Reinforced glass, and method for producing reinforced glass
A tempered glass has a surface and a thickness. When a compressive stress of the tempered glass is represented by a positive number and a tensile stress thereof is represented by a negative number, the compressive stress at the surface is 400 MPa or more, a stress profile of the tempered glass obtained by measuring a stress in a depth direction from the surface has inflection points at each of which a second derivative of the stress profile becomes zero between the surface and a depth equal to half of the thickness, and the compressive stress value at a first inflection point at a position closest to the surface among the inflection points is 150 MPa or less. The compressive stress at a second inflection point at a position deeper than the first inflection point is 45 MPa or less.
1. A tempered glass having a surface and a thickness T,
wherein, when a compressive stress of the tempered glass is represented by a positive number and a tensile stress thereof is represented by a negative number,
a maximum value of the compressive stress at the surface is 400 MPa or more,
a stress profile of the tempered glass obtained by measuring a stress in a depth direction from the surface has inflection points at each of which a second derivative of the stress profile becomes zero between the surface and a depth equal to a half of the thickness T, and
the compressive stress at a first inflection point present at a position closest to the surface among the inflection points is 150 MPa or less,
wherein the inflection points comprise a second inflection point present at a position deeper than the first inflection point, and
wherein (σ 1 −σ 2 )/(d 1 −d 2 ) is −1.0 MPa/μm or more, where σ 1 represents the stress at the first inflection point, d 1 represents a depth of the first inflection point from the surface, σ 2 represents the stress at the second inflection point, and d 2 represents a depth of the second inflection point from the surface.
2. The tempered glass according to claim 1 , wherein the compressive stress at the second inflection point is 45 MPa or less.
3. The tempered glass according to claim 1 , wherein the depth of the first inflection point from the surface is 50 μm or less.
4. The tempered glass according to claim 1 , wherein the depth of the second inflection point from the surface is 60 μm or more.
5. The tempered glass according to claim 1 ,
wherein the stress profile has a zero stress point at which the stress becomes zero, and
wherein the zero stress point is present at a position deeper than 12% of the thickness T from the surface.
6. The tempered glass according to claim 5 , wherein S CS /T is 16.0 MPa or less, where S CS (Mpa·mm) represents an integrated value of the compressive stress from the surface to the zero stress point.
7. The tempered glass according to claim 1 , wherein a maximum absolute value of the tensile stress is 70 MPa or less.
8. The tempered glass according to claim 1 ,
wherein the thickness T falls within a range of 0.3 mm or more and 1.0 mm or less,
wherein the tempered glass has a front main surface, a back main surface, a first end surface, and a second end surface,
wherein the surface is one of the front main surface, the back main surface, the first end surface, or the second end surface, and
wherein the stress profile is in each of the front main surface, the back main surface, the first end surface, and the second end surface.
9. The tempered glass according to claim 1 ,
wherein the thickness T falls within a range of 0.45 mm or more and 0.85 mm or less,
wherein the maximum value of the compressive stress at the surface falls within a range of 700 MPa or more and 850 MPa or less,
wherein a maximum absolute value of the tensile stress falls within a range of 42 MPa or more and 65 MPa or less,
wherein the stress profile has a zero stress point at which the stress becomes zero,
wherein the zero stress point is present at a position within a range of 17% or more and 25% or less of the thickness T from the surface, and
wherein the compressive stress at the first inflection point falls within a range of 30 MPa or more and 80 MPa or less.
10. The tempered glass according to claim 1 , wherein the tempered glass comprises as a glass composition, in terms of mass %, 40% to 70% of SiO 2 , 10% to 30% of Al 2 O 3 , 0% to 10% of B 2 O 3 , 2% to 11% of Li 2 O, 5% to 25% of Na 2 O, 0% to 10% of K 2 O, 0% to 6% of MgO, and 0% to 20% of P 2 O 5 .
11. A method of producing a tempered glass having a surface and a thickness T according to claim 1 ,
the method comprising:
a first ion exchange step of bringing a glass to be tempered containing Li 2 O and Na 2 O into contact with a first molten salt containing a Na ion to introduce the Na ion into the glass to be tempered; and
a second ion exchange step of bringing, after the first ion exchange step, the glass to be tempered into contact with a second molten salt containing a Li ion and a K ion to desorb at least part of the Na ion from the glass to be tempered, and to introduce the K ion into the glass to be tempered,
wherein the first ion exchange step and the second ion exchange step are performed so that a stress profile of the tempered glass obtained by measuring a stress in a depth direction from the surface with a compressive stress being represented by a positive number and a tensile stress being represented by a negative number has inflection points each of which a second derivative of the stress profile becomes zero between the surface and a depth equal to a half of the thickness T.
12. The method of producing a tempered glass according to claim 11 , wherein the inflection points are formed in the second ion exchange step.