Electrolytes for lithium batteries
The present invention relates generally to lithium batteries, and more specifically, to electrolyte compositions within lithium batteries. Some aspects of the invention are related to an electrolyte for a lithium battery. In some embodiments, the electrolyte comprises a lithium salt, an organic solvent, and an aromatic hydrocarbon solvent that is different from the organic solvent. The aromatic hydrocarbon solvent may have limited solubility in the organic solvent and/or a limited solubility for lithium salt, e.g., such that the aromatic hydrocarbon solvent is capable of inducing phase separation of the electrolyte when present in a certain amount. In one set of embodiments, an electrolyte comprising one or more aromatic hydrocarbon may lead to an enhanced battery cycle life, reduced rate of electrolyte degradation, and improved low temperature performance. The subject matter disclosed herein involves, in some cases, the use of the electrolyte in a lithium battery.
1. An electrolyte for a lithium battery, comprising:
a lithium salt;
an organic solvent comprising fluoroethylene carbonate at a concentration greater than 10% by weight of the electrolyte; and
an aromatic hydrocarbon solvent that is different from the organic solvent, wherein the aromatic hydrocarbon solvent has a formula (I):
wherein, R 1 and R 2 can be the same or different and each is independently selected from hydrogen; halogen; unsubstituted, branched or unbranched aliphatic; substituted or unsubstituted, branched or unbranched haloaliphatic; substituted or unsubstituted, branched or unbranched haloheteroaliphatic; substituted or unsubstituted aryl; substituted or unsubstituted haloaryl; substituted or unsubstituted haloheteroaryl; wherein R 1 and/or R 2 can be substituted, branched or unbranched aliphatic when R 1 and R 2 are different and are not hydrogen or a nitro group;
wherein n and m are integers from 0 to 6, with n+m≤6;
wherein the aromatic hydrocarbon solvent is present at an amount that deviates no more than 20 wt % with respect to a critical amount of aromatic hydrocarbon solvent in the electrolyte;
wherein the critical amount of aromatic hydrocarbon solvent in the electrolyte is an amount at which the electrolyte phase separates from a single liquid phase into at least two liquid phases.
2. An electrolyte as in claim 1 , wherein R 1 and/or R 2 is C 1 -C 10 alkyl.
3. An electrolyte as in claim 1 , wherein R 1 and/or R 2 is C 1 -C 10 haloalkyl.
4. An electrolyte as in claim 1 , wherein R 1 and/or R 2 comprises one or more of fluorine, bromine, chlorine, and iodine.
5. An electrolyte as in claim 1 , wherein R 1 and/or R 2 is an alkoxy group when R 1 and R 2 are different and are not hydrogen or a nitro group.
6. An electrolyte as in claim 1 , wherein the aromatic hydrocarbon solvent of formula (I) comprises one or more of benzene, fluorobenzene, tert-butylbenzene, toluene, α, α, α-trifluorotoluene, difluorobenzene, trifluorobenzene, tetrafluorobenzene, and fluorotoluene.
7. An electrolyte as in claim 1 , wherein the aromatic hydrocarbon solvent is present at an amount close to phase separation with the organic solvent.
8. An electrolyte as in claim 1 , wherein the aromatic hydrocarbon of formula (I) comprises a lithium salt solubility of less than or equal to 5 wt %.
9. An electrolyte as in claim 1 , wherein an increase in salt concentration during charge or discharge at a location adjacent the cathode or anode of an electrochemical cell results in a separation of the aromatic hydrocarbon solvent from the organic solvent at the location adjacent the cathode or anode.
10. An electrolyte for a lithium battery, comprising:
a lithium salt;
an organic solvent comprising a mixture of fluoroethylene carbonate and dimethyl carbonate; and
an aromatic hydrocarbon solvent that is different from the organic solvent, wherein the aromatic hydrocarbon solvent is present at an amount that deviates no more than 20 wt % with respect to a critical amount of aromatic hydrocarbon solvent in the electrolyte, and wherein the critical amount of aromatic hydrocarbon solvent in the electrolyte is an amount at which the electrolyte phase separates from a single liquid phase into at least two liquid phases.
11. An electrolyte as in claim 10 , wherein the organic solvent further comprises one or more of a carbonate-based solvent, a sulfone-based solvent, an ester of carboxylic acid, an ester of phosphoric acid, a linear or cyclic ether, and an acetal.
12. An electrolyte as in claim 11 , wherein the organic solvent further comprises the carbonate-based solvent, and the carbonate-based solvent comprises one or more of diethyl carbonate, ethyl methyl carbonate, propylene carbonate, and ethylene carbonate.
13. An electrolyte as in claim 10 , wherein the fluoroethylene carbonate is present in an amount of at least 10 wt % of a total weight of the electrolyte.
14. An electrolyte as in claim 10 , wherein the aromatic hydrocarbon solvent is present in an amount of at least 12 wt % of a total weight of the electrolyte.
15. An electrolyte as in claim 10 , wherein the organic solvent and the aromatic hydrocarbon has an organic solvent to the aromatic hydrocarbon solvent ratio of greater than or equal to 20 wt %:80 wt % and less than or equal to 99.5 wt %:0.5 wt %.
16. An electrolyte as in claim 10 , wherein the lithium salt comprises one or more of lithium hexafluorophosphate, lithium bis(fluorosulfonyl)imide, lithium perchlorate, lithium hexafluoroarsenate, lithium tetrafluoroborate, lithium trifluromethanesulfonate, and lithium bis(trifluoromethanesulfonyl)imide.
17. An electrolyte as in claim 10 , wherein the lithium salt has a solubility in the organic solvent that is at least 10 times the solubility in the aromatic hydrocarbon solvent.
18. An electrolyte as in claim 10 , wherein the organic solvent comprises fluoroethylene carbonate in an amount of at least 12 wt % of a total weight of the electrolyte.
19. An electrolyte as in claim 10 , wherein the aromatic hydrocarbon solvent is present at an amount that deviates no more than 10 wt % with respect to the critical amount of aromatic hydrocarbon solvent in the electrolyte.
20. An electrolyte as in claim 10 , wherein the aromatic hydrocarbon solvent is present at an amount that deviates no more than 5 wt % with respect to the critical amount of aromatic hydrocarbon solvent in the electrolyte.
21. An electrolyte for a lithium battery, comprising:
a lithium salt;
an organic solvent comprising fluoroethylene carbonate in an amount of at least 10 wt % of a total weight of the electrolyte; and
an aromatic hydrocarbon solvent that is different from the organic solvent, wherein the aromatic hydrocarbon solvent is present at an amount that deviates no more than 20 wt % with respect to a critical amount of aromatic hydrocarbon solvent in the electrolyte, and wherein the critical amount of aromatic hydrocarbon solvent in the electrolyte is an amount at which the electrolyte phase separates from a single liquid phase into at least two liquid phases.
22. An electrolyte as in claim 21 , wherein the aromatic hydrocarbon solvent is present in an amount of at least 12 wt % of a total weight of the electrolyte.