IP Library Granted Patent US 12,546,245
Granted Patent B2
US 12,546,245 · App. 18/648,656 · Granted Feb 10, 2026

Systems and methods for backhaul transportation of liquefied gas and CO2 using liquefied gas carriers

Inventor: Zachary D. Thobe (Findlay, OH)
Assignee: Marthon Petroleum Company LP
F01N13/08F17C7/00G06Q20/10F17C2205/0352F17C2221/013F17C2227/0135F17C2227/0157F17C2250/032F17C2250/0443F17C2250/0447F17C2270/0168
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Quick Facts
Patent No.
US 12,546,245
App. No.
18/648,656
Filed
Apr 29, 2024
Granted
Feb 10, 2026
Kind
B2
Art Unit
3753
USPC
141/1
Abstract

Embodiments of systems and methods for transporting liquefied gas and carbon dioxide (CO2) in a dual-fluid vessel thereby minimizing transportation between locations are disclosed. In an embodiment, the dual-fluid vessel has an outer shell with an outer surface, an outer compartment within the outer shell configured to store liquefied gas, a bladder positioned within the outer compartment configured to store CO2, and insulation positioned between the outer shell and the outer compartment to provide temperature regulation for the liquefied gas when positioned in the outer compartment and CO2 in the bladder.

Claims (59)

1 . A liquefied gas marine vessel to transport liquefied gas and carbon dioxide (CO2), the liquefied gas marine vessel comprising:

one or more dual-fluid storage tanks to transport liquefied gas or CO2, the one or more dual-fluid storage tanks having:

an outer shell;

compartment positioned within the outer shell to store the liquefied gas;

a bladder positioned within the compartment to expand when the CO2 flows therein, thereby to reduce contamination between the CO2 and the liquefied gas; and

insulation positioned between the outer shell and the compartment to provide temperature regulation from external heat sources.

2 . The liquefied gas marine vessel of claim 1 , wherein a pressure and temperature rating for the one or more dual-fluid storage tanks comprises a maximum pressure of about 80 pounds per square inch gauge (psig) to about 102 pounds psig and a minimum temperature of about −260 degrees Fahrenheit.

3 . The liquefied gas marine vessel of claim 1 , wherein the one or more dual-fluid storage tanks comprises one or more of spherical tanks, refrigerated tanks, prismatic tanks, cylindrical tanks, or bilobe tanks.

4 . The liquefied gas marine vessel of claim 1 , wherein the one or more dual-fluid storage tanks includes one or more (a) temperature-control apparatuses to control a temperature within the one or more dual-fluid storage tanks, or (b) pressure-control apparatuses to control a pressure within the one or more dual-fluid storage tanks.

5 . The liquefied gas marine vessel of claim 1 , further comprising a nitrogen tank positioned proximal and connected to one of the one or more dual-fluid storage tanks and wherein the nitrogen tank is configured to, if the bladder is partially or substantially empty, fill the outer compartment with nitrogen to stabilize the bladder.

6 . The liquefied gas marine vessel of claim 1 , wherein the one or more dual-fluid storage tanks further includes one or more membranes, waffles, or baffles positioned within the outer compartment of each of the one or more dual-fluid storage tanks.

7 . A dual-fluid transport system for transporting liquefied gas and carbon dioxide (CO2), the dual-fluid transport system comprising:

a liquefied gas marine vessel configured to transport liquefied gas and CO2, the liquefied gas marine vessel comprising:

one or more dual-fluid storage tanks positioned on the liquefied gas marine vessel to transport the liquefied gas or the CO2, the one or more dual-fluid storage tanks having:

an outer shell,

an outer compartment positioned within the outer shell, the outer compartment configured to store the liquefied gas,

a bladder positioned within the outer compartment and configured to expand when the CO2 flows therein, thereby to reduce contamination between the CO2 and the liquefied gas, and

insulation positioned between the outer shell and the outer compartment to provide temperature regulation from external heat sources;

one or more pumps configured to pump the liquefied gas and CO2 from the one or more dual-fluid storage tanks;

a first controller positioned within a first control room to control unloading/loading operations of CO2 from the bladder and liquefied gas from the outer compartment;

