IP Library › Granted Patent US 12,606,659
Granted Patent B2
US 12,606,659 · App. 18/000,220 · Granted Apr 21, 2026

Single reactor bimodal polyethylene with improved modulus for extrusion blow molding drum applications

Inventors: Bo Liu (Pearland, TX); Shadid Askar (Houston, TX); Joel D. Wieliczko (Charleston, WV); Mridula Kapur (Lake Jackson, TX)
Assignee: Univation Technologies, LLC
C08F210/16C08F2/34C08F4/65912C08L23/0815C08F2500/05C08F2500/07C08F2500/12C08F2500/13C08L2205/02C08L2207/062
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Quick Facts
Patent No.
US 12,606,659
App. No.
18/000,220
Granted
Apr 21, 2026
Kind
B2
Abstract

In various embodiments, a bimodal polyethylene composition may have a density (ρ) from 0.952 g/cm 3 to 0.957 g/cm 3 , a high load melt index (I 21 ) from 1 to 10 dg/min, and a z-average molecular weight (M z(GPC) ) from 3,200,000 to 5,000,000 g/mol. The bimodal polyethylene composition may also have a peak molecular weight (M p(GPC) ) defined by the equation: M p(GPC) <−2,805.3 MWD+102,688, wherein MWD is a molecular weight distribution defined by the equation: MWD=M w(GPC) /M n(GPC) , M w(GPC) is a weight average molecular weight of the bimodal polyethylene composition, M n(GPC ) is a number average molecular weight of the bimodal polyethylene composition. Additionally, the bimodal polyethylene composition has a ratio of the (Mz(GPC)) to the Mw(GPC) from 8.5 to 10.5. Articles made from the bimodal polyethylene composition, such as articles made by blow molding processes, are also provided.

Claims (41)

1 . A bimodal polyethylene composition having:

a density (ρ) from 0.952 g/cm 3 to 0.957 g/cm 3 when measured according to ASTM D792-08, Method B;

a high load melt index (I 21 ) from 1.0 to 10 dg/min when measured according to ASTM D1238 at 190° C. and a 21.6 kg load;

a peak molecular weight (M p(GPC) ) defined by the equation: M p(GPC) <−2,805.3×MWD+102,688, wherein MWD is a molecular weight distribution defined by the equation: MWD=M w(GPC) /M n(GPC) , M w(GPC) is a weight average molecular weight of the bimodal polymer composition, and M n(GPC) is a number average molecular weight of the bimodal polymer composition, and wherein M p(GPC) , M w(GPC) , and M n(GPC) are measured using gel permeation chromatography (GPC), wherein the M n(GPC) is greater than 28,000 g/mol;

a z-average molecular weight (M z(GPC) ) greater than 3,200,000 and less than or equal to 5,000,000 g/mol as measured using GPC; and

a ratio of the (M z(GPC) ) to the M w(GPC) is from 8.5 to 10.5;

wherein the M p(GPC) is from 55,000 g/mol to 65,000 g/mol; and

wherein the bimodal polyethylene composition is a polymerized reaction product of an ethylene monomer and at least one C3-C12 α-olefin comonomer.

2 . The bimodal polyethylene composition of claim 1 , wherein the M w(GPC) is greater than 380,000 g/mol.

3 . The bimodal polyethylene composition of claim 1 having:

a secant modulus(E s ) defined by the equation: E s >−2,622+2,822×ρ+2.5×MFR 5 , wherein MFR 5 is a ratio of the high load melt index (I 21 ) to a melt index (I 5 ) of the bimodal polyethylene composition measured according to ASTM D1238 at 190° C. and a 5.0 kg load;

a secant modulus (E s ) defined by the equation: E s >−4,570.6+4,883×ρ+3.1×MWD;

or both.

4 . The bimodal polyethylene composition of claim 1 , wherein the M w(GPC) is from 380,000 g/mol to 500,000 g/mol.

5 . The bimodal polyethylene composition of claim 1 , wherein MFR 5 is from 20 to 32, wherein MFR 5 is a ratio of the high load melt index (I 21 ) to a melt index (I 5 ) of the bimodal polyethylene composition measured according to ASTM D1238 at 190° C. and a 5.0 kg load.

6 . The bimodal polyethylene composition of claim 1 , wherein the M n(GPC) is from greater than 28,000 g/mol and less than or equal to 40,000 g/mol.

