IP Library Granted Patent US 9,759,680
Granted Patent B2
US 9,759,680 · App. 15/135,921 · Granted Sep 12, 2017

Method and system for diamond-based oxygen sensor

Inventors: Mihai Brezeanu (Bucharest, RO); Bogdan-Catalin Serban (Bucharest, RO); Viorel Georgel Dumitru (Prahova, RO); Octavian Buiu (Bucharest, RO)
Assignee: Honeywell International Inc.
G01N27/4141H01L29/1602H01L29/45C30B29/04
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Quick Facts
Patent No.
US 9,759,680
App. No.
15/135,921
Granted
Sep 12, 2017
Kind
B2
Abstract

A diamond based oxygen sensor is able to function in harsh environment conditions. The oxygen sensor includes a gateless field effect transistor including a synthetic, quasi-intrinsic, hydrogen-passivated, monocrystalline diamond layer exhibiting a 2-dimension hole gas effect. The oxygen sensor also includes a sensing layer comprising yttrium-stabilized zirconia deposited onto a surface of the gateless field effect transistor.

Claims (45)

1. An oxygen sensor, comprising:

a diamond substrate;

a gateless field effect transistor (FET) connected to the diamond substrate, the FET including:

a synthetic diamond layer exhibiting a 2-dimension hole gas effect;

a first highly-doped p-type region;

a second highly-doped p-type region; and

a 2-dimension hole gas conductive channel between the first highly-doped p-type region and the second highly-doped p-type region; and

an oxygen-sensing layer including a yttrium-stabilized zirconia (YSZ) supported by the gateless FET.

2. The oxygen sensor of claim 1 , wherein:

the first highly-doped p-type region is implanted within the synthetic diamond layer; and

the second highly-doped p-type region is implanted within the synthetic diamond layer.

3. The oxygen sensor of claim 1 , the synthetic diamond layer including a quasi-intrinsic and hydrogen-passivated synthetic diamond layer.

4. The oxygen sensor of claim 1 , the gateless FET further including:

an ohmic source contact electrically coupled to the first highly-doped p-type region; and

an ohmic drain contact electrically coupled to the second highly-doped p-type region.

5. The oxygen sensor of claim 3 , wherein:

the oxygen-sensing layer is supported by the 2-dimension hole gas conductive channel and electrically coupled between the ohmic source contact and the ohmic drain contact.

6. The oxygen sensor of claim 1 , the diamond substrate including a polycrystalline diamond substrate.

7. The oxygen sensor of claim 6 , wherein the synthetic diamond layer is grown on a first side of the polycrystalline diamond substrate.

8. The oxygen sensor of claim 7 , the gateless FET further including an ohmic contact substrate supported by a second side of the polycrystalline diamond substrate.

9. The oxygen sensor of claim 2 , wherein:

the first highly-doped p-type region is implanted within the synthetic diamond layer using boron implantation; and

the second highly-doped p-type region is implanted within the synthetic diamond layer using boron implantation.

10. The oxygen sensor of claim 1 , wherein:

the 2-dimension hole gas conductive channel is formed within the synthetic diamond layer by performing hydrogen passivation.

11. The oxygen sensor of claim 4 , wherein the ohmic source contact and the ohmic drain contact are formed using a stack of Ti/Au.

12. A method of forming a gateless FET oxygen sensor, comprising:

forming a gateless field effect transistor (FET) connected to a diamond substrate, the FET including:

a synthetic diamond layer exhibiting a 2-dimension hole gas effect;

a first highly-doped p-type region;

a second highly-doped p-type region; and

a 2-dimension hole gas conductive channel between the first highly-doped p-type region and the second highly-doped p-type region; and

forming an oxygen-sensing layer including a yttrium-stabilized zirconia (YSZ) supported by the gateless FET.

13. The oxygen sensor of claim 12 , wherein forming the gateless FET includes growing the synthetic diamond layer on a first side of the diamond substrate, the diamond substrate including a polycrystalline diamond substrate.

14. The oxygen sensor of claim 12 , wherein forming the gateless FET further includes:

implanting the first highly-doped p-type region within the synthetic diamond layer; and

implanting the second highly-doped p-type region within the synthetic diamond layer.

15. The oxygen sensor of claim 12 , wherein generating the synthetic diamond layer includes generating a quasi-intrinsic, hydrogen-passivated monocrystalline diamond layer between the first highly-doped p-type region and the second highly-doped p-type region.

16. The oxygen sensor of claim 12 , wherein forming the gateless FET further includes:

disposing an ohmic source contact on the first highly-doped p-type region; and

disposing an ohmic drain contact on the second highly-doped p-type region.

17. The oxygen sensor of claim 12 , wherein forming the gateless FET further includes disposing an ohmic contact substrate on a second side of the diamond substrate.

18. The oxygen sensor of claim 12 , wherein the first highly-doped p-type region and the second highly-doped p-type region are generated within the synthetic diamond layer using boron implantation.

19. The oxygen sensor of claim 12 , wherein the 2-dimension hole gas conductive channel is generated within the synthetic diamond layer by performing hydrogen passivation.

20. The oxygen sensor of claim 16 , wherein the ohmic source contact and the ohmic drain contact are formed using a stack of Ti/Au.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 4, 2016
From: BREZEANU, MIHAI; SERBAN, BOGDAN-CATALIN; DUMITRU, VIOREL GEORGEL; BUIU, OCTAVIAN
To: HONEYWELL INTERNATIONAL INC.
Reel/Frame 040232/0107 →
Priority Claims (1)
EP 14182173 · Aug 25, 2014 · regional
Continuity (2)
Continuation 14828718 · Aug 18, 2015
Related Publication 20160238552A1 · Aug 18, 2016