Surface modification of silicon particles for electrochemical storage
Silicon particles for active materials and electro-chemical cells are provided. The active materials comprising silicon particles described herein can be utilized as an electrode material for a battery. In certain embodiments, the composite material includes greater than 0% and less than about 90% by weight silicon particles, the silicon particles having an average particle size between about 10 nm and about 40 μm, wherein the silicon particles have surface coatings comprising silicon carbide or a mixture of carbon and silicon carbide, and greater than 0% and less than about 90% by weight of one or more types of carbon phases, wherein at least one of the one or more types of carbon phases is a substantially continuous phase.
1. A composite material having hard carbon as a matrix phase comprising:
a precursor and silicon particles, wherein:
said silicon particles comprise a surface layer including silicon monoxide (SiO), silicon dioxide (SiO 2 ), or silicon oxide (SiO x );
said precursor is pyrolyzed to convert the precursor into one or more types of carbon phases; and
one of the one or more types of carbon phases are reacted with the silicon monoxide (SiO), silicon dioxide (SiO 2 ), or silicon oxide (SiO x ) to form surface coatings comprising a mixture of carbon and silicon carbide on the silicon particles; and
where the composite material is a continuous phase having said silicon carbide located between the silicon particles and the hard carbon.
2. The composite material of claim 1 , wherein an average particle size of the silicon particles is from about 0.1 μm to about 30 μm.
3. The composite material of claim 1 , wherein the silicon particles are from about 90% pure silicon to about 100% pure silicon.
4. The composite material of claim 1 , wherein the surface layer is a substantially continuous layer.
5. The composite material of claim 1 , wherein the composite material is self-supported.
6. The composite material of claim 1 , wherein the at least one of the one or more types of carbon phases is a continuous phase that is electrochemically active and electrically conductive.
7. The composite material of claim 1 , wherein pyrolyzing the precursor comprises heating the mixture to a temperature of about 750° C. to about 1300° C.
8. The composite material of claim 7 , wherein pyrolyzing the precursor comprises heating the mixture to a temperature of about 800° C. to about 1200° C.
9. The composite material of claim 8 , wherein pyrolyzing the precursor comprises heating the mixture to a temperature of about 1175° C.
10. A lithium-ion battery electrode comprising the composite material of claim 1 .