Methods of making glass constructs
Manufacturing methods for making a substantially rectangular and flat glass preform for manufacturing a Li ion conducting glass separator can involve drawing the preform to a thin sheet and may involve one or more of slumping, rolling or casting the glass within a frame that defines a space filling region and therewith the shape and size of the preform. The thickness of the rectangular flat preform so formed may be about 2 mm or less. The frame may be slotted having a back surface and widthwise wall portion that define the height and width of the space filling region. The flat backing surface and surfaces of the widthwise wall portions are defined may be coated by a material that is inert in direct contact with the heated glass material, such as gold.
1. A method of making a substantially rectangular and flat glass preform for manufacturing a Li ion conducting glass separator by drawing the preform to a thin sheet, the method comprising:
a. providing a Li ion conductive glass material for shaping into a substantially rectangular and flat solid glass preform, the glass material having glass transition temperature, Tg;
b. providing a slotted frame that defines a substantially rectangular space filling region for receiving the Li ion conducting glass material, the slotted frame comprising a flat backing surface and widthwise wall portions that define the height and width of the space filling region;
c. disposing the Li ion conductive glass material within the space filling region;
d. forming the glass preform by heating the glass material above Tg and pressing the glass material against the substantially flat backing surface such that it flows against the widthwise edges of the slotted frame;
e. cooling the glass material below Tg to a form the solid glass preform;
f. removing the solid glass preform from the slotted frame.
2. The method of claim 1 wherein the glass material disposed within the space filling slot is a solid article of Li ion conducting glass.
3. The method of claim 2 wherein the solid article of Li ion conducting glass is cylindrically shaped.
4. The method of claim 1 wherein the slotted frame is disassemblable, comprising first and second conjoined members.
5. The method of claim 4 wherein the first conjoined member is a substantially flat backing plate, and the second conjoined member is a window frame.
6. The method of claim 1 wherein the space filling region of the slotted frame is defined by a disassemblable window frame, and further comprising wherein removing the solid glass preform comprises disassembling the frame prior to removing the glass preform from the frame.
7. The method of claim 1 wherein the slotted frame is composed of a material that is inert in direct contact with the heated glass material.
8. The method of claim 1 wherein the flat backing surface and surfaces of the widthwise wall portions are defined by a material coating that is inert in direct contact with the heated glass material.
9. The method of claim 8 wherein the material coating is a gold coating.