Chemical mechanical polishing pad
View Patent ↗A chemical mechanical polishing pad is provided containing a polishing layer having a polishing surface, wherein the polishing layer comprises a reaction product of ingredients, including: an isocyanate terminated urethane prepolymer; and, a curative system, containing a high molecular weight polyol curative; and, a difunctional curative.
1 . A chemical mechanical polishing pad adapted for polishing a substrate selected from the group consisting of at least one of a magnetic substrate, an optical substrate and a semiconductor substrate, comprising:
a polishing layer adapted for polishing a substrate selected from the group consisting of at least one of a magnetic substrate, an optical substrate and a semiconductor substrate having a polishing surface, wherein the polishing layer comprises a reaction product of ingredients, comprising:
an isocyanate terminated urethane prepolymer having 8.75 to 9.25 wt % unreacted NCO groups; and,
a curative system consisting essentially of:
20 to 60 wt % of a high molecular weight polyol curative, wherein the high molecular weight polyol curative has a number average molecular weight, M N , of 10,000 to 12,000; and wherein the high molecular weight polyol curative has an average of 6 hydroxyl groups per molecule and a hydroxyl number (mg KOH/g) of about 30; and,
40 to 80 wt % of a difunctional curative wherein the polishing layer exhibits a density of greater than 0.6 g/cm 3 and the polishing layer includes polymeric microballoons having shell walls and a weight average diameter of 10 to 50 μm and wherein the polishing layer has an elongation to break of 125 to 300% as measured according to ASTM D412.
2 . The chemical mechanical polishing pad of claim 1 , wherein the curative system has a plurality of reactive hydrogen groups and the isocyanate terminated urethane prepolymer has a plurality of unreacted NCO groups; and wherein a stoichiometric ratio of the reactive hydrogen groups to the unreacted NCO groups is 0.85 to 1.15.
3 . The chemical mechanical polishing pad of claim 1 , wherein the isocyanate terminated urethane prepolymer has 8.95 to 9.25 wt % unreacted NCO groups.
4 . The chemical mechanical polishing pad of claim 1 , wherein the polishing surface has a groove pattern formed therein.
5 . The chemical mechanical polishing pad of claim 1 , wherein the M N of the high molecular weight polyol curative is about 11,400.