicon atoms at an atomic percentage greater than 50%; and
at least one of the substrate semiconductor layer and the strained single crystalline semiconductor layer comprises germanium or carbon at an atomic percentage greater than 0.1%.
5. A ferroelectric transistor, comprising:
a strained single crystalline semiconductor layer;
a strained ferroelectric gate dielectric layer located on a top surface of the strained single crystalline semiconductor layer;
a gate electrode located on the strained ferroelectric gate dielectric layer; and
a source region and a drain region embedded within or in contact with the strained single crystalline semiconductor layer and laterally spaced apart from each other by a semiconductor channel located within the strained single crystalline semiconductor layer and underlying the strained ferroelectric gate dielectric layer;
wherein the strained ferroelectric gate dielectric layer comprises nanoclusters of a non-polar metallic element that does not form a ferroelectric oxide material upon combination with oxygen at an atomic percentage in a range from 0.01% to 10%.