Dispersion of polymer particles in a non-aqueous medium and cosmetic use thereof
Provided is a dispersion of polymer particles, wherein the polymer is surface-stabilized with a stabilizer in a non-aqueous medium containing at least one hydrocarbon-based oil. The polymer of the particles is a C1-C4 alkyl (meth)acrylate polymer; and the stabilizer is an isobornyl (meth)acrylate polymer. Also provided is a composition that comprises the dispersion of polymer particles. The dispersion can be used as a cosmetic for caring for and making up of keratin materials.
1. A dispersion of particles of at least one polymer that is surface-stabilized with a stabilizer in a non-aqueous medium containing at least one apolar hydrocarbon-based oil containing from 8 to 16 carbon atoms, the polymer of the particles comprising a C1-C4 alkyl (meth)acrylate monomer; the stabilizer being an isobornyl (meth)acrylate polymer chosen from isobornyl (meth)acrylate homopolymer and statistical copolymers of isobornyl (meth)acrylate and of C1-C4 alkyl (meth)acrylate present in an isobornyl (meth)acrylate/C1-C4 alkyl (meth)acrylate weight ratio of greater than 4; wherein the polymer of the particles is present in a content ranging from 21% to 58.5% by weight relative to the total weight of the dispersion; and the amount of the stabilizer is from 15% to 30% by weight based upon the total weight of monomers of the stabilizer and particles of the at least one polymer and wherein the particles of the at least one polymer have an average size ranging from 50 to 500 nm.
2. The dispersion according to claim 1 , wherein the polymer of the particles is a methyl acrylate and/or ethyl acrylate polymer.
3. The dispersion according to claim 1 , wherein the polymer of the particles further comprises an ethylenically unsaturated acid monomer or the anhydride thereof.
4. The dispersion according to claim 1 , wherein the polymer of the particles comprises from 80% to 100% by weight of a C1-C4 alkyl (meth)acrylate and from 0 to 20% by weight of an ethylenically unsaturated acid monomer, relative to the total weight of the polymer.
5. The dispersion according to claim 1 , wherein the polymer of the particles is chosen from:
methyl acrylate homopolymers
ethyl acrylate homopolymers
methyl acrylate/ethyl acrylate copolymers
methyl acrylate/ethyl acrylate/acrylic acid copolymers
methyl acrylate/ethyl acrylate/maleic anhydride copolymers
methyl acrylate/acrylic acid copolymers
ethyl acrylate/acrylic acid copolymers
methyl acrylate/maleic anhydride copolymers and
ethyl acrylate/maleic anhydride copolymers.
6. The dispersion according to claim 1 , wherein the stabilizer is a statistical copolymer of isobornyl (meth)acrylate and of C1-C4 alkyl (meth)acrylate present in an isobornyl (meth)acrylate/C1-C4 alkyl (meth)acrylate weight ratio greater than or equal to 5.
7. The dispersion according to claim 1 , wherein the stabilizer is chosen from:
isobornyl acrylate homopolymers
statistical copolymers of isobornyl acrylate/methyl acrylate
statistical copolymers of isobornyl acrylate/methyl acrylate/ethyl acrylate and
statistical copolymers of isobornyl methacrylate/methyl acrylate.
8. The dispersion according to claim 1 , wherein the combination of the stabilizer and polymer of the particles present in the dispersion comprises from 10% to 50% by weight of polymerized isobornyl (meth)acrylate and from 50% to 90% by weight of polymerized C1-C4 alkyl (meth)acrylate, relative to the total weight of the combination of the stabilizer and polymer of the particles.
9. The dispersion according to claim 1 , wherein the hydrocarbon-based oil is isododecane.
10. The dispersion according to claim 1 , which comprises from 30% to 65% by weight of solids, relative to the total weight of the dispersion.
11. The dispersion according to claim 1 , which comprises a plasticizer chosen from tri-n-butyl citrate, tripropylene glycol monomethyl ether and trimethyl pentaphenyl trisiloxane.
12. A composition comprising, in a physiologically acceptable medium, a polymer dispersion according to claim 1 .
13. The composition according to claim 12 , which comprises a cosmetic additive chosen from water, fragrances, preserving agents, fillers, dyestuffs, UV-screening agents, oils, waxes, surfactants, moisturizers, vitamins, ceramides, antioxidants, free-radical scavengers, polymers and thickeners.
14. A non-therapeutic cosmetic process for treating keratin materials, comprising the application to the keratin materials of a composition according to claim 13 .
15. The dispersion according to claim 1 , wherein the polymer of the particles comprises an ethylenically unsaturated acid monomer or the anhydride thereof chosen from (meth)acrylic acid, maleic acid and maleic anhydride.
16. The dispersion according to claim 2 , wherein the polymer of the particles comprises an ethylenically unsaturated acid monomer or the anhydride thereof chosen from (meth)acrylic acid, maleic acid and maleic anhydride.
17. The dispersion according to claim 1 , wherein the polymer of the particles comprises from 80% to 100% by weight of C1-C4 alkyl (meth)acrylate and from 0 to 20% by weight of ethylenically unsaturated acid monomer, relative to the total weight of the polymer.
18. The dispersion according to claim 1 , wherein the polymer of the particles is present in a content ranging from 36% to 42% by weight relative to the total weight of the dispersion.