IP Library Granted Patent US 12,466,998
Granted Patent B2
US 12,466,998 · App. 18/434,280 · Granted Nov 11, 2025

Scintillation compound including a rare earth element and a process of forming the same

Inventors: Samuel Blahuta (Besancon, FR); Eric E. Mattmann (Paris, FR); Damien Pauwels (Mandelieu, FR); Bruno Viana (Montgeron, FR)
Assignee: Luxium Solutions, LLC
C09K11/77742C09K11/77744C09K11/7792G01T1/20185G01T1/2023
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Quick Facts
Patent No.
US 12,466,998
App. No.
18/434,280
Granted
Nov 11, 2025
Kind
B2
Abstract

A scintillation compound can include a rare earth silicate. The rare-earth silicate may be lutetium yttrium orthosilicate. The rare-earth silicate may be doped with Ce. The rare-earth silicate doped with Ce may include a rare-earth element in a tetravalent state at a concentration of at least approximately 10 ppm atomic of the scintillation compound.

Claims (12)

1 . A scintillation compound comprising a rare-earth silicate, wherein the rare-earth silicate is lutetium yttrium orthosilicate, the rare-earth silicate is doped with Ce, and the Ce is in a tetravalent state at a concentration of at least approximately 10 ppm atomic of the scintillation compound.

2 . The scintillation compound of claim 1 , wherein an absorbance of the scintillation material at a wavelength of 357 nm is less than an absorbance of the scintillation material at 280 nm.

3 . The scintillation compound of claim 1 , wherein the scintillation compound is used within a radiation detection apparatus, a positron emission tomography scanner, a laser device, or an optical storage device.

4 . The scintillation compound of claim 1 , wherein the scintillation compound has an afterglow of less than 200 ppm after 100 ms relative to the intensity measured during an X-ray irradiation.

5 . The scintillation compound of claim 1 , wherein the rare earth element in the tetravalent state is at a concentration no greater than approximately 5000 ppm atomic in the scintil-lation compound.

6 . The scintillation compound of claim 1 , wherein the rare earth element in a tetravalent state is at a concentration no greater than approximately 500 ppm atomic of the scintillation compound.

7 . The scintillation compound of claim 4 , wherein cerium representing 0.005 mol % to 20 mol % of all the rare earths included in the scintillation compound.

8 . The scintillation compound of claim 7 , wherein the scintillation compound is codoped with a divalent alkaline earth M or a trivalent metal M′.

9 . The scintillation compound of claim 8 , wherein the mass of codopant in the scintillation compound is less than the mass of cerium in the scintillation compound.

10 . The scintillation compound of claim 8 , wherein M is selected from the group consisting of Ca, Mg, Sr, and Ba.

11 . The scintillation compound of claim 1 , wherein the scintillation compound has an energy resolution of 8.9%.

12 . A scintillation compound comprising a rare earth element in a tetravalent state at a concentration of at least approximately 10 ppm atomic of the scintillation compound, wherein the scintillation compound is a rare earth silicate compound and the rare earth silicate compound is lutetium yttrium orthosilicate.

