IP Library › Granted Patent US 12,735,838
Granted Patent B2
US 12,735,838 · App. 18/446,581 · Granted Sep 15, 2026

Thermal interface materials comprising aligned fibers and materials such as solder, alloys, and/or other metals

Inventors: Rafael Padilla, Jr. (San Leandro, CA); Chunzhou Pan (Quincy, MA)
Assignee: Boston Materials, Inc.
D06M11/83B23K35/365C23C16/06D06M2101/40D10B2101/12
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Quick Facts
Patent No.
US 12,735,838
App. No.
18/446,581
Granted
Sep 15, 2026
Kind
B2
Abstract

The present disclosure is generally directed to a variety of thermally conductive materials for use in semiconductor devices or other applications. In some cases, the materials may include aligned fibers such as carbon fibers, e.g., defining a substrate, and a metal such as solder. In some cases, the metal may be present within a transition metal rich solder alloy, a conductive medium such as a conductive ink, a thermal chemical vapor deposited solder, an oxide coated liquid metal, an oxide coated liquid metal transition metal rich solder alloy, etc. The metal may have a relatively low melting temperature in certain embodiments. The metal may be interspersed or infiltrated between the plurality of discontinuous fibers, and/or surround at least some of the fibers. In some cases, the metal may react with the carbon fibers to form metal carbides and/or diffuse into the carbon fibers, which may facilitate contact between the metal and the carbon fibers. Other aspects are generally directed to devices using such compositions, methods of making such compositions, kits including such compositions, or the like.

Claims (19)

1 . A composition, comprising:

a plurality of discontinuous fibers defining a substrate, wherein the plurality of discontinuous fibers comprise carbon fibers having an average diameter of at least 5 micrometers, and at least 30 vol % of the discontinuous fibers within the substrate are substantially aligned; and

a solder in contact with the plurality of discontinuous fibers, wherein at least some of the solder is interspersed with the plurality of discontinuous fibers, and the plurality of discontinuous fibers is more thermally conductive than the solder.

2 . The composition of claim 1 , wherein the solder comprises a transition metal rich solder alloy.

3 . The composition of claim 1 , wherein the solder comprises an oxide coated liquid metal.

4 . The composition of claim 1 , wherein the solder comprises an oxide coated liquid metal transition metal rich solder alloy.

5 . The composition of claim 1 , wherein the solder comprises a thermal chemical vapor deposited metal.

6 . The composition of claim 1 , wherein the solder is contained within a conductive medium.

7 . The composition of claim 1 , wherein at least some of the solder covers a first side of the substrate.

8 . The composition of claim 1 , wherein at least some of the solder surrounds the plurality of discontinuous fibers.

9 . The composition of claim 1 , wherein the solder has a melting temperature of no more than 265° C.

10 . The composition of claim 1 , wherein the solder comprises nickel.

11 . The composition of claim 1 , further comprising solder flux in contact with the solder.

12 . The composition of claim 1 , wherein the carbon fibers have a carbon content greater than 94% and a modulus of at least 200 GPa.

13 . The composition of claim 1 , wherein at least 30% of the lengths of the discontinuous fibers are in contact with the solder.

14 . The composition of claim 1 , wherein at least 50 vol % of the discontinuous fibers have an alignment that is within 45° of the average alignment of the plurality of discontinuous fibers.

15 . The composition of claim 1 , wherein the composition has an overall heat conductivity of at least 30 W/m K.

16 . The composition of claim 1 , wherein the composition exhibits anisotropic heat conductivity.

