Polymer particles and conductive particles having enhanced conducting properties, and anisotropic conductive packaging materials containing the same
Disclosed herein are anisotropic conductive particles contained in anisotropic conductive adhesive films, which can be used in circuit board mounting applications. The conductive particles can exhibit superior electrical reliability. Further disclosed are polymer particles having good compressive deformability and recoverability from deformation without being ruptured when an adhesive film containing conductive particles including the polymer particles as a component is interposed and compressed between connection substrates, thereby achieving a sufficient contact area between the particles and the connection substrates. Because the polymer particles have a spherical shape, a uniform particle diameter, and a narrow particle diameter distribution, the particles can exhibit enhanced conducting properties.
1. A polymer particle comprises a polymer resin comprising at least one crosslinking polymerizable monomer; a styrene-based monomer; and divinylbenzene, wherein said crosslinking polymerizable monomer comprises a monomer selected from the group consisting of allyl compounds, (poly)alkylene glycol di(meth)acrylates, (poly)dimethylsiloxane di(meth)acrylate, (poly)dimethylsiloxane divinyl, (poly)urethane di(meth)acrylate, pentaerythritol (meth)acrylates, methylolpropane (meth)acrylates, glycerol tri(meth)acrylate, and mixtures thereof and the polymer particle having a 10% K value (K value at 10% particle diameter compressive deformation) of about 250 to about 700 kgf/mm 2 and a compression recovery factor of about 30 to about 70%, wherein the polymer particle further has a 30% K value (K value at 30% compressive deformation) and a 40% K value (K value at 40% compressive deformation) of about 20 to about 70% of the 10% K value.
2. The polymer particle according to claim 1 , wherein the polymer particle has a 10% K value of about 350 to about 600 kgf/mm 2 .
3. The polymer particle according to claim 1 , wherein the polymer particle has a compression rupture deformation of about 40% or higher.
4. The polymer particle according to claim 1 , wherein the polymer particle has an average particle diameter of about 0.1 to about 200 μm.
5. The polymer particle according to claim 1 , wherein the polymer particle has an aspect ratio lower than about 1.5 and a coefficient of variation (CV) value not higher than about 20%.
6. The polymer particle according to claim 1 , wherein said allyl compound comprises at least one compound selected from the group consisting of 1,4-butanediol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, 1,9-nonanediol di(meth)acrylate, allyl (meth)acrylate, divinylsulfone, diallyl phthalate, diallylacrylamide, triallyl (iso)cyanurate, triallyl trimellitate, and mixtures thereof.
7. The polymer particle according to claim 1 , wherein said (poly)alkylene glycol di(meth)acrylate comprises at least one compound selected from the group consisting of (poly)ethylene glycol di(meth)acrylate, (poly)propylene glycol di(meth)acrylate, and mixtures thereof.
8. The polymer particle according to claim 1 , wherein said pentaerythritol (meth)acrylate comprises a compound selected from the group consisting of pentaerythritol tri(meth)acrylate, pentaerythritol di(meth)acrylate, dipentaerythritol hexa(meth)acrylate, dipentaerythritol penta(meth)acrylate, and mixtures thereof.
9. The polymer particle according to claim 1 , wherein said methylolpropane (meth)acrylate comprises a compound selected from the group consisting of trimethylolpropane tri(meth)acrylate, di(trimethylolpropane) tetra(meth)acrylate, tetramethylolpropane tetra(meth)acrylate, and mixtures thereof.
