IP Library Granted Patent US 9,057,787
Granted Patent B2
US 9,057,787 · App. 13/868,654 · Granted Jun 16, 2015

Colorimetric radiation dosimetry based on functional polymer and nanoparticle hybrid

Inventors: Qing Cao (Yorktown Heights, NY); Kangguo Cheng (Schenectady, NY); Zhengwen Li (Scarsdale, NY); Fei Liu (Yorktown Heights, NY); Zhen Zhang (Ossining, NY)
Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATION
G01T1/06
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Quick Facts
Patent No.
US 9,057,787
App. No.
13/868,654
Filed
Apr 23, 2013
Granted
Jun 16, 2015
Kind
B2
Art Unit
2884
USPC
250/473.1
Abstract

A method for colorimetric radiation dosimetry includes subjecting an aggregate including a polymeric matrix having uniformly dispersed nanoparticles therein to radiation. The aggregate is soaked in a solution selected to dissolve decomposed pieces of the polymeric matrix to release into the solution nanoparticles from the decomposed pieces. Color of the solution is compared to a reference to determine a dose of radiation based on number of liberated nanoparticles.

Claims (23)

1. A method for colorimetric radiation dosimetry, comprising:

subjecting an aggregate including a polymeric matrix having uniformly dispersed nanoparticles therein to radiation;

soaking the aggregate in a solution selected to dissolve decomposed pieces of the polymeric matrix to release into the solution nanoparticles from the decomposed pieces; and

comparing color of the solution to a reference to determine a dose of radiation based on number of liberated nanoparticles from said uniformly dispersed nanoparticles that were released from the polymeric matrix of the aggregate into the solution, when the aggregate was said soaking in the solution.

2. The method as recited in claim 1 , wherein the polymeric matrix includes polymethyl methacrylate and a radiation type to be measured includes beta radiation.

3. The method as recited in claim 1 , wherein the polymeric matrix includes poly (olefin sulfones) and a radiation type to be measured includes gamma radiation.

4. The method as recited in claim 1 , wherein the nanoparticles include at least one of gold nanoparticles and quantum nanodots.

5. The method as recited in claim 1 , wherein soaking the aggregate in the solution includes soaking the aggregate in alcohol solution.

6. The method as recited in claim 1 , wherein comparing the color includes analyzing absorption spectra of the solution with the liberated nanoparticles.

7. The method as recited in claim 6 , wherein analyzing absorption spectra includes measuring absorption spectra at wavelengths of at least one of 522 nanometers and 700 nanometers for gold nanoparticles.

8. The method as recited in claim 1 , wherein comparing the color includes comparing the color to a visual reference to determine radiation dose.

9. A method for colorimetric radiation dosimetry, comprising:

forming an aggregate material including a polymeric matrix having uniformly dispersed nanoparticles therein;

subjecting the aggregate material to radiation or a potential radiation source;

soaking the aggregate material in a solution selected to dissolve decomposed pieces of the polymeric matrix to release into the solution nanoparticles from the decomposed pieces; and

comparing color of the solution to a reference to determine a dose of radiation based on number of liberated nanoparticles from said uniformly dispersed nanoparticles that were released from the polymeric matrix of the aggregate into the solution, when the aggregate was said soaking in the solution.

10. The method as recited in claim 9 , wherein the polymeric matrix includes at least one of: polymethyl methacrylate and a radiation type to be measured includes beta radiation; and poly (olefin sulfones) and the radiation type to be measured includes gamma radiation.

11. The method as recited in claim 9 , wherein forming the aggregate material includes employing a HAuCl 4 precursor mixed with the polymer material in acetone to provide gold nanoparticles in the aggregate material.

12. The method as recited in claim 9 , wherein soaking the aggregate in the solution includes soaking the aggregate in alcohol solution.

13. The method as recited in claim 9 , wherein comparing the color includes analyzing absorption spectra of the solution with the liberated nanoparticles.

14. The method as recited in claim 13 , wherein analyzing absorption spectra includes measuring absorption spectra at wavelengths of at least one of 522 nanometers and 700 nanometers for gold nanoparticles.

15. The method as recited in claim 9 , wherein comparing the color includes comparing the color to a visual reference to determine radiation dose.

16. The method as recited in claim 9 , wherein forming the aggregate material includes shaping the aggregate material into one or more of an article of clothing, a shaped three-dimensional object and a film on an object.

Assignments (6)
RELEASE OF SECURITY INTEREST Recorded May 12, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 056987/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 20, 2020
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES INC.
Reel/Frame 054636/0001 →
SECURITY AGREEMENT Recorded Nov 29, 2018
From: GLOBALFOUNDRIES INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 049490/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 5, 2015
From: GLOBALFOUNDRIES U.S. 2 LLC; GLOBALFOUNDRIES U.S. INC.
To: GLOBALFOUNDRIES INC.
Reel/Frame 036779/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 3, 2015
From: INTERNATIONAL BUSINESS MACHINES CORPORATION
To: GLOBALFOUNDRIES U.S. 2 LLC
Reel/Frame 036550/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 23, 2013
From: CAO, QING; CHENG, KANGGUO; LI, ZHENGWEN; LIU, FEI; ZHANG, ZHEN
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 030268/0600 →
Continuity (1)
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