17 . A device, comprising the composition of claim 1 , wherein the composition is in thermal communication with a heat source and a cooling apparatus.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 13, 2023
From: PADILLA, RAFAEL, JR.; PAN, CHUNZHOU
To: BOSTON MATERIALS, INC.
Reel/Frame 064889/0118 →
Continuity (2)
Provisional Application 63398190 · Aug 15, 2022
Related Publication 20240052558A1 · Feb 15, 2024
References Cited (203)
US 4025911A · Bobeck et al. · 1977 [cited by applicant]
US 4481249A · Ebneth et al. · 1984 [cited by applicant]
US 4523628A · Vives · 1985 [cited by applicant]
US 5432000A · Young et al. · 1995 [cited by applicant]
US 5876540A · Pannell · 1999 [cited by applicant]
US 5968639A · Childress · 1999 [cited by applicant]
US 6837306B2 · Houle · 2005 [cited by examiner]
US 7073538B2 · Bhatnagar et al. · 2006 [cited by applicant]
US 7409757B2 · Hall et al. · 2008 [cited by applicant]
US 7439475B2 · Ohta · 2008 [cited by applicant]
US 7537825B1 · Wardle et al. · 2009 [cited by applicant]
US 7655581B2 · Goering · 2010 [cited by applicant]
US 7663242B2 · Lewis · 2010 [cited by examiner]
US 7803262B2 · Haik et al. · 2010 [cited by applicant]
US 7832983B2 · Kruckenberg et al. · 2010 [cited by applicant]
US 7951464B2 · Roberts · 2011 [cited by applicant]
US 8173857B1 · Yananton · 2012 [cited by applicant]
US 8197888B2 · Sue et al. · 2012 [cited by applicant]
US 8575045B1 · McKnight et al. · 2013 [cited by applicant]
US 8790565B2 · Miller · 2014 [cited by applicant]
US 8889761B2 · Studart et al. · 2014 [cited by applicant]
US 9312046B2 · Hong et al. · 2016 [cited by applicant]
US 9388577B2 · Kromer et al. · 2016 [cited by applicant]
US 9394196B2 · Peters et al. · 2016 [cited by applicant]
US 9732463B2 · Carter et al. · 2017 [cited by applicant]
US 9892835B2 · Hong et al. · 2018 [cited by applicant]
US 9896783B2 · Kia · 2018 [cited by applicant]
US 11479656B2 · Soheilian et al. · 2022 [cited by applicant]
US 11767415B2 · Soheilian et al. · 2023 [cited by applicant]
US 11820880B2 · Gurijala et al. · 2023 [cited by applicant]
US 11840028B2 · Mone et al. · 2023 [cited by applicant]
US 12428587B1 · Stagon et al. · 2025 [cited by applicant]
US 20050058805A1 · Kimura et al. · 2005 [cited by applicant]
US 20050061496A1 · Matabayas, Jr. · 2005 [cited by applicant]
US 20050175813A1 · Wingert et al. · 2005 [cited by applicant]
US 20050228097A1 · Zhong et al. · 2005 [cited by applicant]
US 20050239948A1 · Haik et al. · 2005 [cited by applicant]
US 20060157223A1 · Gelorme et al. · 2006 [cited by applicant]
US 20060286361A1 · Yonetake et al. · 2006 [cited by applicant]
US 20080145647A1 · Ganguli et al. · 2008 [cited by applicant]
US 20080274326A1 · Kim et al. · 2008 [cited by applicant]
US 20090117269A1 · Hansen et al. · 2009 [cited by applicant]
US 20090227162A1 · Kruckenberg et al. · 2009 [cited by applicant]
US 20100040902A1 · Mizrahi · 2010 [cited by applicant]
US 20100128439A1 · Tilak et al. · 2010 [cited by applicant]
US 20100196688A1 · Kritzer et al. · 2010 [cited by applicant]
US 20100320320A1 · Kismar et al. · 2010 [cited by applicant]
US 20110186775A1 · Shah et al. · 2011 [cited by applicant]
US 20120107599A1 · Yonetake et al. · 2012 [cited by applicant]
US 20120289107A1 · Beissinger et al. · 2012 [cited by applicant]
US 20130053471A1 · Studart et al. · 2013 [cited by applicant]
US 20130252497A1 · Schiebel et al. · 2013 [cited by applicant]
