Electrodes, electrochemical cells, and methods of forming electrodes and electrochemical cells
Electrodes and methods of forming electrodes are described herein. The electrode can be an electrode of an electrochemical cell or battery. The electrode includes a current collector and a film in electrical communication with the current collector. The film may include a carbon phase that holds the film together. The electrode further includes an electrode attachment substance that adheres the film to the current collector.
1. An electrochemical cell comprising:
an electrode comprising an active material;
a separator; and
a cell attachment substance to adhere the electrode to the separator, wherein the electrode comprises a hard carbon phase to hold the active material together.
2. The electrochemical cell of claim 1 , wherein the hard carbon phase is amorphous.
3. The electrochemical cell of claim 1 , wherein the hard carbon phase is crystalline.
4. The electrochemical cell of claim 1 , wherein the hard carbon phase includes amorphous and crystalline carbon.
5. The electrochemical cell of claim 1 , wherein the hard carbon phase is a matrix phase in the cell attachment substance.
6. The electrochemical cell of claim 1 , wherein the cell attachment substance comprises one or more additives including silicon, the hard carbon phase embedded in pores of the one or more additives, wherein the amount of silicon in the cell attachment substance is greater than about 50% by weight.
7. The electrochemical cell of claim 6 , further comprising a silicon carbide layer between one or more silicon particles of the one or more additives and hard carbon.
8. The electrochemical cell of claim 1 , wherein an amount of hard carbon in the cell attachment substance includes about 10% to about 25% by weight.
9. The electrochemical cell of claim 8 , wherein the hard carbon reacts with the one or more additives to create a material at interfaces of the electrode.
10. The electrochemical cell of claim 1 , wherein the electrode comprises surfaces that are substantially free of the cell attachment substance.
11. The electrochemical cell of claim 1 , wherein the separator or the cell attachment substance comprises porosity.
12. An electrochemical cell comprising:
an electrode;
a separator; and
a cell attachment substance that adheres the electrode to the separator, wherein:
the electrode comprises porosity and at least about 60 percent of the porosity is substantially free of the cell attachment substance;
the electrode comprises an active material and a carbon phase holds the active material together, the carbon phase comprising hard carbon; and
the active material comprises silicon particles distributed within the carbon phase.
13. The electrochemical cell of claim 12 , wherein the cell attachment substance further comprises one or more conductive particles.
14. The electrochemical cell of claim 13 , wherein the one or more conductive particles are formed of metals or alloys including copper, nickel, or stainless steel.
15. The electrochemical cell of claim 13 , wherein the one or more conductive particles are formed of conductive carbon including carbon blacks, carbon fibers, carbon nanofibers, or carbon nanotubes.
16. The electrochemical cell of claim 12 , wherein the hard carbon phase is embedded in the pores of the silicon particles.
17. The electrochemical cell of claim 12 , wherein the hard carbon phase is substantially amorphous.
18. The electrochemical cell of claim 12 , wherein the hard carbon phase is substantially crystalline.
19. The electrochemical cell of claim 12 , wherein the hard carbon phase includes amorphous and crystalline carbon.
20. The electrochemical cell of claim 12 , wherein the hard carbon phase is a matrix phase in the cell attachment substance.
21. The electrochemical cell of claim 12 , wherein the active material can be cast onto a copper substrate to form a coating on the substrate.