Assignments (1)
INTELLECTUAL PROPERTY SECURITY AGREEMENT SUPPLEMENT Recorded May 8, 2026
From: LUXIUM SOLUTIONS, LLC
To: GOLUB CAPITAL MARKETS LLC, AS COLLATERAL AGENT
Reel/Frame 075574/0443 →
Priority Claims (3)
FR 1059394 · Nov 16, 2010 · national
FR 1158466 · Sep 22, 2011 · national
FR 1158467 · Sep 22, 2011 · national
Continuity (9)
Continuation 17664634 · May 23, 2022
Continuation 17128297 · Dec 21, 2020
Continuation 15833774 · Dec 6, 2017
Continuation 14856159 · Sep 16, 2015
Continuation 13885966
Continuation In Part 12977947 · Dec 23, 2010
Provisional Application 61540326 · Sep 28, 2011
Provisional Application 61540339 · Sep 28, 2011
Related Publication 20240174923A1 · May 30, 2024
References Cited (186)
US 4017294A · Sanford et al. · 1977 [cited by applicant]
US 4518546A · Greskovich et al. · 1985 [cited by applicant]
US 4747973A · Cusano et al. · 1988 [cited by applicant]
US 4958080A · Melcher · 1990 [cited by applicant]
US 5003181A · Morlotti · 1991 [cited by applicant]
US 5124072A · Dole et al. · 1992 [cited by applicant]
US 5264154A · Akiyama et al. · 1993 [cited by applicant]
US 5318722A · Tsoukala et al. · 1994 [cited by applicant]
US 5521387A · Riedner et al. · 1996 [cited by applicant]
US 5998925A · Shimizu et al. · 1999 [cited by applicant]
US 6093347A · Lynch et al. · 2000 [cited by applicant]
US 6210605B1 · Srivastava et al. · 2001 [cited by applicant]
US 6278832B1 · Zagumennyi et al. · 2001 [cited by applicant]
US 6323489B1 · McClellan · 2001 [cited by applicant]
US 6437336B1 · Pauwels et al. · 2002 [cited by applicant]
US 6498828B2 · Jiang · 2002 [cited by applicant]
US 6624420B1 · Chai et al. · 2003 [cited by applicant]
US 6818896B2 · Pauwels et al. · 2004 [cited by applicant]
US 6921901B1 · Chai et al. · 2005 [cited by applicant]
US 6967330B1 · Lempicki et al. · 2005 [cited by applicant]
US 7102135B2 · Lecoq · 2006 [cited by applicant]
US 7132060B2 · Zagumennyi et al. · 2006 [cited by applicant]
US 7138074B1 · Nakamura · 2006 [cited by applicant]
US 7151261B2 · Chai · 2006 [cited by applicant]
US 7166845B1 · Chai · 2007 [cited by applicant]
US 7180068B1 · Brecher et al. · 2007 [cited by applicant]
US 7397034B2 · Chai et al. · 2008 [cited by applicant]
US 7531036B2 · Shimura et al. · 2009 [cited by applicant]
US 7531109B2 · LaCourse et al. · 2009 [cited by applicant]
US 7595492B2 · Nakamura et al. · 2009 [cited by applicant]
US 7618491B2 · Kurata et al. · 2009 [cited by applicant]
US 7651632B2 · Ferrand et al. · 2010 [cited by applicant]
US 7692153B2 · Shimizu et al. · 2010 [cited by applicant]
US 7749323B2 · Shimura et al. · 2010 [cited by applicant]
US 7863572B1 · Doty · 2011 [cited by applicant]
US 7947956B2 · Nakamura et al. · 2011 [cited by applicant]
US 8034258B2 · Ferrand et al. · 2011 [cited by applicant]
US 8062419B1 · Andreaco et al. · 2011 [cited by applicant]
US 8158948B2 · Chou · 2012 [cited by applicant]
US 8278624B2 · Koschan et al. · 2012 [cited by applicant]
US 8394195B2 · Andreaco et al. · 2013 [cited by applicant]
US 8486300B2 · Gundiah et al. · 2013 [cited by applicant]
US 8574458B2 · Ferrand et al. · 2013 [cited by applicant]
US 8597542B2 · Nass · 2013 [cited by applicant]
US 8617422B2 · Koschan et al. · 2013 [cited by applicant]
US 8728232B2 · Usui et al. · 2014 [cited by applicant]
US 8999281B2 · Kurata et al. · 2015 [cited by applicant]
US 9328288B2 · Cohen et al. · 2016 [cited by applicant]
US 9543170B2 · Ferrand et al. · 2017 [cited by applicant]
US 9868900B2 · Blahuta · 2018 [cited by examiner]
US 10094048B2 · Chou · 2018 [cited by applicant]
US 10647916B2 · Blahuta et al. · 2020 [cited by applicant]
US 10890670B2 · Ferrand et al. · 2021 [cited by applicant]
US 10907096B2 · Blahuta et al. · 2021 [cited by applicant]
US 20020144640A1 · Andreaco et al. · 2002 [cited by applicant]