US 20130316148A1 · Gunnink · 2013 [cited by applicant]
US 20140110049A1 · Yuen et al. · 2014 [cited by applicant]
US 20140250665A1 · Choi et al. · 2014 [cited by applicant]
US 20140342630A1 · Amtmann et al. · 2014 [cited by applicant]
US 20150168087A1 · Kim et al. · 2015 [cited by applicant]
US 20150228388A1 · Hong et al. · 2015 [cited by applicant]
US 20160055930A1 · Humfeld · 2016 [cited by applicant]
US 20160083535A1 · Wilenski et al. · 2016 [cited by applicant]
US 20160169009A1 · Okamoto et al. · 2016 [cited by applicant]
US 20160340482A1 · Williams et al. · 2016 [cited by applicant]
US 20170067186A1 · Kia · 2017 [cited by applicant]
US 20170101730A1 · Gilbertson · 2017 [cited by applicant]
US 20170135227A1 · Ramakrishna · 2017 [cited by examiner]
US 20170173895A1 · Williams · 2017 [cited by applicant]
US 20170182700A1 · Brady · 2017 [cited by applicant]
US 20170240715A1 · Hsiao et al. · 2017 [cited by applicant]
US 20170338497A1 · Tatsuno et al. · 2017 [cited by applicant]
US 20180016420A1 · Fujimaki · 2018 [cited by applicant]
US 20180016740A1 · Kia et al. · 2018 [cited by applicant]
US 20190048500A1 · Tierney et al. · 2019 [cited by applicant]
US 20200024795A1 · Gurijala et al. · 2020 [cited by applicant]
US 20200066614A1 · Cola et al. · 2020 [cited by applicant]
US 20210008840A1 · Gurijala et al. · 2021 [cited by applicant]
US 20210009789A1 · Soheilian et al. · 2021 [cited by applicant]
US 20220001631A1 · Mone et al. · 2022 [cited by applicant]
US 20230002591A1 · Soheilian et al. · 2023 [cited by applicant]
US 20230272256A1 · Pan et al. · 2023 [cited by applicant]
US 20260062598A1 · Stagon et al. · 2026 [cited by applicant]
CN 1784516A · 2006 [cited by applicant]
CN 1894435A · 2007 [cited by applicant]
CN 1906234A · 2007 [cited by applicant]
CN 1950200A · 2007 [cited by applicant]
CN 101224601A · 2008 [cited by applicant]
CN 103109330A · 2013 [cited by applicant]
CN 105073848A · 2015 [cited by applicant]
CN 105390210A · 2016 [cited by applicant]
CN 105690802A · 2016 [cited by applicant]
CN 105734535A · 2016 [cited by applicant]
CN 105980512A · 2016 [cited by applicant]
CN 106460312A · 2017 [cited by applicant]
CN 107107537A · 2017 [cited by applicant]
CN 110828828A · 2020 [cited by applicant]
CN 108251063B · 2021 [cited by applicant]
EP 2013408A2 · 2009 [cited by applicant]
EP 2085215A1 · 2009 [cited by applicant]
EP 2883930A1 · 2015 [cited by applicant]
EP 3184288A1 · 2017 [cited by applicant]
GB 1438509A · 1976 [cited by applicant]
JP S4926381A · 1974 [cited by applicant]
JP S57149551A · 1982 [cited by applicant]
JP S60082332A · 1985 [cited by applicant]
JP S63295751A · 1988 [cited by applicant]
JP 07197311A · 1995 [cited by applicant]
JP 07331358A · 1995 [cited by applicant]
JP 2000281802A · 2000 [cited by applicant]
JP 2003301048A · 2003 [cited by applicant]
JP 2004051853A · 2004 [cited by applicant]
JP 2004103403A · 2004 [cited by applicant]
JP 2004276478A · 2004 [cited by applicant]
JP 2004360160A · 2004 [cited by applicant]
JP 2006335957A · 2006 [cited by applicant]
JP 2007009363A · 2007 [cited by applicant]
JP 2008266586A · 2008 [cited by applicant]
JP 2013023801A · 2013 [cited by applicant]
JP 2015063664A · 2015 [cited by applicant]
JP 2016044302A · 2016 [cited by applicant]
JP 2016064648A · 2016 [cited by applicant]
JP 2018523599A · 2018 [cited by applicant]
JP 2021008369A · 2021 [cited by applicant]
JP 2022512188A · 2022 [cited by applicant]
