IP Library › Granted Patent US 12,454,478
Granted Patent B2
US 12,454,478 · App. 18/463,206 · Granted Oct 28, 2025

Ionically conductive glass preform

Inventors: Steven J. Visco (Berkeley, CA); Vitaliy Nimon (Berkeley, CA); Alexei Petrov (Berkeley, CA); Yevgeniy S. Nimon (Berkeley, CA); Bruce D. Katz (Berkeley, CA)
Assignee: PolyPlus Battery Company
C03B23/0013
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Quick Facts
Patent No.
US 12,454,478
App. No.
18/463,206
Filed
Sep 7, 2023
Granted
Oct 28, 2025
Kind
B2
Art Unit
1746
USPC
65/102
Abstract

An ionically conductive glass (or glassy) monolithic preform having a certain shape, size, and dimension may be made from a monolithic precursor material (e.g., an ingot or boule of ion conductive glass), generally of a different shape and size.

Claims (15)

1. A method of making an ionically conductive glass preform, the method comprising:

a. providing an inorganic ion conductive glass monolith as a precursor material, the glass precursor monolith having a precursor shape, size, dimension, glass transition temperature (Tg), and glass melting temperature (T m );

b. providing a collapsible hollow structure having a wall with an inner and outer surface;

c. disposing the glass precursor monolith inside the collapsible hollow structure; and

d. pressing and heating the glass precursor monolith while it is inside the collapsible hollow structure, wherein the temperature of the glass precursor monolith during pressing is at or above the precursor Tg, wherein the pressing and heating operation uniformly collapses the hollow structure and thereby transforms the glass precursor monolith into a monolithic glass preform having a preform shape and dimension different than that of the glass precursor monolith;

wherein an inner liner material is disposed inside the collapsible hollow structure and thereby serves as an interlayer between the glass precursor monolith and the inner wall surface of the collapsible hollow structure.

2. The method of claim 1 wherein the glass precursor monolith is a glass boule.

3. The method of claim 2 wherein the glass boule has a cylindrical shape, with a substantially round cross section and further wherein the preform shape of the monolithic glass preform has a substantially rectangular cross section.

4. The method of claim 3 wherein the collapsible hollow structure is in the form of a tube having a substantially circular cross section, with a cross-sectional diameter sufficient to accommodate the glass boule.

5. The method of claim 4 wherein the collapsible hollow structure is a flattenable tube.

6. The method of claims 1 or 5 wherein the collapsible hollow structure is an organic polymeric material.

7. The method of claim 6 wherein the organic polymeric material is a fluorinated polymer.

8. The method of claim 6 where the organic polymeric material is a not a fluorinated polymer and chemically incompatible with the glass precursor monolith at or near the precursor Tg.

9. The method of claim 6 wherein the inner liner is a fluorinated polymeric material.

10. The method of claim 6 wherein the wall of the collapsible hollow structure has a thickness that is selected to maintain a hollow shape at room temperature sufficient to accommodate the glass precursor monolith and to allow the collapsible hollow structure to uniformly collapse to the preform shape of the monolithic glass preform when heated to a temperature above the precursor Tg.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 3, 2024
From: VISCO, STEVEN J.; NIMON, VITALIY; PETROV, ALEXEI; NIMON, YEVGENIY S.; KATZ, BRUCE D.
To: POLYPLUS BATTERY COMPANY
Reel/Frame 067598/0443 →
Continuity (3)
Provisional Application 63496894 · Apr 18, 2023
Provisional Application 63375212 · Sep 9, 2022
Related Publication 20240092676A1 · Mar 21, 2024
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