Metal bodies and method for production thereof
The present invention relates to methods for producing coated metal bodies by applying a metal powder composition to a metal body, such that a coated metal body is obtained, the coating of which contains one or more wax components; heating the coated metal body to the melting temperature of at least one of the wax components and subsequent cooling to room temperature, such that a coated metal body is obtained; and thermally treating the coated metal body in order to achieve alloy formation between metal portions of metal body and metal powder composition, wherein the metal body comprises nickel, cobalt, copper and/or iron and the metal powder composition comprises a metal component in powder form, which contains aluminium, silicon or magnesium in elemental or alloyed form. By melting and cooling the wax, the method makes metal bodies having a more uniform alloy coverage accessible. The invention furthermore relates to methods wherein the metal body is subsequently treated with a basic solution. The present invention additionally comprises the metal bodies obtainable by the method according to the invention, which find application as load-bearing and structural components, for example, and in catalyst converter technology.
1 . A process for producing coated metal bodies, comprising the following steps:
(a) applying a metal powder composition comprising one or more wax components to a metal body so as to obtain a coated metal body 1, the coating of which contains one or more wax components;
(b) heating the coated metal body 1 up to the melting temperature of at least one of the wax components and then cooling it down to room temperature so as to obtain a coated metal body 2;
(c) treating the coated metal body 2 thermally in order to form an alloy between metallic components of the metal body and the metal powder composition, so as to obtain metal body 3;
wherein the metal body used in step (a) comprises a metal component selected from the group consisting of: nickel, cobalt, copper, and iron;
wherein the metal powder composition used in step (a) comprises a pulverulent metal component containing aluminum, silicon or magnesium in elemental or alloyed form; and
wherein a wax component is a substance or a substance mixture which:
(i) is firm and kneadable at 20° C., and
(ii) melts without decomposition in the temperature region of 40° C., and
(iii) can be converted fully to gaseous products by thermolysis within the temperature range from 100 to 400° C.
2 . The process of claim 1 , wherein the metal body used in step (a) is a metal foam body.
3 . The process of claim 2 , wherein the metal body used in step (a) consists of one of the following:
metallic nickel;
metallic
cobalt;
metallic
copper;
alloy of nickel and
cobalt; alloy of
nickel and copper;
arrangements of two superposed layers of two individual metallic components, in which one of the metallic components forms an inner layer of the metal body and the other metallic component forms an outer layer of the metal body, wherein the metallic components are selected from the following combinations: nickel on the inside and cobalt on the outside; iron on the inside and nickel on the outside.
4 . The process of claim 3 , wherein the metal body used in step (a) consists of a metal selected from the following group: Ni, Fe, Co and Cu.
5 . The process of claim 4 , wherein the metal powder composition used in step (a) of the process comprises one or more pulverulent metal components selected from the group consisting of: aluminum, silicon, magnesium, alloys of aluminum and chromium, alloys of aluminum and molybdenum, alloys of aluminum and copper, alloys of aluminum and iron, alloys of aluminum and iron and chromium, alloys of aluminum and titanium, alloys of aluminum and molybdenum and titanium, alloys of silicon and chromium, alloys of silicon and molybdenum, alloys of silicon and copper, alloys of silicon and iron, alloys of silicon and iron and chromium, alloys of silicon and titanium, alloys of silicon and molybdenum and titanium, alloys of magnesium and chromium, alloys of magnesium and molybdenum, alloys of magnesium and copper, alloys of magnesium and iron, alloys of magnesium and iron and chromium, alloys of magnesium and titanium, alloys of magnesium and molybdenum and titanium.
6 . The process of claim 5 , wherein the metal powder composition used in step (a) consists of pulverulent aluminum and one or more pulverulent wax components.
7 . The process of claim 6 , wherein at least one of the wax components in the coating of the coated metal body 1 obtained in step (a) has a solidification temperature in the range from 45 to 160° C.
8 . The process of claim 7 , wherein one or more wax components are added to the metal powder composition used in step (a).
9 . The process of claim 3 , further comprising:
(d) treating the metal body 3 with a basic solution.
10 . The process of claim 9 , wherein the treatment of metal body 3 with a basic solution is performed for a period of from 5 minutes to 8 hours at a temperature of from 20 to 120° C., and wherein the basic solution is an aqueous NaOH solution having an NaOH concentration between 2% and 30% by weight.
11 . The process of claim 1 , wherein the metal body used in step (a) consists of one of the following:
metallic
nickel;
metallic
cobalt;
metallic
copper;
alloy of nickel and
cobalt; alloy of
nickel and copper;
arrangements of two superposed layers of two individual metallic components, in which one of the metallic components forms an inner layer of the metal body and the other metallic component forms an outer layer of the metal body, wherein the metallic components are selected from the following combinations: nickel on the inside and cobalt on the outside; iron on the inside and nickel on the outside.
12 . The process of claim 1 , wherein the metal body used in step (a) consists of a metal selected from the group consisting of: Ni, Fe, Co, and Cu.
13 . The process of claim 1 , wherein the metal powder composition used in step (a) of the process comprises one or more pulverulent metal components selected from the group consisting of: aluminum, silicon, magnesium, alloys of aluminum and chromium, alloys of aluminum and molybdenum, alloys of aluminum and copper, alloys of aluminum and iron, alloys of aluminum and iron and chromium, alloys of aluminum and titanium, alloys of aluminum and molybdenum and titanium, alloys of silicon and chromium, alloys of silicon and molybdenum, alloys of silicon and copper, alloys of silicon and iron, alloys of silicon and iron and chromium, alloys of silicon and titanium, alloys of silicon and molybdenum and titanium, alloys of magnesium and chromium, alloys of magnesium and molybdenum, alloys of magnesium and copper, alloys of magnesium and iron, alloys of magnesium and iron and chromium, alloys of magnesium and titanium, alloys of magnesium and molybdenum and titanium.
14 . The process of claim 1 , wherein the metal powder composition used in step (a) consists of pulverulent aluminum and one or more pulverulent wax components.
15 . The process of claim 1 , wherein at least one of the wax components in the coating of the coated metal body 1 obtained in step (a) has a solidification temperature in the range from 45 to 160° C.
16 . The process of claim 1 , wherein one or more wax components are added to the metal powder composition used in step (a).
17 . The process of claim 1 , further comprising:
(d) treating the metal body 3 with a basic solution.
18 . The process of claim 17 , wherein the treatment of metal body 3 with a basic solution is performed for a period of from 5 minutes to 8 hours at a temperature of from 20 to 120° C., and wherein the basic solution is an aqueous NaOH solution having an NaOH concentration between 2% and 30% by weight.
19 . A coated metal body produced by the process of claim 17 , wherein the metal body used in step (a) is a metal foam body, wherein a standard deviation of a powder foam ratio (PFR) of at least 36 circular cutouts of the metal body 3 having a diameter of 30 mm is less or equal to 0.7.
20 . A coated metal body produced by the process of claim 1 , wherein the metal body used in step (a) is a metal foam body, wherein a standard deviation of a powder foam ratio (PFR) of at least 36 circular cutouts of the metal body 3 having a diameter of 30 mm is less or equal to 0.7.