7 . The bimodal polyethylene composition of claim 1 , wherein a secant modulus (E s ) of the bimodal polyethylene composition is greater than 965 MPa.

8 . The bimodal polyethylene composition of claim 1 , having an environmental stress-cracking resistance F 50 greater than 150 hours when measured according to ASTM D1693, Procedure B, 10% Igepal.

9 . An article manufactured using the bimodal polyethylene composition of claim 1 .

10 . The article of claim 9 , wherein the article is a blow molded article.

11 . A method for producing the bimodal polyethylene composition of claim 1 , comprising polymerizing via gas-phase polymerization ethylene and at least one C 3 -C 12 α-olefin comonomer in the presence of a main catalyst and a trim catalyst in a single reactor to produce the bimodal polyethylene composition.

12 . A bimodal polyethylene composition having:

a density (ρ) from 0.952 g/cm 3 to 0.957 g/cm 3 when measured according to ASTM D792-08, Method B;

a high load melt index (I 21 ) from 1.0 to 10 dg/min when measured according to ASTM D1238 at 190° C. and a 21.6 kg load;

a peak molecular weight (M p(GPC) ) defined by the equation: M p(GPC) <−2,805.3×MWD+102,688, wherein MWD is a molecular weight distribution defined by the equation: MWD=M w(GPC) /M n(GPC) , M w(GPC) is a weight average molecular weight of the bimodal polymer composition, and M n(GPC) is a number average molecular weight of the bimodal polymer composition, and wherein M p(GPC) , M w(GPC) , and M n(GPC) are measured using gel permeation chromatography (GPC), wherein the M n(GPC) is greater than 28,000 g/mol

a z-average molecular weight (M z(GPC) ) greater than 3,200,000 and less than or equal to 5,000,000 g/mol as measured using GPC;

a ratio of the (M z(GPC) ) to the M w(GPC) is from 8.5 to 10.5;

a secant modulus (E s ) defined by the equation: E s >−2,622+2,822×ρ+2.5×MFR 5 , wherein MFR 5 is a ratio of the high load melt index (I 21 ) to a melt index (I 5 ) of the bimodal polyethylene composition measured according to ASTM D1238 at 190° C. and a 5.0 kg load;

a secant modulus (E s ) defined by the equation: E s >−4,570.6+4,883×ρ+3.1×MWD;

or both.

13 . The bimodal polyethylene composition of claim 12 , wherein the M p(GPC) is from 55,000 g/mol to 65,000 g/mol.

14 . The bimodal polyethylene composition of claim 12 , wherein the M w(GPC) is greater than 380,000 g/mol.

15 . A bimodal polyethylene composition having:

a density (ρ) from 0.952 g/cm 3 to 0.957 g/cm 3 when measured according to ASTM D792-08, Method B;

a high load melt index (I 21 ) from 1.0 to 10 dg/min when measured according to ASTM D1238 at 190° C. and a 21.6 kg load;

a peak molecular weight (M p(GPC) ) defined by the equation: M p(GPC) <−2,805.3×MWD+102,688, wherein MWD is a molecular weight distribution defined by the equation: MWD=M w(GPC) /M n(GPC) , M w(GPC) is a weight average molecular weight of the bimodal polymer composition, and M n(GPC) is a number average molecular weight of the bimodal polymer composition, and wherein M p(GPC) , M w(GPC) , and M n(GPC) are measured using gel permeation chromatography (GPC), wherein the M n(GPC) is greater than 28,000 g/mol

a z-average molecular weight (M z(GPC) ) greater than 3,200,000 and less than or equal to 5,000,000 g/mol as measured using GPC; and

a ratio of the (M z(GPC) ) to the M w(GPC) is from 8.5 to 10.5;

wherein a secant modulus (E s ) of the bimodal polyethylene composition is greater than 965 MPa.

16 . The bimodal polyethylene composition of claim 15 , wherein the bimodal polyethylene composition is a polymerized reaction product of an ethylene monomer and at least one C3-C12 α-olefin comonomer.

17 . The bimodal polyethylene composition of claim 15 , wherein the M w(GPC) is from 380,000 g/mol to 500,000 g/mol.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 5, 2022
From: DOW GLOBAL TECHNOLOGIES LLC
To: UNIVATION TECHNOLOGIES, LLC
Reel/Frame 061977/0228 →
Continuity (2)
Provisional Application 63031712 · May 29, 2020
Related Publication 20230192920A1 · Jun 22, 2023
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