Electronic device
An electronic device is provided. The device comprises a singulated carrier portion, a substrate molded onto the singulated carrier portion, and conductive traces disposed on the substrate. The substrate comprises a polymer composition that includes a thermotropic liquid crystalline polymer, a mineral filler, wherein the polymer composition exhibits an in-plane thermal conductivity of about 1 W/m-K or more as determined in accordance with ASTM E1461-13.
1 . An electronic device comprising:
a singulated carrier portion;
a substrate molded onto the singulated carrier portion, wherein the substrate comprises a polymer composition that includes a thermotropic liquid crystalline polymer, a mineral filler, and an electrically conductive filler, wherein the mineral filler comprises wollastonite fibers having a median diameter of from about 1 to about 35 micrometers, and wherein the polymer composition exhibits an in-plane thermal conductivity of about 1 W/m-K or more as determined in accordance with ASTM E1461-13 and a surface resistivity of about 1×10 16 ohms or more as determined in accordance with IEC 62631-3-1:2016, wherein the polymer composition is free of carbon fibers and fillers having an intrinsic thermal conductivity of 50 W/m-K or more; and
conductive traces disposed on the substrate.
2 . The electronic device of claim 1 , wherein the polymer composition exhibits a volume resistivity of about 1×10 13 ohm or more as determined in accordance with IEC 62631-3-1:2016.
3 . The electronic device of claim 1 , wherein the polymer matrix constitutes from about 30 wt. % to about 80 wt. % of the polymer composition.
4 . The electronic device of claim 1 , wherein the liquid crystalline polymer has a melting temperature of about 280° C. or more.
5 . The electronic device of claim 4 , wherein the liquid crystalline polymer contains one or more repeating units derived from an aromatic hydroxycarboxylic acid, wherein the hydroxycarboxylic acid repeating units constitute about 40 mol. % or more of the polymer.
6 . The electronic device of claim 5 , wherein the liquid crystalline polymer contains repeating units derived from 4-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid, or a combination thereof.
7 . The electronic device of claim 5 , wherein the liquid crystalline polymer contains repeating units derived from 4-hydroxybenzoic acid in an amount of from about 30 mol. % to about 90 mol. % of the polymer and contains repeating units derived from 6-hydroxy-2-naphthoic acid in amount of from about 1 mol. % to about 30 mol. % of the polymer.
8 . The electronic device of claim 5 , wherein the liquid crystalline polymer further contains repeating units derived from terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, hydroquinone, 4,4′-biphenol, acetaminophen, 4-aminophenol, or a combination thereof.
9 . The electronic device of claim 1 , wherein the polymer composition exhibits a through-plane thermal conductivity of about 0.2 W/m-K or more as determined in accordance with ASTM E1461-13.
10 . The electronic device of claim 1 , wherein the mineral filler is present in the polymer composition in an amount of from about 10 to about 80 parts by weight per 100 parts by weight of the polymer matrix.
11 . The electronic device of claim 10 , wherein the mineral filler further contains mineral particles.
12 . The electronic device of claim 11 , wherein the mineral particles include talc, mica, or a combination thereof.
13 . The electronic device of claim 1 , wherein the wollastonite fibers have a median diameter of from about 2 to about 20 micrometers.
14 . The electronic device of claim 1 , wherein the wollastonite fibers have an aspect ratio of from about 1.1 to about 100.
15 . The electronic device of claim 1 , wherein the polymer composition has a melt viscosity of from about 10 to about 250 Pa-s, as determined in accordance with ISO Test No. 11443:2014 at a shear rate of 1,000 s −1 and temperature that is 15° C. above the melting temperature of the composition.
16 . The electronic device of claim 1 , wherein the singulated carrier portion comprises a metal.
17 . A light assembly comprising an LED module that contains one or more light emitting diodes, wherein the light assembly comprises the electronic device of claim 1 .
18 . The electronic device of claim 1 , wherein the polymer composition exhibits a surface resistivity greater than 1×10 17 ohms as determined in accordance with IEC 62631-3-1:2016.
19 . The electronic device of claim 1 , wherein the polymer composition exhibits a tensile strength from 143 to about 500 MPa and a tensile strain at break from 2.7% to about 15% as determined in accordance with ISO Test No. 527:2019 at 23° C.
20 . An electronic device comprising:
a singulated carrier portion;
a substrate molded onto the singulated carrier portion, wherein the substrate comprises a polymer composition that consists essentially of a thermotropic liquid crystalline polymer, a mineral filler, an electrically conductive filler, and optionally one or more additives selected from the group consisting of glass fibers, impact modifiers, lubricants, pigments, antioxidants, stabilizers, surfactants, waxes, flame retardants, anti-drip additives, and nucleating agents,
wherein the mineral filler comprises wollastonite fibers having a median diameter of from about 1 to about 35 micrometers, and wherein the polymer composition exhibits an in-plane thermal conductivity of about 1 W/m-K or more as determined in accordance with ASTM E1461-13 and a surface resistivity of about 1×10 16 ohms or more as determined in accordance with IEC 62631-3-1:2016, wherein the polymer composition is free of carbon fibers and fillers having an intrinsic thermal conductivity of 50 W/m-K or more; and
conductive traces disposed on the substrate.