IP Library › Granted Patent US 7,964,502
Granted Patent B2
US 7,964,502 · App. 12/277,408 · Granted Jun 21, 2011

Multilayered through via

Assignee: Freescale Semiconductor, Inc.
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Quick Facts
Patent No.
US 7,964,502
App. No.
12/277,408
Granted
Jun 21, 2011
Kind
B2
Abstract

A method for forming a through substrate via (TSV) comprises forming an opening within a substrate. An adhesion layer of titanium is formed within the via opening, a nucleation layer of titanium nitride is formed over the adhesion layer, and a tungsten layer is deposited over the nucleation layer, the tungsten layer having a thickness less than or equal to a critical film thickness sufficient to provide for film integrity and adhesion stability. A stress relief layer of titanium nitride is formed over the tungsten layer and a subsequent tungsten layer is deposited over the stress relief layer. The subsequent tungsten layer has a thickness less than or equal to the critical film thickness. The method further includes planarizing to expose the interlevel dielectric layer and a top of the TSV and backgrinding a bottom surface of the substrate sufficient to expose a bottom portion of the TSV.

Claims (55)

1. A method for forming a through substrate via (TSV) in a semiconductor substrate having an interlevel dielectric layer overlying a top surface of the semiconductor substrate, the method comprising:

forming a via opening within the interlevel dielectric layer and the semiconductor substrate, the via opening having a depth less than a thickness of the semiconductor substrate;

forming an adhesion layer within the via opening, wherein the adhesion layer comprises titanium (Ti);

forming a nucleation layer over the adhesion layer, wherein the nucleation layer comprises titanium nitride (TiN);

depositing a first tungsten (W) layer over the nucleation layer, the first tungsten layer having a thickness less than or equal to a critical film thickness sufficient to provide for film integrity and adhesion stability;

forming a stress relief layer over the first tungsten layer, wherein the stress relief layer comprises titanium nitride (TiN);

depositing a subsequent tungsten layer over the stress relief layer, the subsequent tungsten layer having a thickness less than or equal to the critical film thickness sufficient to provide for film integrity and adhesion stability, wherein a portion of the subsequent tungsten layer, the stress relief layer, the first tungsten layer, the nucleation layer, and the adhesion layer which overlie the interlevel dielectric collectively comprise an overlying composite layer;

planarizing to remove the overlying composite layer and to expose the interlevel dielectric layer and a top of the TSV; and

backgrinding a bottom surface of the semiconductor substrate sufficient to expose a bottom of the TSV.

2. The method of claim 1 , wherein prior to planarizing, the method further comprising:

depositing a subsequent stress relief layer overlying the subsequent tungsten layer;

depositing of a still further tungsten layer overlying the subsequent stress relief layer; and

repeating the depositing of the subsequent stress relief layer and the depositing of the still further tungsten layer a number of times sufficient to achieve a desired filling of the via opening.

3. The method of claim 2 , wherein the desired filling of the via opening includes leaving a gap within the via opening, the method further comprising:

filling the gap with a dielectric material.

4. The method of claim 3 , wherein the dielectric material comprises a spin on glass or a sub-atmosphere chemical vapor deposition (SACVD) dielectric material.

5. The method of claim 1 , wherein the via opening comprises a blind via having an aspect ratio of up to 50:1.

6. The method of claim 1 , wherein the via opening has a width dimension between 0.5 to 3.0 microns (5000 to 30000 angstroms) and a depth dimension of greater than 4.0 microns (40000 angstroms) but less than the thickness of the semiconductor substrate.

7. The method of claim 1 , wherein forming the via opening includes forming an insulative coating liner within the via opening.

8. The method of claim 1 , wherein forming the via opening includes forming a tapered via opening, wherein a bottom dimension of the tapered via opening is smaller than a top dimension of the tapered via opening.

9. The method of claim 1 , wherein the adhesion layer has a thickness on the order of 0.01 to 0.04 microns (100 to 400 angstroms), wherein the nucleation layer has a thickness on the order of 0.01 to 0.04 microns (100 to 400 angstroms), wherein the tungsten layer has a thickness on the order of up to 1.0 microns (10000 angstroms), wherein the stress relief layer has a thickness greater than a minimum thickness sufficient to overcome a surface roughness of the tungsten layer, and wherein the subsequent tungsten layer has a thickness on the order of up to 1.0 microns (10000 angstroms).

10. The method of claim 1 , wherein forming the adhesion layer comprises using ion metal plasma (IMP) deposition, wherein forming the nucleation layer comprises using chemical vapor deposition (CVD), wherein depositing the tungsten layer includes using chemical vapor deposition (CVD), wherein forming the stress relief layer comprises using physical vapor deposition (PVD) or chemical vapor deposition (CVD), and wherein depositing the subsequent tungsten layer includes using chemical vapor deposition (CVD).

11. The method of claim 1 , wherein for thicknesses greater than the critical film thickness, the tungsten layer would be prone to undesirable flaking characteristics.