one or more articulated rigid loading arms positioned at a location and to connect the liquefied gas marine vessel to the location and configured to load and unload the liquefied gas and CO2;

a vapor return line connected to the one or more articulated rigid loading arms and configured to return excess vapor from the liquefied gas to the location;

one or more liquefied gas storage tanks configured to store liquefied gas and one or more CO2 storage tanks configured to store CO2;

a dehydration unit (a) positioned between the one or more articulated rigid loading arms and the one or more liquefied gas storage tanks and (b) configured to remove water from the CO2 when the CO2 is loaded onto the liquefied gas marine vessel; and

a second controller positioned within a location control room at the location and to control unloading/loading operation of CO2 and liquefied gas to/from CO2 storage tanks and liquefied gas storage tanks.

8 . The dual-fluid transport system of claim 7 , wherein the one or more dual-fluid storage tanks comprises a maximum pressure of about 80 pounds per square inch gauge (psig) to about 102 pounds psig and a minimum temperature of about −260 degrees Fahrenheit.

9 . The dual-fluid transport system of claim 7 , wherein the one or more dual-fluid storage tanks comprises one or more of spherical tanks, refrigerated tanks, prismatic tanks, cylindrical tanks, or bilobe tanks.

10 . The dual-fluid transport system of claim 7 , wherein the one or more dual-fluid storage tanks includes one or more of (a) temperature-control apparatuses to control a temperature within the one or more dual-fluid storage tanks or (b) pressure-control apparatuses to control a pressure within the one or more dual-fluid storage tanks.

11 . The dual-fluid transport system of claim 7 , further comprising a nitrogen tank positioned proximal and connected to one of the one or more dual-fluid storage tanks and wherein the nitrogen tank is configured to, if the bladder is partially or substantially empty, fill the outer compartment with nitrogen to stabilize the bladder.

12 . The dual-fluid transport system of claim 7 , wherein the one or more dual-fluid storage tanks includes one or more membranes, waffles, or baffles positioned within each of the one or more dual-fluid storage tanks.

13 . The dual-fluid transport system of claim 7 , wherein the one or more dual-fluid storage tanks further comprises one or more sensors, the one or more sensors to determine a temperature or a pressure of the liquefied gas and the CO2.

14 . The dual-fluid transport system of claim 7 , further comprising a liquefaction unit positioned at the location to transfer the CO2 to the liquefied gas marine vessel.

15 . The dual-fluid transport system of claim 7 , further comprising one or more valves positioned between the one or more articulated rigid loading arms and the one or more liquefied gas storage tanks and one or more CO2 storage tanks, and wherein the one or more valves are controlled by the first controller and/or the second controller thereby to control the flow of the liquefied gas and the CO2.

16 . A method of unloading/loading liquefied gas and carbon dioxide (CO2) at a location, the method comprising:

aligning one or more articulated rigid loading arms positioned at a location with one or more dual-fluid storage tanks positioned on a liquefied gas marine vessel, the one or more dual-fluid storage tanks including an outer compartment configured to store liquefied gas and a bladder connected to a wall within the outer compartment configured to store CO2;

connecting each of the one or more articulated rigid loading arms to the outer compartment or the bladder of each of the one or more dual-fluid storage tanks; and

if the outer compartment contains liquefied gas:

in response to reception of a first liquefied gas pump operation signal from a first controller and a second liquefied gas pump operation signal from a second controller, pumping a first liquefied gas from the outer compartment to one or more liquefied gas storage tanks and one of (a) a second liquefied gas from one or more liquefied gas storage tanks to the outer compartment or (b) CO2 from one or more CO2 storage tanks to the bladder, or

if the bladder contains CO2:

in response to reception of a first CO2 signal from the first controller and a signal from a second CO2 signal from the second controller, pumping CO2 from the bladder to one or more CO2 storage tanks at the location and the second liquefied gas from one or more liquefied gas storage tanks to the outer compartment.

17 . The method of claim 16 , wherein the CO2 comprises liquid CO2.

18 . The method of claim 16 , wherein the bladder comprises an expandable bladder that expands as the CO2 flows therein.

