Intermetallic nanoparticles
A process for preparing intermetallic nanoparticles of two or more metals is provided. In particular, the process includes the steps: a) dispersing nanoparticles of a first metal in a solvent to prepare a first metal solution, b) forming a reaction mixture with the first metal solution and a reducing agent, c) heating the reaction mixture to a reaction temperature; and d) adding a second metal solution containing a salt of a second metal to the reaction mixture. During this process, intermetallic nanoparticles, which contain a compound with the first and second metals are formed. The intermetallic nanoparticles with uniform size and a narrow size distribution is also provided. An electrochemical device such as a battery with the intermetallic nanoparticles is also provided.
1. Intermetallic nanoparticles comprising:
a first metal (M1) selected from the group consisting of: Sn, Pb, Sb, In, Ga, Bi, Ge, Zn; and
a second metal (M2) selected from the group consisting of: Cu, Ag, Au, Pt, Pd, Ru, Ir, Fe, Co, Ni, wherein the intermetallic nanoparticles comprise a compound comprising the first metal and the second metal, and the average diameter of the intermetallic nanoparticles is from about 100 nm to about 400 nm
wherein the intermetallic nanoparticles have a chemical formula M1xM2y, wherein “x” is an integer between 1 to 8, “y” is an integer between 1 to 8.
2. The intermetallic nanoparticles of claim 1 , wherein the first metal is Sn and the second metal is Cu.
3. The intermetallic nanoparticles of claim 2 further comprising a substituted metal (MS) selected from the group consisting of Ni, Zn, Fe, wherein the intermetallic nanoparticles have a chemical formula MS 1 M1xM2y −1 , wherein “x” is an integer between 1 to 8, “y” is an integer between 1 to 8.
4. The intermetallic nanoparticles of claim 1 wherein the first metal is Sn and the second metal is Cu and further comprising a third metal (M3) selected from the group consisting of: Ag, Ag, Au, Pt, Pd, Ru, Ir wherein the intermetallic nanoparticles have a chemical formula M1xM2yM3z, wherein “x” is an integer between 1 to 8, “y” is an integer between 1 to 8, and z is an integer from 1 to 8.
5. Intermetallic nanoparticles comprising:
a first metal (M1) selected from the group consisting of: Sn, Pb, Sb, In, Ga, Bi, Ge, Zn; and
a second metal (M2) selected from the group consisting of: Cu, Ag, Au, Pt, Pd, Ru, Ir, Fe, Co, Ni; and
and a third metal (M3) selected from the group consisting of: Ag, Ag, Au, Pt, Pd, Ru, Ir;
wherein the intermetallic nanoparticles comprise a compound comprising the chemical formula M1xM2yM3z, wherein “x” is an integer between 1 to 8, “y” is an integer between 1 to 8, and “z” is an integer from 0 to 8.
6. The intermetallic nanoparticles of claim 5 , wherein the first metal is Sn and the second metal is Cu.
7. The intermetallic nanoparticles of claim 6 wherein the second metal is Cu.
8. The intermetallic nanoparticles of claim 6 , wherein the average diameter of the intermetallic nanoparticles is from about 100 nm to about 400 nm.