Drilling composition, process for its preparation, and applications thereof
The present invention relates to a drilling composition comprising: I) an organic phase comprising components i, from about 20 wt. % to about 99,999 wt. %, based on the total weight of components i. and ii., of at least one linear or branched, cyclic or non-cyclic, saturated hydrocarbon, ii. from about 0.001 wt % to about 25 wt. %, based on the total weight of components i. and ii., of at least one ester, II) from 0 to about 50 wt. %, based on the total weight of the composition, of water or aqueous phase, III) from 0 to about 60 wt. %, based on the total weight of the composition, of at least one additive, wherein the sum of the weight components I) to III) is 100 wt %, to a process for preparation of a drilling composition, to uses of a drilling composition, to a drilling system, to a process for making a borehole, to a process for conveying cuttings, to a process for treating a drill head, to a process for production of at least one of oil and gas.
1. A process for the preparation of a drilling composition, comprising the steps of:
a) providing component i) of from 92 wt. % to 98 wt. %, based on a total amount of i) and ii), of at least one linear or branched, cyclic or non-cyclic, saturated hydrocarbon,
b) providing component ii) of from 2 wt. % to 8 wt. %, based on the total amount of i) and ii), of at least one ester having a carbon chain distribution of an acid-derived component with carbon numbers in the ranges of from 0 to 0.50% C 6 , from 4.00% to 7.00% C 8 , from 5.00% to 8.00% C 10 , from 60.00% to 80.00% C 12 , from 10.00 to 20.00% C 14 , from 2.00 to 4.00% C 16 and from 0.1 to 0.60% C 18 , wherein the ester has a viscosity determined using a Brookfield RVT viscometer (Brookfield, RVT viscosity) at temperatures of 0° C. to 5° C. of not more than 10 mPas and a non-toxicity measured by the 96 hour LC 50 Mysid shrimp acute toxicity bioassay test result of greater than 800,000, and wherein the sum of the weight amounts provided in a) and b) is 100 wt. %,
c) combining component i) and component ii),
wherein the sum of the weight components i) to ii) is 100 wt. % and wherein at least 50% of the ester is based on saturated aliphatic C 12 -C 14 monocarboxylic acids and a monofunctional C 2 -C 12 alcohol or mixtures thereof.
2. The process according to claim 1 , wherein the at least one hydrocarbon is at least one alkane.
3. The process according to claim 1 , wherein the at least one hydrocarbon comprises at least one iso-alkane.
4. The process according to claim 1 , wherein the hydrocarbon comprises at least one C 10 to C 25 alkane selected from the group consisting of n-alkanes, i-alkanes, sec-alkanes, tert-alkanes, or a mixture of two or more thereof.
5. The process according to claim 1 , wherein the hydrocarbon comprises a polynuclear aromatic content measured by high resolution mass spectrometry of less than 50 ppm, whereby wt. % and ppm amounts are based on a total amount of component i.
6. The process according to claim 1 , wherein the hydrocarbon comprises a viscosity of between 1 and 10 centistokes.
7. The process according to claim 1 , wherein the hydrocarbon comprises a viscosity of less than 7 centistokes.
8. The process according to claim 1 , wherein the hydrocarbon comprises a pour point in the range from −60° C. to −10° C.
9. A process for preparation of a drilling composition, comprising the steps:
A) preparing an organic phase comprising components i from 92 wt. % to 98 wt. %, based on the total weight of components i and ii, of at least one linear or branched, cyclic or non-cyclic, saturated hydrocarbon, ii from 2 wt. % to 8 wt. %, based on the total weight of components i and ii, of at least one ester having a carbon chain distribution of an acid-derived component with carbon numbers in the ranges of from 0 to 0.50% C 6 , from 4.00% to 7.00% C 8 , from 5.00% to 8.00% C 10 , from 60.00% to 80.00% C 12 , from 10.00 to 20.00% C 14 , from 2.00 to 4.00% C 16 and from 0.1 to 0.60% C 18 , wherein the ester has a viscosity determined using a Brookfield RVT viscometer (Brookfield, RVT viscosity) at temperatures of 0° C. to 5° C. of not more than 10 mPas and a non-toxicity measured by the 96 hour LC 50 Mysid shrimp acute toxicity bioassay test result of greater than 800,000;
B) preparing an aqueous phase comprising from 50 wt. % to 100 wt. % water, based on a total amount of aqueous phase;
C) combining the organic phase prepared in step A) with from 0 to 50 wt. %, based on the total weight of the composition, of the aqueous phase prepared in step B); and
D) combining at least one of the organic phase, the aqueous phase and the combination of the organic phase and the aqueous phase with from 0 to 60 wt. %, based on the total weight of the composition, of at least one additive.
10. The process according to claim 9 , further comprising a step E) homogenization.
11. The process according to claim 10 , wherein the composition at the end of at least one of steps C), D) or E) is in the form of an emulsion.
12. The process according to claim 11 , wherein the emulsion is a nanoemulsion or a microemulsion with droplet sizes in the range from 5 nm to 1000 μm.
13. A process for making a borehole comprising the steps of:
a1) providing a drilling composition comprising
I) an organic phase comprising components
i. from 92 wt. % to 98 wt. %, based on the total weight of components i. and ii., of at least one linear or branched, cyclic or non-cyclic, saturated hydrocarbon,
ii. from 2 wt. % to 8 wt. %, based on the total weight of components i. and ii., of at least one ester having a carbon chain distribution of an acid-derived component with carbon numbers in the ranges of from 0 to 0.50% C 6 , from 4.00% to 7.00% C 8 , from 5.00% to 8.00% C 10 , from 60.00% to 80.00% C 12 , from 10.00 to 20.00% C 14 , from 2.00 to 4.00% C 16 and from 0.1 to 0.60% C 18 , wherein the ester has a viscosity determined using a Brookfield RVT viscometer (Brookfield, RVT viscosity) at temperatures of 0° C. to 5° C. of not more than 10 mPas and a non-toxicity measured by the 96 hour LC 50 Mysid shrimp acute toxicity bioassay test result of greater than 800,000,
II) from 0 to 50 wt. %, based on the total weight of the composition, of water or aqueous phase, and
III) from 0 to 60 wt. %, based on the total weight of the composition, of at least one additive,
wherein the sum of the weight components I) to III) is 100 wt. % and wherein at least 50% of the ester is based on saturated aliphatic C 12 -C 14 monocarboxylic acids and a monofunctional C 2 -C 12 alcohol or mixtures thereof;
a2) drilling a hole in a subterranean formation; and
a3) circulating the composition provided in a1) at least partially in the hole at least partially while drilling.
14. The process according to claim 13 , wherein the at least one hydrocarbon is at least one alkane.
15. The process according to claim 13 , wherein the at least one hydrocarbon comprises at least one iso-alkane.
16. The process according to claim 13 , wherein the hydrocarbon comprises at least one C 10 to C 25 alkane selected from the group consisting of n-alkanes, i-alkanes, sec-alkanes, tert-alkanes, or a mixture of two or more thereof.
17. The process according to claim 13 , wherein the hydrocarbon comprises a polynuclear aromatic content measured by high resolution mass spectrometry of less than 50 ppm, whereby wt. % and ppm amounts are based on a total amount of component i.
18. The process according to claim 13 , wherein the hydrocarbon comprises a viscosity of between 1 and 10 centistokes.
19. The process according to claim 13 , wherein the hydrocarbon comprises a pour point in the range from −60° C. to −10° C.