Granted Patent B2

US 12,272,764 · App. 18/152,452 · Granted Apr 8, 2025

Inventors: Petar Atanackovic (Henley Beach South, AU); Matthew Godfrey (Sydney, AU)

Assignee: Silanna UV Technologies Pte Ltd

H01L33/06H01L21/02381H01L21/02389H01L21/0242H01L21/02458H01L21/02472H01L21/02483H01L21/02507H01L21/0251H01L21/0254H01L21/02554H01L21/02565H01L27/15H01L33/007H01L33/10H01L33/14H01L33/16H01L33/18H01L33/32

Abstract

Claims (42)

1. A semiconductor structure comprising:

a growth axis;

a first layer consisting of a single layer, wherein the single layer comprises:

a first semiconductor comprising a polar crystal structure with a spontaneous polarization axis that is parallel to the growth axis; and

a monotonic change in composition from a wider band gap (WBG) material to a narrower band gap (NBG) material or from a NBG material to a WBG material along the growth axis, wherein the monotonic change in composition comprises a continuous change in composition along the growth axis;

wherein the monotonic change in composition induces p-type or n-type conductivity in the first layer; and

a second layer comprising a second semiconductor with the polar crystal structure, wherein there is no abrupt change in polarization at an interface between the first layer and the second layer;

wherein the monotonic change in composition is the only monotonic change in composition in the semiconductor structure, and

wherein the first semiconductor is selected from:

aluminium gallium nitride (Al x Ga 1-x N) where 0≤x≤1;

boron aluminium nitride B x Al 1-x N where 0≤x≤1;

aluminium gallium indium nitride (Al x Ga y In 1-x-y N) where 0≤x≤1, 0≤y≤1 and 0≤(x+y)≤1; and

magnesium zinc oxide (Mg x Zn 1-x O) where 0≤x≤1.

2. The semiconductor structure of claim 1 , wherein the first semiconductor comprises a cation-polar orientation with respect to the growth axis that is a metal-polar orientation with respect to the growth axis.

3. The semiconductor structure of claim 1 , wherein the first semiconductor comprises an anion-polar orientation with respect to the growth axis that is either a nitrogen-polar orientation with respect to the growth axis or an oxygen-polar orientation with respect to the growth axis.

4. The semiconductor structure of claim 1 , wherein the first layer comprises the p-type conductivity, wherein the first semiconductor comprises a cation-polar orientation with respect to the growth axis, and wherein the monotonic change in composition changes monotonically from a composition corresponding to the wider band gap (WBG) material to a composition corresponding to the narrower band gap (NBG) material along the growth axis.

5. The semiconductor structure of claim 1 , wherein the first layer comprises the p-type conductivity, wherein the first semiconductor comprises an anion-polar orientation with respect to the growth axis, and wherein the monotonic change in composition changes monotonically from a composition corresponding to the narrower band gap (NBG) material to a composition corresponding to the wider band gap (WBG) material along the growth axis.

6. The semiconductor structure of claim 1 , wherein the first layer comprises the n-type conductivity, wherein the first semiconductor comprises an anion-polar orientation with respect to the growth axis, and wherein the monotonic change in composition changes monotonically from a composition corresponding to the wider band gap (WBG) material to a composition corresponding to the narrower band gap (NBG) material along the growth axis.

7. The semiconductor structure of claim 1 , wherein the first layer comprises the n-type conductivity, wherein the first semiconductor comprises a cation-polar orientation with respect to the growth axis, and wherein the monotonic change in composition changes monotonically from a composition corresponding to the narrower band gap (NBG) material to a composition corresponding to the wider band gap (WBG) material along the growth axis.

8. The semiconductor structure of claim 1 , wherein the second semiconductor is selected from:

gallium nitride (GaN);

aluminium nitride (AlN);

aluminium gallium nitride (Al x Ga 1-x N) where 0≤x≤1;

boron aluminium nitride B x Al 1-x N where 0≤x≤1; and

aluminium gallium indium nitride (Al x Ga y In 1-x-y N) where 0≤x≤1, 0≤y≤1 and 0≤(x+y)≤1.

9. The semiconductor structure of claim 1 , wherein the second semiconductor is selected from:

magnesium oxide (MgO);

zinc oxide (ZnO); and

magnesium zinc oxide (Mg x Zn 1-x O) where 0≤x≤1.

10. The semiconductor structure of claim 1 , wherein the first semiconductor or the second semiconductor comprises a group-III metal nitride.

11. The semiconductor structure of claim 1 , wherein the polar crystal structure comprises a wurtzite crystal structure.

12. The semiconductor structure of claim 1 , wherein the composition of the first semiconductor comprises:

at least two types of metal atom cations; and

a non-metal atom anion comprising nitrogen or oxygen.

13. The semiconductor structure of claim 12 , wherein the monotonic change in composition of the first semiconductor comprises a changing molar fraction of one or more of the at least two types of metal atom cations in the composition of the first semiconductor along the growth axis.

14. The semiconductor structure of claim 1 , wherein the first semiconductor further comprises impurity dopants to enhance the induced p-type or n-type conductivity.

15. The semiconductor structure of claim 1 , further comprising:

a substrate; and

a buffer or dislocation filter layer located between the substrate and the first layer, wherein the buffer or dislocation filter layer comprises a bulk-like semiconductor or a semiconductor superlattice.

16. The semiconductor structure of claim 15 , wherein the substrate is a sapphire (Al 2 O 3 ) substrate, an aluminium nitride (AlN) substrate, a silicon substrate, or a gallium nitride (GaN) substrate.

17. The semiconductor structure of claim 15 , wherein the second semiconductor comprises a p-type or n-type conductivity.

18. A light emitting diode (LED) comprising the semiconductor structure of claim 1 .

Assignments (3)

Priority Claims (1)

Continuity (8)

References Cited (282)