US 20030020044A1 · Lyons et al. · 2003 [cited by applicant]
US 20030062465A1 · Pauwels et al. · 2003 [cited by applicant]
US 20030159643A1 · Sumiya et al. · 2003 [cited by applicant]
US 20040108492A1 · Derenzo et al. · 2004 [cited by applicant]
US 20040200964A1 · Lefaucheur et al. · 2004 [cited by applicant]
US 20040245479A1 · Misawa et al. · 2004 [cited by applicant]
US 20050082484A1 · Srivastava et al. · 2005 [cited by applicant]
US 20050104000A1 · Kindem et al. · 2005 [cited by applicant]
US 20050211906A1 · Tonami et al. · 2005 [cited by applicant]
US 20060086311A1 · Zagumennyi et al. · 2006 [cited by applicant]
US 20060266276A1 · Shimura et al. · 2006 [cited by applicant]
US 20060266277A1 · Usui et al. · 2006 [cited by applicant]
US 20060288926A1 · Kurata et al. · 2006 [cited by applicant]
US 20070209581A1 · Ferrand et al. · 2007 [cited by applicant]
US 20070210256A1 · Dorenbos et al. · 2007 [cited by applicant]
US 20080017802A1 · Nakamura et al. · 2008 [cited by applicant]
US 20080067391A1 · Shimizu et al. · 2008 [cited by applicant]
US 20080089824A1 · Shimura et al. · 2008 [cited by applicant]
US 20090029005A1 · Van Amerongen et al. · 2009 [cited by applicant]
US 20100078595A1 · Eriksson et al. · 2010 [cited by applicant]
US 20100193739A1 · Peuchert et al. · 2010 [cited by applicant]
US 20100327227A1 · Kurata et al. · 2010 [cited by applicant]
US 20110204240A1 · Chou · 2011 [cited by applicant]
US 20110293499A1 · Iltis · 2011 [cited by applicant]
US 20110297882A1 · Ferrand et al. · 2011 [cited by applicant]
US 20120119092A1 · Blahuta et al. · 2012 [cited by applicant]
US 20120126171A1 · Andreaco et al. · 2012 [cited by applicant]
US 20130327986A1 · Blahuta et al. · 2013 [cited by applicant]
US 20140061537A1 · Zagumennyi et al. · 2014 [cited by applicant]
US 20140291580A1 · Zagumennyi et al. · 2014 [cited by applicant]
US 20150069298A1 · Kurata et al. · 2015 [cited by applicant]
US 20160002529A1 · Blahuta et al. · 2016 [cited by applicant]
US 20160025263A1 · Gibbons et al. · 2016 [cited by applicant]
US 20160252631A1 · Blahuta et al. · 2016 [cited by applicant]
US 20180079956A1 · Blahuta et al. · 2018 [cited by applicant]
US 20180094189A1 · Blahuta et al. · 2018 [cited by applicant]
US 20210147748A1 · Blahuta et al. · 2021 [cited by applicant]
US 20220290046A1 · Blahuta et al. · 2022 [cited by applicant]
CN 1109112A · 1995 [cited by applicant]
CN 1390988A · 2003 [cited by applicant]
CN 1404522A · 2003 [cited by applicant]
CN 1636910A · 2005 [cited by applicant]
CN 1847469A · 2006 [cited by applicant]
CN 1926218A · 2007 [cited by applicant]
CN 101545140A · 2009 [cited by applicant]
CN 102477580A · 2012 [cited by applicant]
CN 1926218B · 2012 [cited by applicant]
CN 103975042A · 2014 [cited by applicant]
CN 105986320A · 2016 [cited by applicant]
CN 103249805B · 2017 [cited by applicant]
CN 108186041A · 2018 [cited by applicant]
CN 210803733U · 2020 [cited by applicant]
DE 19950087A1 · 2000 [cited by applicant]
DE 112011103780T5 · 2013 [cited by applicant]
EP 0097296B1 · 1986 [cited by applicant]
EP 0097295B1 · 1987 [cited by applicant]
EP 0795631A1 · 1997 [cited by applicant]
EP 1028154B1 · 2003 [cited by applicant]
EP 1466955A2 · 2004 [cited by applicant]
EP 1707613A1 · 2006 [cited by applicant]
EP 2758489B1 · 2016 [cited by applicant]
EP 3091060A1 · 2016 [cited by applicant]
FR 2967421B1 · 2012 [cited by applicant]
FR 2967420B1 · 2014 [cited by applicant]
GB 2499343A · 2013 [cited by applicant]
JP H02300696A · 1990 [cited by applicant]
JP H04321600A · 1992 [cited by applicant]
JP H06287553A · 1994 [cited by applicant]
JP H07252476A · 1995 [cited by applicant]
JP 2000178554A · 2000 [cited by applicant]
JP 2001294853A · 2001 [cited by applicant]
JP 2001524163A · 2001 [cited by applicant]
