IP Library › Granted Patent US 10,093,564
Granted Patent B2
US 10,093,564 · App. 15/388,767 · Granted Oct 9, 2018

Chelating base product for use in water-based system treatments

Inventors: David Nicholas (Gulf Breeze, FL); Reid Henry Bowman (Fort Collins, CO); Freddie L. Singleton (Fruit Cove, FL)
Assignee: Earth Science Laboratories
C02F1/683C02F2101/10
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 10,093,564
App. No.
15/388,767
Granted
Oct 9, 2018
Kind
B2
Abstract

A base product fluid is produced by adding anhydrous liquid ammonia and a first portion of sulfuric acid to water in a process line to form a mixed fluid. The mixed fluid may be cooled and a second portion of sulfuric acid may be added to the mixed fluid to form the base product fluid. The base product fluid may include a molecular compound that is a chelating compound. The molecular compound may have the formula: ((NH 4 ) 2 SO 4 ) a .(H 2 SO 4 ) b .(H 2 O) c .(NH 4 HSO 4 ) x . In the formula, a may be between 1 and 5, b may be between 1 and 5, c may be between 0 and 5, and x may be between 1 and 20.

Claims (30)

1. A chelating compound having the formula:

((NH 4 ) 2 SO 4 ) a .(H 2 SO 4 ) b .(H 2 O) c .(NH 4 HSO 4 ) x ;

wherein a is between 1 and 5, b is between 1 and 5, c is between 0 and 5, and x is between 1 and 20.

2. The chelating compound of claim 1 , wherein the chelating compound is crystalline.

3. The chelating compound of claim 1 , wherein the chelating compound is hydroscopic.

4. The chelating compound of claim 1 , wherein the chelating compound is capable of chelating a metal salt.

5. The chelating compound of claim 4 , wherein the metal salt comprises a salt of zinc, magnesium, manganese, selenium, molybdenum, iron, boron, cobalt, copper, bismuth, or combinations thereof.

6. The chelating compound of claim 1 , wherein the chelating compound has a pH below about 2 when mixed with water.

7. The chelating compound of claim 1 , wherein the nitrogen atoms in the chelating compound have an oxidation state of −3.

8. The chelating compound of claim 1 , wherein the sulfur atoms in the chelating compound have an oxidation state of +6.

9. A chelating compound having the formula:

((NH 4 ) 2 SO 4 ) a .(H 2 SO 4 ) b .(H 2 O) c .(NH 4 HSO 4 ) x ;

wherein a is at least 1, b is at least 1, c is at least 0, and x is between 1 and 20; and

wherein the chelating compound comprises an elemental composition of:

between about 3% and 6% hydrogen;

between about 10% and about 15% nitrogen;

between about 25% and about 30% sulfur; and

between about 52% and about 60% oxygen.

10. The chelating compound of claim 9 , wherein the chelating compound is crystalline.

11. The chelating compound of claim 9 , wherein a is between 1 and 5, b is between 1 and 5, c is between 0 and 5, and x is between 1 and 20.

12. The chelating compound of claim 9 , wherein the chelating compound is hydroscopic.

13. The chelating compound of claim 9 , wherein the chelating compound is capable of chelating a metal salt.

14. The chelating compound of claim 13 , wherein the metal salt comprises a salt of zinc, magnesium, manganese, selenium, molybdenum, iron, boron, cobalt, copper, bismuth, or combinations thereof.

15. The chelating compound of claim 9 , wherein the chelating compound has a pH below about 2 when mixed with water.

16. The chelating compound of claim 9 , wherein the nitrogen atoms in the chelating compound have an oxidation state of −3.

17. The chelating compound of claim 9 , wherein the sulfur atoms in the chelating compound have an oxidation state of +6.

18. A chelating compound having the formula:

((NH 4 ) 2 SO 4 ) a .(H 2 SO 4 ) b .(H 2 O) c .(NH 4 HSO 4 ) x ;

wherein a is at least 1, b is at least 1, c is at least 0, and x is between 1 and 20; and

wherein the chelating compound has a pH below about 2 when mixed with water.

Assignments (4)
SECURITY INTEREST Recorded Sep 3, 2026
From: SEPRO CORPORATION
To: VARAGON CAPITAL PARTNERS AGENT, LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 075890/0044 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 4, 2026
From: EARTH SCIENCE LABORATORIES, INC.
To: SEPRO CORPORATION
Reel/Frame 074852/0166 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NAME OF THE ASSIGNEE TO EARTH SCIENCE LABORATORIES, INC. PREVIOUSLY RECORDED ON REEL 044419 FRAME 0319. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Aug 4, 2021
From: NICHOLAS, DAVID; BOWMAN, REID HENRY; SINGLETON, FREDDIE L.
To: EARTH SCIENCE LABORATORIES, INC.
Reel/Frame 057075/0436 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 18, 2017
From: NICHOLAS, DAVID; BOWMAN, REID HENRY; SINGLETON, FREDDIE L.
To: EARTH SCIENCE LABORATORIES
Reel/Frame 044419/0319 →
Continuity (3)
Continuation In Part 15184523 · Jun 16, 2016
Provisional Application 62182191 · Jun 19, 2015
Related Publication 20170225979A1 · Aug 10, 2017