IP Library Granted Patent US 10,151,990
Granted Patent B2
US 10,151,990 · App. 15/814,818 · Granted Dec 11, 2018

Toner

Inventors: Masao Suzuki (Kawasaki, JP); Kazuyuki Sato (Yokohama, JP); Shohei Fukuya (Tokyo, JP); Atsushi Nakamoto (Tokyo, JP); Makoto Fukatsu (Suntou-gun, JP); Takahiro Kawamoto (Yokohama, JP); Maki Okajima (Kawasaki, JP); Masayoshi Kato (Tokyo, JP); Yasunori Chigono (Kashiwa, JP); Takeshi Yamamoto (Yokohama, JP)
Assignee: CANON KABUSHIKI KAISHA
G03G9/08708C08F287/00C08L23/00C08L25/06G03G9/0819G03G9/0821G03G9/08797C08L2207/04
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Quick Facts
Patent No.
US 10,151,990
App. No.
15/814,818
Granted
Dec 11, 2018
Kind
B2
Abstract

A toner comprising a toner particle that contains a binder resin, wherein the surface of the toner particle is covered with a resin A; the modulus of elasticity Ea of the resin A and the modulus of elasticity Eb of the binder resin satisfy the following formula: 0.5≤( Ea/Eb )×100≤50.0; and the adhesion force A T of the toner particle is at least 500 nN when a probe having spherical SiO 2 attached at the tip of a cantilever is pressed into the toner particle at 3 μN.

Claims (39)

1. A toner comprising a toner particle including:

a toner base particle containing a binder resin, the binder resin being a vinyl resin, a polyester resin, or a hybrid resin provided by their bonding; and

a covering layer on the surface of the toner base particle, said covering layer containing a resin A, wherein

resin A is a polyolefinic thermoplastic elastomer having a hydrophilic group, and is present at the surface of the toner particle,

the modulus of elasticity Ea of the resin A and the modulus of elasticity Eb of the binder resin satisfy 0.5≤(Ea/Eb)×100[%]≤50.0, and

the adhesion force A T of the toner particle is at least 500 nN when a probe having spherical SiO 2 attached at the tip of a cantilever is pressed into the toner particle at 3 μN.

2. The toner according to claim 1 , wherein the ratio of coverage of the toner particle surface by the resin A is at least 70%.

3. The toner according to claim 1 , wherein the A T is at least 600 nN, and

the toner comprises fine particles on the surface of the toner particle, the fine particles satisfying specifications i) and ii):

i) the number-average particle diameter of the fine particles is at least 0.090 μm; and

ii) the ratio of coverage C (%) of the toner particle by the fine particles satisfies formula (1)

C

>

3

π

18

D

E

(

D

T

+

D

E

)

2

D

T

3

×

100

(

1

)

where D T represents the number-average particle diameter D1 (μm) of the toner particle and D E represents the number-average particle diameter D1 (μm) of the fine particles.

4. The toner according to claim 3 , wherein a value (percentage mass change/specific surface area) obtained by dividing the percentage mass change for the fine particles by the specific surface area of the fine particles is not more than 0.055%·g/m 2 , wherein the percentage mass change is obtained when the fine particles are held for 24 hours in an environment having a temperature of 23° C. and a relative humidity of 5% followed by holding for 1 hour in an environment having a temperature of 30° C. and a relative humidity of 80%.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 8, 2018
From: SUZUKI, MASAO; SATO, KAZUYUKI; FUKUYA, SHOHEI; NAKAMOTO, ATSUSHI; FUKATSU, MAKOTO; KAWAMOTO, TAKAHIRO; OKAJIMA, MAKI; KATO, MASAYOSHI; CHIGONO, YASUNORI; YAMAMOTO, TAKESHI
To: CANON KABUSHIKI KAISHA
Reel/Frame 045281/0406 →
Priority Claims (2)
JP 2016-228880 · Nov 25, 2016 · national
JP 2017-202917 · Oct 19, 2017 · national
Continuity (1)
Related Publication 20180149989A1 · May 31, 2018
Cited By (13)
US 12,306,579 US 12,405,543 US 12,461,463 US 12,529,972 US 12,529,973 US 12,547,091 US 12,613,478 US 12,638,789 US 12,663,734 US 12,663,736 US 12,675,060 US 12,687,796 US 12,687,797