12. The method of claim 1 , wherein depositing the tungsten layer and the subsequent tungsten layer comprise conformal depositing the tungsten layer and the subsequent tungsten layer.

13. The method of claim 1 , wherein the via opening has a width dimension at a top portion thereof which is subject to becoming constricted by the deposition of one or more of the first, subsequent, and further tungsten layers and which prevents the deposition of a yet further tungsten layer within the via opening sufficient to achieve a desired filling of the via opening, the method further comprising:

performing an etch back of a corresponding layer responsible for causing a constriction subsequent to the depositing of the one or more of the first, subsequent, and further tungsten layers, wherein the etch back enables deposition of still further layers within the via opening;

depositing an additional layer within the via opening, wherein the additional layer comprises one or more of a further adhesion layer, a further nucleation layer, and a further stress relief layer; and

depositing the yet further tungsten layer overlying the additional layer within the via opening.

14. The method of claim 1 , wherein prior to the backgrinding, the method further comprising:

forming contact plug via openings within the interlevel dielectric layer and overlying an active device within the semiconductor substrate;

filling the contact plug via openings with tungsten; and

after filling the contact plug via openings, planarizing a top surface of the contact plug via openings to form completed contact plugs.

15. The method of claim 14 , wherein prior to the backgrinding, the method further comprising:

forming an interconnect layer overlying the completed contact plugs and the TSV.

16. The method of claim 1 , wherein the TSV comprises one of a trench via, an annular via, and a sidewall via.

17. A method for forming a through substrate via (TSV) in a semiconductor substrate having an interlevel dielectric layer overlying a top surface of the semiconductor substrate, the method comprising:

forming a via opening within the interlevel dielectric layer and the semiconductor substrate, the via opening having a depth less than a thickness of the semiconductor substrate;

forming an adhesion layer within the via opening, wherein the adhesion layer comprises titanium (Ti);

forming a nucleation layer over the adhesion layer, wherein the nucleation layer comprises titanium nitride (TiN);

depositing a first tungsten (W) layer over the nucleation layer, the first tungsten layer having a thickness less than or equal to a critical film thickness sufficient to provide for film integrity and adhesion stability;

forming a stress relief layer over the first tungsten layer, wherein the stress relief layer comprises titanium nitride (TiN);

depositing a subsequent tungsten layer over the stress relief layer, the subsequent tungsten layer having a thickness less than or equal to the critical film thickness sufficient to provide for film integrity and adhesion stability, wherein a portion of the subsequent tungsten layer, the stress relief layer, the first tungsten layer, the nucleation layer, and the adhesion layer which overlie the interlevel dielectric layer collectively comprise an overlying composite layer;

planarizing to remove the overlying composite layer and to expose the interlevel dielectric layer and a top of the TSV;

forming contact plug via openings within the interlevel dielectric layer and overlying an active device within the semiconductor substrate;

filling the contact plug via openings with tungsten;

after filling the contact plug via openings, planarizing a top surface of the contact plug via openings to form completed contact plugs; and

backgrinding a bottom surface of the semiconductor substrate sufficient to expose a bottom of the TSV, wherein the TSV comprises one of a trench via, an annular via, and a sidewall via.

18. The method of claim 17 , wherein prior to planarizing, the method further comprising:

depositing a subsequent stress relief layer overlying the subsequent tungsten layer;

depositing of a still further tungsten layer overlying the subsequent stress relief layer; and

repeating the depositing of the subsequent stress relief layer and the depositing of the still further tungsten layer a number of times sufficient to achieve a desired filling of the via opening, wherein the desired filling of the via opening includes leaving a gap within the via opening and filling the gap with a dielectric material, wherein the dielectric material comprises a spin on glass or a sub-atmosphere chemical vapor deposition (SACVD) dielectric material.

19. The method of claim 17 , wherein the via opening has a width dimension at a top portion thereof which is subject to becoming constricted by the deposition of one or more of the first, subsequent, and further tungsten layers and which prevents deposition of a yet further tungsten layer within the via opening sufficient to achieve a desired filling of the via opening, the method further comprising:

performing an etch back of a corresponding layer responsible for causing a constriction subsequent to the deposition of the one or more of the first, subsequent, and further tungsten layers, wherein the etch back enables deposition of still further layers within the via opening;

depositing an additional layer within the via opening, wherein the additional layer comprises one or more of a further adhesion layer, a further nucleation layer, and a further stress relief layer; and

depositing the yet further tungsten layer overlying the additional layer within the via opening.

Assignments (18)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE PREVIOUSLY RECORDED AT REEL: 040632 FRAME: 0001. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER AND CHANGE OF NAME. Recorded Sep 21, 2017
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
Reel/Frame 044209/0047 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
Reel/Frame 040632/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039138/0001 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0807 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →
SECURITY AGREEMENT Recorded Jun 18, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 030633/0424 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 10, 2011
From: DAO, THUY B.; VUONG, CHANH M.
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 025788/0781 →
SECURITY AGREEMENT Recorded Mar 12, 2009
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A.
Reel/Frame 022380/0409 →
Continuity (1)
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