WO WO2001025514A1 · 2001 [cited by applicant]
WO WO2005085334A2 · 2005 [cited by applicant]
WO WO2007130979A2 · 2007 [cited by applicant]
WO WO2009009207A2 · 2009 [cited by applicant]
WO WO2011100734A1 · 2011 [cited by applicant]
WO WO2017027699A1 · 2017 [cited by applicant]
WO WO2018175134A1 · 2018 [cited by applicant]
WO WO2020123334A1 · 2018 [cited by applicant]
WO WO2021007381A1 · 2021 [cited by applicant]
WO WO2021007389A1 · 2021 [cited by applicant]
WO WO2023163848A2 · 2023 [cited by applicant]
WO WO2024039598A1 · 2024 [cited by applicant]
Solder Alloys by Indium Corporation, https://www.indium.com/products/alloys/solder-alloys/ (Year: 2026). [cited by examiner]
Chinese Office Action for Application No. 20188003308.2 mailed Jun. 29, 2021. [cited by applicant]
Chinese Office Action for Application No. 20188003308.2 mailed Jan. 24, 2022. [cited by applicant]
Chinese Office Action for Application No. 201880033308.2 mailed Jul. 29, 2022. [cited by applicant]
Extended European Search Report for Application No. 18770244.4 mailed Dec. 3, 2020. [cited by applicant]
European Office Action mailed Nov. 21, 2022 for Application No. 18770244.4. [cited by applicant]
Japanese Office Action for Application No. 2020-500780 mailed Feb. 15, 2022. [cited by applicant]
Japanese Office Action for Application No. 2020-500780 mailed Jun. 28, 2022. [cited by applicant]
International Search Report and Written Opinion for Application No. PCT/US2018/021975 mailed May 24, 2018. [cited by applicant]
International Preliminary Report on Patentability for Application No. PCT/US2018/021975 mailed Oct. 3, 2019. [cited by applicant]
Chinese Office Action for Application No. 2019800800347 mailed Feb. 16, 2022. [cited by applicant]
Chinese Office Action for Application No. 2019800800347 mailed Jun. 28, 2022. [cited by applicant]
Chinese Office Action mailed Jan. 10, 2023, for Application No. CN201980080034.7. [cited by applicant]
Extended European Search Report for Application No. 19896171.6 mailed Aug. 16, 2022. [cited by applicant]
European Office Action mailed Jul. 14, 2023, for Application No. 19896171.6. [cited by applicant]
Japanese Office Action mailed Sep. 5, 2023, for Application No. JP2021-532970. [cited by applicant]
International Search Report and Written Opinion for Application No. PCT/US2019/065142 mailed Mar. 10, 2020. [cited by applicant]
International Preliminary Report on Patentability for Application No. PCT/US2019/065142 mailed Jun. 24, 2021. [cited by applicant]
Invitation to Pay Additional Fees for Application No. PCT/US2020/041306 mailed Oct. 29, 2020. [cited by applicant]
International Search Report and Written Opinion for Application No. PCT/US2020/041306 mailed Dec. 21, 2020. [cited by applicant]
International Preliminary Report on Patentability for Application No. PCT/US2020/041306 mailed Jan. 20, 2022. [cited by applicant]
International Search Report and Written Opinion for Application No. PCT/US2020/041322 mailed Oct. 9, 2020. [cited by applicant]
International Preliminary Report on Patentability for Application No. PCT/US2020/041322 mailed Jan. 20, 2022. [cited by applicant]
Invitation to Pay Additional Fees for Application No. PCT/US2023/012171 mailed Jun. 23, 2023. [cited by applicant]
[No Author Listed], Permanent Magnets vs Electromagnets. Adams Magnetic Products. Accessed Sep. 20, 2017. 5 pages. [cited by applicant]