19 . The method of claim 16 , further comprising:

directing the CO2 from the one or more CO2 storage tanks via the first controller and the second controller to a dehydration unit positioned at the location; and

dehydrating the CO2 by operation of the dehydration unit via the second controller before loading the CO2 on the liquefied gas marine vessel.

20 . The method of claim 16 , wherein the first controller is located on the liquefied gas marine vessel, and wherein the second controller is located at the location.

21 . A controller for a liquefied gas marine vessel for transporting liquefied gas and carbon dioxide (CO2), the controller comprising:

a first input/output in signal communication with one or more temperature-control apparatuses positioned within an outer compartment of each of one or more dual-fluid storage tanks on a liquefied gas marine vessel and a bladder positioned within the outer compartment, the controller configured to obtain a first temperature of a liquefied gas contained within the outer compartment and a second temperature of CO2 contained within the bladder during unloading operations, onloading operations, and transport of the liquefied gas and CO2;

a second input/output in signal communication with one or more pressure-control apparatuses positioned within the outer compartment of each of one or more dual-fluid storage tanks and the bladder, the controller configured to obtain a first pressure of the liquefied gas contained within the outer compartment and a second pressure of CO2 contained within the bladder during one or more of the unloading operations, the onloading operations, or the transport of the liquefied gas and CO2;

a third input/output in signal communication with a first flow meter positioned at a first inlet of the outer compartment and a second flow meter positioned at a second inlet of the bladder, the controller configured to measure a first flow rate of the liquefied gas and a second flow rate of the CO2; and

a fourth input/output in signal communication with a first control valve, the first control valve designed to adjust flow of the liquefied gas via one or more unloading/loading pumps positioned on the liquefied gas marine vessel, thereby to modify the first flow rate of the liquefied gas, and a second flow control valve, the second control valve designed to adjust flow of the CO2 via the one or more unloading/loading pumps, thereby to modify the second flow rate, the controller configured to:

after initiation of the unloading operations or the onloading operations:

determine whether the first flow rate or the second flow rate is to be modified based on an outer compartment temperature, an outer compartment pressure, a bladder pressure, or a bladder temperature,

in response to a determination that the first flow rate is to be modified:

adjust a position of the first flow control valve that adjusts flow of the liquefied gas, thereby modifying the first flow rate, and

in response to a determination that the second flow rate is to be modified:

adjust a position of the second flow control valve that adjusts flow of the CO2, thereby modifying the second flow rate.

22 . The controller of claim 21 , wherein modification of the first flow rate or the second flow rate is based on a first amount of the liquefied gas within the outer compartment and a second amount of the CO2 within the bladder.

23 . The controller of claim 21 , wherein modification of the first flow rate or the second flow rate is based on a third amount of the liquefied gas within one or more liquefied gas storage tanks positioned at a location and a second amount of the CO2 within one or more CO2 storage tanks.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 29, 2024
From: THOBE, ZACHARY D.
To: MARATHON PETROLEUM COMPANY LP
Reel/Frame 067250/0188 →
Continuity (20)
Continuation 18234800 · Aug 16, 2023
Continuation In Part 18227472 · Jul 28, 2023
Continuation In Part 18217270 · Jun 30, 2023
Continuation In Part 18207722 · Jun 9, 2023
Continuation 18129926 · Apr 3, 2023
Continuation 18093747 · Jan 5, 2023
Continuation 18093756 · Jan 5, 2023
Continuation 18093741 · Jan 5, 2023
Division 18082656 · Dec 16, 2022
Division 17739488 · May 9, 2022
Continuation In Part 17739488 · May 9, 2022
Continuation In Part 17652530 · Feb 25, 2022
Division 17652530 · Feb 25, 2022
Division 17652530 · Feb 25, 2022
Continuation In Part 17652530 · Feb 25, 2022
Provisional Application 63377822 · Sep 30, 2022
Provisional Application 63267567 · Feb 4, 2022
Provisional Application 63265554 · Dec 16, 2021
Provisional Application 63200581 · Mar 16, 2021
Related Publication 20240271556A1 · Aug 15, 2024
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