Additive manufacturing of metal films
View Patent ↗Reflectors for concentrated solar power as well as systems and methods for additively manufacturing the reflectors is provided. The disclosed method can directly print metal films from an aqueous precursor solution onto a substrate with little to no post-fabrication treatment to achieve highly reflective surfaces with low surface roughness. The method provides precise control to form a metal film having an RMS surface roughness of about 2 to about 5 nm and a relative reflectivity of about 90% to about 96% at 550 nm on a substrate having an area of at least 1 square meter.
1. A method of forming a reflector for a concentrated solar power system, the method comprising:
forming a precursor solution comprising a liquid, a compound comprising a metal, and an organic binder;
irradiating the precursor solution with ultraviolet radiation to form a plurality of metal nanoparticles, wherein each of the plurality of metal nanoparticles comprises the metal and the organic binder; and
interconnecting the plurality of metal nanoparticles by the organic binder to form a metal film on a substrate, wherein the substrate has an area of at least 1 square meter and wherein the metal film comprises an RMS surface roughness of about 2 to about 5 nm and a relative reflectivity of about 90% to about 96% at 550 nm,
wherein the organic binder is polyallylamine.
2. The method of claim 1 , wherein the metal is silver, aluminum, platinum or mixtures thereof.
3. The method of claim 1 , wherein irradiating the precursor solution with ultraviolet radiation to form a plurality of metal nanoparticles comprises:
photo-initiating a reduction of the compound comprising the metal to form a plurality of metal ions; and
binding of a portion of the metal ions by the organic binder to form the metal nanoparticles.
4. The method of claim 1 , wherein the precursor solution further comprises a reducing agent.
5. The method of claim 4 , wherein the reducing agent comprises sodium citrate, and the metal is silver.
6. The method of claim 1 , further comprising depositing the metal film to cover an area of at least about 1 square meter.
7. The method of claim 1 , wherein interconnecting the plurality of metal nanoparticles by the organic binder to form the metal film on a substrate comprises one or more cycles of refreshing the precursor solution.
8. The method of claim 1 , further comprising extending an area of the metal film by using an array of light sources to form adjacent and connected areas of metal film on the substrate.
9. The method of claim 1 , further comprising extending an area of the metal film by moving a light source irradiating the precursor solution with ultraviolet radiation to form adjacent and connected areas of metal film on the substrate.
10. The method of claim 1 , further comprising forming a protective coating on the metal film, wherein the protective coating comprises a dielectric.
11. The method of claim 1 , further comprising, prior to irradiating the precursor solution with ultraviolet radiation to form a plurality of metal nanoparticles, depositing an adhesion film on the substrate to promote adhesion of the metal film to the substrate.