[No Author Listed], HexTow® IM7 Carbon Fiber. HEXCEL® Product Data Sheet. Jan. 1, 2020. Retrieved from the Internet. 2 pages. [cited by applicant]
[No Author Listed], New Practical Handbook of Hardware. Ed. Zhenwu, Z. Liaoning Science and Tech Publishing House, Jan. 2015: 1486-7. [cited by applicant]
Barrett et al., The mechanics of z-fiber reinforcement. Composite Structures. Sep. 1996; 36(1-2): 23-32. [cited by applicant]
Boden et al., Nanoplatelet size to control the alignment and thermal conductivity in copper-graphite composites. Nano Lett. Jun. 11, 2014;14(6):3640-4. doi: 10.1021/nl501411g. Epub May 22, 2014. [cited by applicant]
Erb et al., Composites reinforced in three dimensions by using low magnetic fields. Science. Jan. 13, 2012;335(6065):199-204. doi: 10.1126/science.1210822. [cited by applicant]
Erb et al., Concentration gradients in mixed magnetic and nonmagnetic colloidal suspensions. J Appl Phys. Mar. 7, 2008;103(07A312):1-3. [cited by applicant]
Erb et al., Magnetic assembly of colloidal superstructures with multipole symmetry. Nature. Feb. 19, 2009;457(7232):999-1002. doi: 10.1038/nature07766. [cited by applicant]
Erb et al., Non-linear alignment dynamics in suspensions of platelets under rotating magnetic fields. Soft Matter. 2012;8:7604-9. [cited by applicant]
Gardiner, Z-direction composite properties on an affordable, industrial scale. Composite World. Apr. 20, 2021. <https://www.compositesworld.com/articles/z-direction-composite-properties-on-an-affordable-industrial-scale… [cited by applicant]
Hashin, Analysis of the effects of fiber anisotropy on the properties of carbon and graphite fiber composites. J Appl Mech. 1979; 46: 543-50. [cited by applicant]
Huang, Fabrication and properties of carbon fibers. Materials. Dec. 16, 2009; 2: 2369-403. doi:10.3390/ma2042369. [cited by applicant]
Jackson et al., Out-of-plane properties. NASA, Langley Research Center Mechanics of Textile Composites Conference. Oct. 1, 1995:315-348. [cited by applicant]
Kimura et al., Uniaxial alignment of the smallest diamagnetic susceptibility axis using time-dependent magnetic fields. Langmuir. Jul. 6, 2004;20(14):5669-72. doi: 10.1021/la049347w. [cited by applicant]
Le Ferrand et al., Magnetically assisted slip casting of bioinspired heterogeneous composites. Nat Mater. Nov. 2015;14(11):1172-9. doi: 10.1038/nmat4419. Epub Sep. 21, 2015. [cited by applicant]
Libanori et al., Mechanics of platelet-reinforced composites assembled using mechanical and magnetic stimuli. ACS Appl Mater Interfaces. Nov. 13, 2013;5(21):10794-805. doi: 10.1021/am402975a. Epub Oct. 25, 2013. [cited by applicant]
Libanori et al., Ultrahigh magnetically responsive microplatelets with tunable fluorescence emission. Langmuir. Nov. 26, 2013;29(47):14674-80. doi: 10.1021/la4027305. Epub Nov. 15, 2013. [cited by applicant]
Martin et al., Designing bioinspired composite reinforcement architectures via 3D magnetic printing. Nat Commun. Oct. 23, 2015;6:8641. doi: 10.1038/ncomms9641. [cited by applicant]
Martin et al., Understanding and overcoming shear alignment of fibers during extrusion. Soft Matter. Jan. 14, 2015;11(2):400-5. doi: 10.1039/c4sm02108h. [cited by applicant]
Matsuo, Electric, Dielectric and Magnetic Properties of Polymer and Carbon Fillers. International Workshop on Advanced Polymer Science and Turbulent Drag Reduction. Mar. 10-20, 2008. 57 pages. [cited by applicant]