JP 2003253255A · 2003 [cited by applicant]
JP 2004300418A · 2004 [cited by applicant]
JP 2004339506A · 2004 [cited by applicant]
JP 2006083275A · 2006 [cited by applicant]
JP 2006199727A · 2006 [cited by applicant]
JP 2006257199A · 2006 [cited by applicant]
JP 2007001849A · 2007 [cited by applicant]
JP 2007001850A · 2007 [cited by applicant]
JP 2007016197A · 2007 [cited by applicant]
JP 2007246653A · 2007 [cited by applicant]
JP 2008509270A · 2008 [cited by applicant]
JP 2009046598A · 2009 [cited by applicant]
JP 2014505742A · 2014 [cited by applicant]
JP 2014526587A · 2014 [cited by applicant]
JP 5984940B2 · 2016 [cited by applicant]
WO 9935512A1 · 1999 [cited by applicant]
WO 2004050792A1 · 2004 [cited by applicant]
WO 2005042812A1 · 2005 [cited by applicant]
WO 2006018586A1 · 2006 [cited by applicant]
WO 2006068130A1 · 2006 [cited by applicant]
WO 2006071236A1 · 2006 [cited by applicant]
WO 2010136116A1 · 2010 [cited by applicant]
WO 2012066424A1 · 2012 [cited by applicant]
WO 2012066425A2 · 2012 [cited by applicant]
WO 2013041251A2 · 2013 [cited by applicant]
WO 2015185988A1 · 2015 [cited by applicant]
Rare Eearth Element: Electronic Structure and Ionic Radius, Encyclopedia Britannica, Pecharsky et al, last updated Mar. 16, 2025. [cited by examiner]
Aitasalo, Tuomas et al., “Delayed Luminescence of Ce3+ doped Y2SiO5,” Optical Materials, Dec. 19, 2003, pp. 107-112, vol. 26, Elsevier. [cited by applicant]
Alba et al., “Formation of High-Temperature Lutetium Disilicate from Lutetium-Saturated Aluminosilicates in Mild Conditions. Incorporation of Si and Al XAS Techniques to the Study of These Systems,” 100 J. Phys. Chem. 5… [cited by applicant]
Assefa, Zerihun et al., “Correlation of the oxidation state of cerium in sol-gel glasses as a function of thermal treatment via optical spectroscopy and XANES studies,” Spectrochimica Acta Part A, Oct. 13, 2003, pp. 187… [cited by applicant]
Blahuta, S. et al., “Evidence and Consequences of Ce4+ in LYSO: Ce, Ca and LYSO: Ce, Mg Single Crystals for Medical Imaging Applications,” IEEE Transactions on Nuclear Science, vol. 60, No. 4, Aug. 2013, pp. 3134-3141. [cited by applicant]
Derenzo, Stephen et al., “Scintillation Properties,” 14 pages, Lawrence Berkeley National Laboratory, Feb. 12, 2009, US, http://scintillator.lbl.gov. [cited by applicant]
Ding, Dongzhou et al., “Air Atmosphere Annealing Effects on LSO:Ce Crystal,” IEEE Transaction on Nuclear Science, Jun. 1, 2010, pp. 1272-1277, vol. 57, No. 3, IEEE Service Center, New York, US. [cited by applicant]
Dorenbos, P., “The 5d level positions of the trivalent lanthanides in inorganic compounds,” Journal of Luminescence, Apr. 3, 2000, pp. 155-176, vol. 91, Elsevier. [cited by applicant]
Feng, He et al., “Annealing effects on Czochralski grown Lu2Si207:Ce3+ crystals under different atmospheres,” Journal of Applied Physics, Apr. 22, 2008, p. 83109, vol. 103, No. 8, American Institute of Physics, New York… [cited by applicant]
Fleet Michael E. et al., “The Structure of NaCa2LuSi2O7F2, A Synthetic Phase of the Cuspidine Group,” The Canadian Mineralogist, 1995, vol. 33, pp. 879-884. [cited by applicant]
Friedrich, Stephan et al., “A 36-Pixel Tunnel Junction Soft X-Ray Spectrometer for Scintillator Material Science,” IEEE Transactions on Applied Superconductivity, Jun. 2007, pp. 351-354, vol. 17, No. 2, IEEE. [cited by applicant]
Hautefeuille, B. et al., “Shaped crystal growth of Ce3+-doped Lu2(1-x)Y2xSIO5 oxyorthosilicate for scintillator applications by pulling-down technique,” Journal of Crystal Growth, Jan. 10, 2006, pp. 172-177, vol. 289, E… [cited by applicant]
He, Ming et al., “Growth and optical properties of YBa3B9O18:Ce crystals,” Journal of Crystal Growth, Jun. 23, 2007, pp. 427-431, vol. 307, Elsevier. [cited by applicant]
