Granted Patent
B2
US 12,269,961 · App. 17/390,259 · Granted Apr 8, 2025
Multi-coat polymer photonic crystal films
Inventors:
Ryan Michael Pearson (Berkeley, CA); Matthew David Ryan (Berkeley, CA); Garret Miyake (Fort Collins, CO)
C09D155/005B29D11/00865C08F299/0485C09D4/00C09D5/002C09D7/41C09D7/61C09D133/10C09D153/00C09D175/14C09D181/02G02B1/005Y10T428/2848
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Abstract
Polymer composite photonic crystal materials are disclosed as coatings with topcoats having high reflection (>30%) in a specific range of the electromagnetic spectrum, such as ultraviolet (<400 nm), visible (Vis, 400 nm-700 nm), or near-infrared radiation range (NIR, 700-2000 nm), and optionally a relatively low reflection (<20% reflection) in a second, different range of the electromagnetic spectrum. Surprisingly, it was found that through a multi-layer coating approach, the optical properties of polymer composite photonic crystal films can be selectively modified from a variety of different coating methods, including spray deposition.
Claims (31)
1. A multilayer coating comprising:
a) a first layer of a photonic crystal film comprising an additive and brush block copolymer (BBCP) of Formula IA or Formula IB:
wherein
R x is —(C 2 -C 6 )alkyl-OC(═O)G 1 wherein G 1 comprises polyacrylate, polymethacrylate or polylactic acid; or
—(C 1 -C 8 )alkyl-G 2 -G 3 wherein G 2 is —C(═O)O— or a nitrogen heterocycle and G 3 comprises polystyrene, polyacrylate, polydimethylsiloxane, polyether, polymethacrylate, or polylactic acid;
R y is —(C 2 -C 6 )alkyl-OC(═O) G 1 wherein G 1 comprises polyacrylate, polymethacrylate or polylactic acid; or
—(C 1 -C 8 ) alkyl-G 2 -G 3 wherein G 2 is —C(═O)O— or a nitrogen heterocycle and G 3 comprises polystyrene, polyacrylate, polydimethylsiloxane, polyether, polymethacrylate, or polylactic acid;
R 1 is unbranched alkyl;
R 2 is branched alkyl;
each G is each independently CH 2 or C═O;
each J 1 is independently CH 2 , C═O, or O;
each J 2 is independently CH 2 , C═O, or O;
each Q is independently alkyl, cycloalkyl, heterocycloalkyl, carbonyl, silyl, aryl, or heteroaryl;
a and b are each independently 0 to about 1000; and
x and y are each independently 1 to about 1000;
wherein blocks a, b, x and y are in any order, the ratio of x:a is 1:0 to about 1:3, and the ratio of y:b is 1:0 to about 1:3; and
b) a second layer comprising a topcoat wherein the topcoat is an optical adhesive or ultraviolet curable resin;
wherein the first layer and second layer form a multilayer film and the multilayer coating comprises one or more multilayer films.
2. The multilayer coating of claim 1 wherein the a and the b are each independently 1 to about 300.
3. The multilayer coating of claim 1 wherein the x and the y are each independently 1 to about 300.
4. The multilayer coating of claim 1 wherein the ratio of x:a is about 1:0.5 to about 1:1.
5. The multilayer coating of claim 1 wherein the ratio of y:b is about 1:0.5 to about 1:1.
6. The multilayer coating of claim 1 wherein the BBCP has a number average molecular weight of about 500 kDa to about 3000 kDa.
7. The multilayer coating of claim 1 wherein the weight percent of the BBCP is about 50% to about 99.9%.
8. The multilayer coating of claim 1 wherein the photonic crystal film further comprises a polymer additive.
9. The multilayer coating of claim 1 wherein Formula IA is:
wherein Formula IB is:
wherein
R 3 and R 4 are each independently H or unbranched or branched —(C 1 -C 6 )alkyl; and
m and n are each independently 1 to about 100.
10. The multilayer coating of claim 9 wherein m and n are each independently 10 to about 50.
Assignments (2)
CONFIRMATORY LICENSE
Recorded Aug 31, 2023
From: COLORADO STATE UNIVERSITY RESEARCH FOUNDATION
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 064788/0452 →
ASSIGNMENT OF ASSIGNOR'S INTEREST
Recorded Dec 3, 2021
From: PEARSON, RYAN MICHAEL; RYAN, MATTHEW DAVID; MIYAKE, GARRET
To: COLORADO STATE UNIVERSITY RESEARCH FOUNDATION
Reel/Frame 058283/0661 →
Continuity (3)
Continuation In Part
PCTUS2020015928
· Jan 30, 2020
Provisional Application
62799945
· Feb 1, 2019
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