High molecular weight polyacrylates for aluminum protection in warewash applications
A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, high molecular weight polyacrylates (polyacrylic acid homopolymers) with a molecular weight of at least about 5000 are used as corrosion inhibitors and can be included for aluminum protection in a number of different detergent compositions.
1. A detergent composition comprising:
(a) an alkaline source in an amount effective to provide a use composition having a pH of at least about 8 and obtained by diluting the detergent composition with water;
(b) a corrosion inhibitor component in an amount sufficient for reducing corrosion of aluminum or aluminum containing alloys, the corrosion inhibitor component comprising one or more polyacrylic acid homopolymers having a molecular weight of at least about 5,000 daltons, wherein said sufficient amount of corrosion inhibitor is greater than 10 wt. % and 30 wt. %; and
(c) less than about 0.1% by weight of phosphorous, wherein said composition does not contain polymaleic acid polymers, wherein said composition does not include sodium carbonate, wherein said composition does not include an active oxygen source bleaching agent, and wherein said composition does not include 1-hydroxy ethylidene 1-1-diphosphonic acid.
2. The detergent composition according to claim 1 further comprising:
(d) a cleaning agent comprising a detersive amount of a surfactant.
3. The detergent composition according to claim 2 , wherein the detergent composition comprises between about 0.5 wt. % and about 20 wt. % of the cleaning agent.
4. The detergent composition according to claim 1 , wherein the corrosion inhibitor component comprises one or more polyacrylic acid homopolymers having a molecular weight of greater than 10,000 daltons.
5. The detergent composition according to claim 4 , wherein the corrosion inhibitor component comprises one or more polyacrylic acid homopolymers having a molecular weight of greater than 50,000 daltons.
6. The detergent composition according to claim 5 , wherein the corrosion inhibitor component comprises one or more polyacrylic acid homopolymers having a molecular weight of 70,000 daltons or greater.
7. The detergent composition according to claim 5 , wherein the corrosion inhibitor component comprises one or more polyacrylic acid homopolymers having a molecular weight of 100,000 daltons or greater.
8. The detergent composition according to claim 1 , wherein the detergent composition comprises greater than 10 wt. % and equal to or less than about 25 wt. % of active corrosion inhibitor component.
9. The detergent composition according to claim 2 , wherein the cleaning agent comprises at least one of an anionic surfactant, a nonionic surfactant, a cationic surfactant, or a zwitterionic surfactant.
10. The detergent composition according to claim 1 , wherein the alkaline source comprises a metal silicate.
11. The detergent composition according to claim 1 wherein the detergent comprise less than about 0.05% by weight of phosphorous.