International Search Report for PCT/EP2012/059055, dated Apr. 25, 2013, 28 pages. [cited by applicant]
International Search Report for PCT/IB2011/003026, dated Mar. 29, 2012, 16 pages. [cited by applicant]
International Search Report for PCT/IB2011/003028, dated Jun. 12, 2012, 12 pages. [cited by applicant]
Kurata, Y. et al., “Scintillation Characteristics of GSO Single Crystal Grown Under O2-Containing Atmosphere,” IEEE Transactions on Nuclear Science, Aug. 1995, pp. 1038-1040, vol. 42, No. 4. [cited by applicant]
Mansuy, Christelle et al., “Molecular design of inorganic scintillators: from alkoxides to scintillating materials,” Journal of Materials Chemistry, Jan. 1, 2004, p. 3274-3280, vol. 14, No. 21. [cited by applicant]
Mckeever, “Thermoluminescence of solids,” Cambridge Solid State Science Series, pp. 1-3, pp. 143-147, Cambridge University Press. [cited by applicant]
Melcher et al., “Czochralski growth of rare earth oxyorthosilicate single crystals,” Journal of Crystal Growth, Mar. 1, 1993, pp. 1001-1005, vol. 128, No. 1-4, Elsevier, Amsterdam, NL. [cited by applicant]
Melcher, C. et al., “Cerium Oxidation State in LSO:Ce Scintillators,” IEEE Transactions on Nuclear Science, Oct. 2005, pp. 1809-1812, vol. 52, No. 5. [cited by applicant]
Naik, Y.P. et al., “Synthesis and luminescence investigation of RE3+ (Eu3+, Tb3+ and Ce3+)-doped lithium silicate (Li2SiO3),” Journal of Luminescence, Jun. 7, 2009, pp. 1225-1229, vol. 129, Elsevier. [cited by applicant]
Peak, Jonathan D. et al., “Combinatorial thin film sputtering investigation of cerium concentration in Lu2SiO5 scintillators,” Journal of Luminescence, Mar. 2, 2010, pp. 1366-1370, vol. 130, Elsevier. [cited by applicant]
Peter et al., “Etching studies on lutetium yttrium orthosilicate LuxY2-xSiO5:Ce (LYSO) scintillator crystals,” 11th Europhysical Conference on Defects in Insulating Materials, 2010, pp. 1-6, IOP Publishing Ltd. [cited by applicant]
Potdevin, A. et al., “Structural, morphological and scintillation properties of Ce3+-doped Y3Al5O12 powders and films elaborated by the sol-gel process,” Materials Chemistry and Physics, Jul. 7, 2011, pp. 500-506, vol. … [cited by applicant]
Preliminary Search Report for FR1059394, dated Jan. 28, 2011, 10 pages. [cited by applicant]
Shimura, N. et al., “Zr doped GSO:Ce single crystals and their scintillation performance,” Oct. 2004, 4 pages. [cited by applicant]
Yang, Kan et al., “Effects of Calcium Codoping on Charge Traps in LSO:Ce Crystals,” IEEE Transaction on Nuclear Science, Oct. 1, 2009, pp. 2960-2965, vol. 56, No. 5, IEEE Service Center, New York, US. [cited by applicant]
Yang, Kan et al., “Luminescence centers in calcium co-doped LSO:Ce single crystals,” 2009 IEEE Nuclear Science Symposium and Medical Imaging Conference, Oct. 24, 2009, pp. 1-5, IEEE, Orlando, US. [cited by applicant]
Zavartsev, Yuri D. et al., “Czochralski growth and characterisation of large Ce3+:Lu2SiO5 single crystals co-doped with Mg2+ or Ca2+ or Tb3+ for scintillators,” Journal of Crystal Growth, Jan. 1, 2005, pp. e2167-e2171, … [cited by applicant]
Zhu, Fang et al., “The influence on intrinsic light emission of calcium tungstate and molybdate powders by multivalence PR codoping,” Applied Physics A, Jul. 21, 2010, pp. 689-693, vol. 101, Springer-Verlag. [cited by applicant]
Laishun Qin, et al., “Growth and characteristics of LYSO (Lu2(1-x-y)Y2xSiO5:Cey) scintillation crystals,” Journal of Crystal Growth, vol. 281 (2005) pp. 518-524. [cited by applicant]
Letter from Allen, Dyer, Doppelt & Gilchrist, P.A. to Hill, Ward & Henderson, P.A. and Kirkland & Ellis, LLP re Saint-Gobain Cristaux et Detecteurs V. Crystal Photonics, Inc. Case, dated Sep. 16, 2021, 94 pgs. [cited by applicant]