Process for producing alkali taurinate
There is disclosed a process for producing taurine in a molar yield of at least 80% from alkali isethionate, alkali ditaurinate, or alkali tritaurinate by adding excess ammonia and at least of equal molar amount of an alkali hydroxide to a solution comprised of alkali ditaurinate, alkali tritaurinate, or their mixture and subjecting the solution to an ammonolysis to yield a solution comprised of alkali taurinate.
1. A process for producing alkali taurinate from alkali isethionate in a molar yield of at least 80% on the basis of alkali isethionate in more than one vessel, comprising:
(a) adding alkali hydroxide and excess ammonia to a solution comprised of alkali isethionate and alkali ditaurinate; wherein the molar amount of alkali hydroxide is at least equal to the molar amount of total taurinates comprising alkali ditaurinate in the solution; and wherein the alkali is lithium, sodium, potassium, or a mixture thereof;
(b) subjecting the solution of step (a) to an ammonolysis; and
(c) evaporating excess ammonia from the solution of step (b) to obtain a solution comprising alkali taurinate.
2. The process of claim 1 , wherein the solution comprised of alkali isethionate and alkali ditaurinate is comprised of the mother liquor solution produced from alkali isethionate in a process comprising the steps of:
(1) adding alkali hydroxide and excess ammonia to a solution comprised of alkali isethionate; wherein the alkali is lithium, sodium, potassium, or a mixture thereof;
(2) subjecting the solution of step (1) to an ammonolysis;
(3) removing excess ammonia from the solution of step (2) to obtain a solution comprising alkali taurinate;
(4) converting the alkali taurinate of step (3) to taurine; and
(5) isolating the taurine of step (4) to form a mother liquor solution.
3. The process of claim 2 , wherein the mother liquor solution is comprised of alkali isethionate and alkali ditaurinate.
4. The process according to claim 2 , wherein the mother liquor solution is comprised of alkali isethionate and residual taurine.
5. The process according to claim 2 , wherein the mother liquor solution is comprised of alkali isethionate, alkali ditaurinate, and alkali tritaurinate.
6. The process according to claim 1 , wherein the excess ammonia is evaporated and reclaimed for reuse.
7. The process according to claim 1 , wherein the alkali hydroxide is added to the solution comprised of alkali isethionate and alkali ditaurinate to a pH of at least 10.
8. The process according to claim 1 , wherein a process for producing taurine further comprises the step of:
(d) converting the alkali taurinate in the solution of step (c) to taurine.
9. The process according to claim 8 , wherein the alkali taurinate is converted to taurine by reacting with an acid, which is selected from the group consisting of sulfuric acid, hydrochloric acid, nitric acid, phosphoric acid, hydrobromic acid, and a mixture thereof.
10. The process according to claim 8 , wherein the alkali taurinate is converted to taurine by reacting with an ion exchange resin.
11. The process according to claim 1 , wherein the taurinates are selected from the group consisting of taurine, alkali ditaurinate, alkali tritaurinate, and a mixture thereof.
12. The process of claim 1 , wherein the solution comprised of alkali isethionate and ditaurinate is the mother liquor solution produced in a process comprising the steps of:
(1) adding excess ammonia to a solution comprised of alkali isethionate; wherein the alkali is lithium, sodium, potassium, or a mixture thereof;
(2) subjecting the solution of step (1) to an ammonolysis and removing excess ammonia to obtain a solution comprising alkali taurinate;
(3) converting the alkali taurinate of step (2) to taurine; and
(4) isolating the taurine of step (3) to form a mother liquor solution.
13. The process according to claim 12 , wherein the mother liquor solution is comprised of alkali ditaurinate.
14. The process according to claim 12 , wherein the mother liquor solution is comprised of alkali isethionate and alkali ditaurinate.
15. The process according to claim 12 , wherein the mother liquor solution is comprised of alkali tritaurinate.