10. A conductive particle comprising:
a polymer particle comprises a polymer resin comprising at least one crosslinking polymerizable monomer; a styrene-based monomer; and divinylbenzene, wherein said crosslinking polymerizable monomer comprises a monomer selected from the group consisting of allyl compounds, (poly)alkylene glycol di(meth)acrylates, (poly)dimethylsiloxane di(meth)acrylate, (poly)dimethylsiloxane divinyl, (poly)urethane di(meth)acrylate, pentaerythritol (meth)acrylates, methylolpropane (meth)acrylates, glycerol tri(meth)acrylate, and mixtures thereof and the polymer particle having a 10% K value (K value at 10% particle diameter compressive deformation) of about 250 to about 700 kgf/mm 2 and a compression recovery factor of about 30 to about 70%, wherein the polymer particle further has a 30% K value (K value at 30% compressive deformation) and a 40% K value (K value at 40% compressive deformation) of about 20 to about 70% of the 10% K value, and
at least one conductive metal layer formed on the surface of the polymer particle.
11. The conductive particle according to claim 10 , wherein the conductive metal layer comprises at least one metal selected from the group consisting of nickel (Ni), gold (Au), silver (Ag), copper (Cu), platinum (Pt), palladium (Pd), cobalt (Co), tin (Sn), indium (In), indium tin oxide (ITO), and mixtures thereof.
12. The conductive particle according to claim 10 , wherein the conductive metal layer comprises a double layer of nickel and gold.
13. The conductive particle according to claim 10 , wherein the conductive metal layer has a thickness of about 0.01 to about 5 μm.
14. An anisotropic conductive packaging material comprising:
a polymer particle comprises a polymer resin comprising at least one crosslinking polymerizable monomer; a styrene-based monomer; and divinylbenzene, wherein said crosslinking polymerizable monomer comprises a monomer selected from the group consisting of allyl compounds, (poly)alkylene glycol di(meth)acrylates, (poly)dimethylsiloxane di(meth)acrylate, (poly)dimethylsiloxane divinyl, (poly)urethane di(meth)acrylate, pentaerythritol (meth)acrylates, methylolpropane (meth)acrylates, glycerol tri(meth)acrylate, and mixtures thereof and the polymer particle having a 10% K value (K value at 10% particle diameter compressive deformation) of about 250 to about 700 kgf/mm 2 and a compression recovery factor of about 30 to about 70%, wherein the polymer particle further has a 30% K value (K value at 30% compressive deformation) and a 40% K value (K value at 40% compressive deformation) of about 20 to about 70% of the 10% K value, and
at least one conductive metal layer formed on the surface of the polymer particle.
15. An electrical connection structure comprising:
a pair of facing substrates; and
an anisotropic conductive packaging material interposed between the facing substrates and comprising a polymer particle comprises a polymer resin comprising at least one crosslinking polymerizable monomer; a styrene-based monomer; and divinylbenzene, wherein said crosslinking polymerizable monomer comprises a monomer selected from the group consisting of allyl compounds, (poly)alkylene glycol di(meth)acrylates, (poly)dimethylsiloxane di(meth)acrylate, (poly)dimethylsiloxane divinyl, (poly)urethane di(meth)acrylate, pentaerythritol (meth)acrylates, methylolpropane (meth)acrylates, glycerol tri(meth)acrylate, and mixtures thereof and the polymer particle having a 10% K value (K value at 10% particle diameter compressive deformation) of about 250 to about 700 kgf/mm 2 and a compression recovery factor of about 30 to about 70%, wherein the polymer particle further has a 30% K value (K value at 30% compressive deformation) and a 40% K value (K value at 40% compressive deformation) of about 20 to about 70% of the 10% K value, and at least one conductive metal layer formed on the surface of the polymer particle.
16. The electrical connection structure according to claim 15 , wherein said anisotropic conductive packaging material is subjected to pressure while heating.
17. The conductive particle according to claim 10 , wherein the polymer particle comprises a polymer resin comprising crosslinking polymerizable monomer and divinyl benzene in an amount greater than zero weight percent and no greater than 40 weight percent; and a styrene-based monomer.
18. The polymer particle according to claim 1 , wherein the polymer particle comprises a polymer resin comprising crosslinking polymerizable monomer and divinyl benzene in an amount greater than zero weight percent and no greater than 40 weight percent; and a styrene-based monomer.