Matthews et al., Magnetic alignment of mesophase pitch-based carbon fibers. Appl Phys Lett. Jul. 15, 1996;69(3):430-2. [cited by applicant]
Ooi et al., On the controllability of nanorod alignment in magnetic fluids. Journal of Applied Physics. Feb. 7, 2008;103(07E910):1-3. [cited by applicant]
Sander et al., High-performance battery electrodes via magnetic templating. Nature Energy. Aug. 2016;1:1-7. [cited by applicant]
Sato et al., Recent trend of carbon fiber technology from mesophase pitch (part 1)—the new method for high performance and improved properties. TANSO. 1993; 157: 107-19. Japanese. [cited by applicant]
Sherman et al., Fiber sizings: coupling agent companions. CompositesWorld. Aug. 1, 2013. Retrieved from the Internet at URL:https://www.compositesworld.com/articles/fiber-sizings-coupling-agent-companions. Last Accessed… [cited by applicant]
Sommer et al., Injectable materials with magnetically controlled anisotropic porosity. ACS Appl Mater Interfaces. Oct. 24, 2012;4(10):5086-91. doi: 10.1021/am301500z. Epub Oct. 9, 2012. [cited by applicant]
Walsh et al., Carbon fibers. Composites. ASM International. 2001; 35-40. [cited by applicant]
International Search Report and Written Opinion, mailed Jan. 8, 2024 for International Application No. PCT/US2023/030139. [cited by applicant]
Invitation to Pay Additional Fees for Application No. PCT/US2023/030139 mailed Nov. 16, 2023. [cited by applicant]
European Office Action mailed Nov. 6, 2023, for Application No. 18770244.4. [cited by applicant]
Chinese Office Action mailed Nov. 2, 2023, for Application No. 201980080034.7. [cited by applicant]
Japanese Office Action mailed Mar. 12, 2024, for Application No. JP2021-532970. [cited by applicant]
Japanese Office Action mailed Oct. 8, 2024, for Application No. JP2021-532970. [cited by applicant]
Chinese Office Action mailed Mar. 27, 2024, for Application No. 202080065034.2. [cited by applicant]
European Office Action mailed Jan. 27, 2023, for Application No. 20751409.2. [cited by applicant]
International Search Report and Written Opinion mailed Aug. 16, 2023, for Application No. PCT/US2023/012171. [cited by applicant]
International Preliminary Report on Patentability mailed Sep. 12, 2024, for Application No. PCT/US2023/012171. [cited by applicant]
International Preliminary Report on Patentability mailed Feb. 27, 2025, for Application No. PCT/US2023/030139. [cited by applicant]
Canadian Office Action issued Feb. 23, 2026 for Application No. 3,255,197. [cited by applicant]
Taiwanese Office Action mailed Jul. 15, 2025, for Application No. 113139491. [cited by applicant]
International Search Report and Written Opinion mailed Mar. 10, 2025, for Application No. PCT/US2024/044998. [cited by applicant]
[No Author Listed], Standard Test Method for Thermal Transmission Properties of Thermally Conductive Electrical Insulation Materials. Designation D5470-17. ASTM International. Nov. 2017. 6 pages. [cited by applicant]
Li et al., Carbon nanotube/paraffin/montmorillonite composite phase change material for thermal energy storage. Sol Energy. Apr. 2017;146:1-7. doi: 10.1016/j.solener.2017.02.003. [cited by applicant]
Xing et al., Ice thermal energy storage enhancement using aligned carbon nanotubes under external magnetic field. J Energy Storage. Dec. 1, 2002;56(Part A):105931. doi: 10.1016/j.est.2022.105931. [cited by applicant]
PCT/US2023/030139, Jan. 8, 2024, International Search Report and Written Opinion. [cited by applicant]