Granted Patent B2

US 12,378,363 · App. 17/620,688 · Granted Aug 5, 2025

Inventors: Debo Hong (Shanghai, CN); Chong Xing (Shanghai, CN); Zhiting Liu (Shanghai, CN)

Assignee: DOW SILICONES CORPORATION

C08G77/44C08K5/549C08L83/10C08K2003/2227

Abstract

Claims (29)

1. A thermal conductive silicone composition comprising:

(A) 100 parts by mass of a liquid organopolysiloxane with a kinematic viscosity at 25° C. of 10 to 100,000 mm 2 /s, and having at least two silicon atom-bonded alkenyl groups with 2 to 12 carbon atoms per molecule;

(B) from 100 to 500 parts by mass of a thermal conductive filler, which is aluminum hydroxide with an average particle size of from 5 to 50 μm;

(C) from 10 to 100 parts by mass of a thermal conductive filler, which is aluminum hydroxide with an average particle size of at least 0.1 μm and less than 5 μm; and

(D) from 0.1 to 5 parts by mass of a carbasilatrane derivative represented by the following general formula:

wherein R 1 is an alkyl group with 1 to 6 carbon atoms or an alkoxy group with 1 to 3 carbon atoms, R 2 are the same or different hydrogen atoms or alkyl groups with 1 to 6 carbon atoms, and R 3 are the same or different and are selected from groups represented by the following general formulae:

—R 6 —SiR 4 a (OR 5 ) (3-a)

—R 7 —O—R 8

wherein R 4 is an alkyl group with 1 to 6 carbon atoms, R 5 is an alkyl group with 1 to 3 carbon atoms, R 6 is an alkylene group with 2 to 6 carbon atoms or an alkylenoxyalkylene group with 4 to 12 carbon atoms, R′ is an alkylene group with 2 to 6 carbon atoms, R 8 is an alkyl group with 1 to 6 carbon atoms, an alkenyl group with 2 to 6 carbon atoms or an acyl group with 2 to 6 carbon atoms, and “a” is 0, 1 or 2.

2. The thermal conductive silicone composition according to claim 1 , wherein component (B) is present in an amount of from about 150 to about 250 parts by mass.

3. The thermal conductive silicone composition according to claim 1 , wherein component (C) is present in an amount of from about 50 to about 100 parts by mass.

4. The thermal conductive silicone composition according to claim 1 , wherein components (B) and (C) are surface-treated with a surface treating agent in the presence of component (A), then component (D) is added to a mixture of components (A) to (C).

5. The thermal conductive silicone composition according to claim 4 , wherein the surface treating agent is selected from the group consisting of hexamethyldisilazane, tetramethyl divinyl disilazane, methyl trimethoxysilane, vinyl trimethoxysilane, and dichloro dimethylsilane.

6. The thermal conductive silicone composition according to claim 1 , wherein component (D) is a carbasilatrane derivative represented by the following formula:

7. The thermal conductive silicone composition according to claim 1 , further comprising:

(E) an organosiloxane having at least one silicon atom-bonded hydrogen atom per molecule, in an amount of from 1 to 30 parts by mass relative to 100 parts by mass of component (A).

8. The thermal conductive silicone composition according to claim 7 , further comprising:

(G) a liquid organosiloxane with a kinematic viscosity at 25° C. of 1 to 100 mm 2 /s, and free of an alkenyl group and a silicon atom-bonded hydrogen atom, in an amount of from 1 to 30 parts by mass per 100 parts by mass of component (A).

9. The thermal conductive silicone composition according to claim 1 , further comprising:

(F) a catalytic amount of a hydrosilylation reaction catalyst.

10. The thermal conductive silicone composition according to claim 9 , further comprising:

(G) a liquid organosiloxane with a kinematic viscosity at 25° C. of 1 to 100 mm 2 /s, and free of an alkenyl group and a silicon atom-bonded hydrogen atom, in an amount of from 1 to 30 parts by mass per 100 parts by mass of component (A).

11. The thermal conductive silicone composition according to claim 1 , further defined as a curable thermal conductive silicone composition comprising a part (I) and a part (II), wherein the curable thermal conductive silicone composition further comprises:

(E) from 1 to 30 parts by mass of an organosiloxane having at least one silicon atom-bonded hydrogen atom per molecule, to form part (I); and

(F) a catalytic amount of a hydrosilylation reaction catalyst, to form part (II); and

wherein each of components (A), (B), (C), and (D) is in part (I) and/or in part (II).

12. The curable thermal conductive silicone composition according to claim 11 , further comprising:

(G) a liquid organosiloxane with a kinematic viscosity at 25° C. of 1 to 100 mm 2 /s, and free of an alkenyl group and a silicon atom-bonded hydrogen atom, in an amount of from 1 to 30 parts by mass per 100 parts by mass of component (A);

wherein component (G) is in part (I) and/or in part (II).

Assignments (1)

Continuity (1)

References Cited (120)