Blister-free polycrystalline silicon for solar cells
Described herein are methods of fabricating solar cells. In an example, a method of fabricating a solar cell includes forming an amorphous dielectric layer on the back surface of a substrate opposite a light-receiving surface of the substrate. The method also includes forming a microcrystalline silicon layer on the amorphous dielectric layer by plasma enhanced chemical vapor deposition (PECVD). The method also includes forming an amorphous silicon layer on the microcrystalline silicon layer by PECVD. The method also includes annealing the microcrystalline silicon layer and the amorphous silicon layer to form a homogeneous polycrystalline silicon layer from the microcrystalline silicon layer and the amorphous silicon layer. The method also includes forming an emitter region from the homogeneous polycrystalline silicon layer.
1. A back contact solar cell, comprising:
a substrate having a light-receiving surface and a back surface;
a first polycrystalline silicon emitter region of a first conductivity type on a first dielectric layer on the back surface of the substrate;
a second polycrystalline silicon emitter region of a second conductivity type, different from the first conductivity type, on a first portion of a second dielectric layer, the second dielectric layer having the first portion on the back surface of the substrate and having a second portion laterally directly between the first and second polycrystalline silicon emitter regions, wherein a portion of the second polycrystalline silicon emitter region is further over a portion of the first polycrystalline silicon emitter region;
a first conductive contact structure on the first polycrystalline silicon emitter region; and
a second conductive contact structure on the second polycrystalline silicon emitter region.
2. The back contact solar cell of claim 1 , wherein the second polycrystalline silicon emitter region is a blister-free polycrystalline silicon emitter region of the second conductivity type.
3. The back contact solar cell of claim 2 , wherein the first polycrystalline silicon emitter region is a blister-free polycrystalline silicon emitter region of the first conductivity type.
4. The back contact solar cell of claim 1 , further comprising:
an insulator layer on the first polycrystalline silicon emitter region, wherein the first conductive contact structure is through the insulator layer, and wherein a second portion of the second polycrystalline silicon emitter region overlaps the insulator layer but is separate from the first conductive contact structure.
5. The back contact solar cell of claim 1 , further comprising:
an insulator layer on the first polycrystalline silicon emitter region; and
a polycrystalline silicon layer of the second conductivity type on the insulator layer, wherein the first conductive contact structure is through the polycrystalline silicon layer of the second conductivity type and through the insulator layer.
6. The back contact solar cell of claim 1 , wherein the second polycrystalline silicon emitter region and the second dielectric layer are in a recess in the substrate.
7. The back contact solar cell of claim 6 , wherein the recess has a texturized surface.
8. The back contact solar cell of claim 1 , wherein the first polycrystalline silicon emitter region and the first dielectric layer are on a flat portion of the back surface of the substrate, and wherein the second polycrystalline silicon emitter region and the first portion of the second dielectric layer are on a texturized portion of the back surface of the substrate.
9. The back contact solar cell of claim 1 , wherein each of the first and second conductive contact structures comprise an aluminum-based metal seed layer on the first and second polycrystalline silicon emitter regions, respectively, and each of the first and second conductive contact structures further comprise a metal layer on the aluminum-based metal seed layer.
10. The back contact solar cell of claim 1 , wherein the first dielectric layer comprises silicon and oxygen.
11. The back contact solar cell of claim 1 , wherein the second dielectric layer comprises silicon and oxygen.
12. A back contact solar cell, comprising:
a substrate having a light-receiving surface and a back surface;
a first polycrystalline silicon emitter region of a first conductivity type on a first dielectric layer on the back surface of the substrate, wherein the first polycrystalline silicon emitter region is a blister-free polycrystalline silicon emitter region of the first conductivity type;
a second polycrystalline silicon emitter region of a second conductivity type, different from the first conductivity type, on a first portion of a second dielectric layer, the second dielectric layer having the first portion on the back surface of the substrate and having a second portion laterally directly between the first and second polycrystalline silicon emitter regions, wherein a portion of the second polycrystalline silicon emitter region is further over a portion of the first polycrystalline silicon emitter region;
a first conductive contact structure on the first polycrystalline silicon emitter region; and
a second conductive contact structure on the second polycrystalline silicon emitter region.
13. The back contact solar cell of claim 12 , further comprising:
an insulator layer on the first polycrystalline silicon emitter region, wherein the first conductive contact structure is through the insulator layer, and wherein a second portion of the second polycrystalline silicon emitter region overlaps the insulator layer but is separate from the first conductive contact structure.
14. The back contact solar cell of claim 12 , further comprising:
an insulator layer on the first polycrystalline silicon emitter region; and
a polycrystalline silicon layer of the second conductivity type on the insulator layer, wherein the first conductive contact structure is through the polycrystalline silicon layer of the second conductivity type and through the insulator layer.
15. The back contact solar cell of claim 12 , wherein the second polycrystalline silicon emitter region and the second dielectric layer are in a recess in the substrate.
16. The back contact solar cell of claim 15 , wherein the recess has a texturized surface.
17. The back contact solar cell of claim 15 , wherein the first polycrystalline silicon emitter region and the first dielectric layer are on a flat portion of the back surface of the substrate, and wherein the second polycrystalline silicon emitter region and the first portion of the second dielectric layer are on a texturized portion of the back surface of the substrate.
18. The back contact solar cell of claim 12 , wherein each of the first and second conductive contact structures comprise an aluminum-based metal seed layer on the first and second polycrystalline silicon emitter regions, respectively, and each the first and second conductive contact structures further comprise a metal layer on the aluminum-based metal seed layer.
19. The back contact solar cell of claim 12 , wherein the first dielectric layer comprises silicon and oxygen.
20. The back contact solar cell of claim 12 , wherein the second dielectric layer comprises silicon and oxygen.