IP Library › Granted Patent US 12,663,734
Granted Patent B2
US 12,663,734 · App. 17/808,807 · Granted Jun 23, 2026

Toner

Inventors: Tomohisa Sano (Shizuoka, JP); Kazuyuki Sato (Kanagawa, JP); Tohru Hiramatsu (Shizuoka, JP)
Assignee: CANON KABUSHIKI KAISHA
G03G9/09733G03G9/0819G03G9/08711G03G9/09725
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Quick Facts
Patent No.
US 12,663,734
App. No.
17/808,807
Filed
Jun 24, 2022
Granted
Jun 23, 2026
Kind
B2
Art Unit
1734
USPC
430/108.4
Abstract

A toner comprising a toner particle comprising a binder resin, a crystalline material, and a silica particle, wherein a number average particle diameter D1 of the silica particle comprised in the toner particle is 400 to 3000 nm; the silica particle has a pointed portion; and the crystalline material comprises a compound having an ester group.

Claims (17)

1 . A toner, comprising:

a toner particle comprising a binder resin, a crystalline material and a silica particle;

the silica particle being present within the toner particle, and a number average particle diameter D1 of the silica particle within the toner particle being 400 to 3000 nm, wherein

the silica particle has a pointed portion, and

the crystalline material comprises a compound having an ester group.

2 . The toner according to claim 1 , wherein the toner particle further comprises a colorant, and

the colorant comprises a magnetic body as a main component.

3 . The toner according to claim 2 , wherein D1 is 2 to 20 times a number average particle diameter of the magnetic bodies.

4 . The toner according to claim 1 , wherein the compound having the ester group has a melting point of 60 to 150° C.

5 . The toner according to claim 1 , wherein the binder resin is a styrene acrylic resin.

6 . The toner according to claim 1 , wherein the compound having the ester group is an ester wax.

7 . The toner according to claim 1 , wherein the amount of the silica particle comprised in the toner particle is 0.1 to 10.0 parts by mass with respect to 100 parts by mass of the binder resin.

8 . The toner according to claim 1 , wherein a value of a mass-based ratio of the amount of the compound having the ester group in the toner particle to the amount of the silica particle comprised in the toner particle is 1.0 to 20.0.

9 . The toner according to claim 1 , wherein in cross-sectional observation of the toner particle with a transmission electron microscope, a proportion of the number of cross sections of the toner particles comprising the silica particle having the pointed portion to the number of observed cross sections of the toner particles is 90% by number or more.

10 . The toner according to claim 1 , wherein the amount of the compound having the ester group is 3.0 to 20.0 parts by mass with respect to 100 parts by mass of the binder resin.

11 . The toner according to claim 1 , wherein the toner further comprises a silica particle as an external additive on a surface of the toner particle other than the silica particle comprised in the toner particle.

12 . The toner according to claim 1 , wherein a number of the silica particle having the pointed portion is 1.0 to 30.0 per cross section of the toner particle in cross-sectional observation with a transmission electron microscope.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 25, 2022
From: SANO, TOMOHISA; SATO, KAZUYUKI; HIRAMATSU, TOHRU
To: CANON KABUSHIKI KAISHA
Reel/Frame 060918/0925 →
Priority Claims (1)
JP 2021-110925 · Jul 2, 2021 · national
Continuity (1)
Related Publication 20230014130A1 · Jan 19, 2023
References Cited (110)
US 5449583A · Murofushi et al. · 1995 [cited by applicant]
US 5660959A · Moriyama et al. · 1997 [cited by examiner]
US 7123862B2 · Hasegawa · 2006 [cited by applicant]
US 7582401B2 · Ogawa · 2009 [cited by applicant]
US 7678523B2 · Hiroko · 2010 [cited by applicant]
US 7678524B2 · Hasegawa · 2010 [cited by applicant]
US 7811734B2 · Ogawa · 2010 [cited by applicant]
US 7923190B2 · Magome · 2011 [cited by applicant]
US 7935467B2 · Dojo · 2011 [cited by applicant]
US 8227162B2 · Sano · 2012 [cited by applicant]
US 8426091B2 · Magome · 2013 [cited by applicant]
US 8426094B2 · Magome · 2013 [cited by applicant]
US 8518620B2 · Dojo · 2013 [cited by applicant]
US 8614044B2 · Matsui · 2013 [cited by applicant]
US 8778585B2 · Matsui · 2014 [cited by applicant]
US 8841054B2 · Dojo · 2014 [cited by applicant]
US 8918035B2 · Hasegawa · 2014 [cited by applicant]
US 9029055B2 · Aoki · 2015 [cited by applicant]
US 9152065B2 · Sano · 2015 [cited by applicant]
US 9213250B2 · Nomura · 2015 [cited by applicant]
US 9235151B2 · Tanaka · 2016 [cited by applicant]
US 9239528B2 · Hasegawa · 2016 [cited by applicant]
US 9244371B2 · Suzumura · 2016 [cited by applicant]
US 9377708B2 · Magome · 2016 [cited by applicant]
US 9417542B2 · Hiroko · 2016 [cited by applicant]
US 9423711B2 · Uratani et al. · 2016 [cited by applicant]
US 9551947B2 · Hiroko · 2017 [cited by applicant]
US 9625841B2 · Hiroko · 2017 [cited by applicant]
US 9658549B2 · Tanaka · 2017 [cited by applicant]
US 9804514B2 · Suzumura · 2017 [cited by applicant]
US 9804519B2 · Suzumura · 2017 [cited by applicant]
US 9841692B2 · Hasegawa · 2017 [cited by applicant]
US 9880478B2 · Shimano · 2018 [cited by applicant]
US 9927728B2 · Arimura · 2018 [cited by applicant]
US 9946179B2 · Arimura · 2018 [cited by applicant]
US 9946181B2 · Hasegawa · 2018 [cited by applicant]
US 9964874B2 · Suzumura · 2018 [cited by applicant]
US 9964881B2 · Ikejiri · 2018 [cited by applicant]
US 9971262B2 · Hasegawa · 2018 [cited by applicant]
US 9971263B2 · Fukudome · 2018 [cited by applicant]
US 9971264B2 · Sano · 2018 [cited by applicant]
US 10012923B2 · Sano · 2018 [cited by applicant]
US 10151990B2 · Suzuki · 2018 [cited by applicant]
US 10228627B2 · Nagashima · 2019 [cited by applicant]
US 10295920B2 · Nishikawa · 2019 [cited by applicant]
US 10303075B2 · Tanaka · 2019 [cited by applicant]
US 10310397B2 · Sano · 2019 [cited by applicant]
US 10545420B2 · Kinumatsu · 2020 [cited by applicant]
US 10698327B2 · Nagashima · 2020 [cited by applicant]
US 10747136B2 · Kenmoku · 2020 [cited by applicant]
US 11079695B2 · Sato · 2021 [cited by applicant]
US 11099493B2 · Komiya · 2021 [cited by applicant]
US 11181839B2 · Yamashita · 2021 [cited by applicant]
US 11181840B2 · Nagata · 2021 [cited by applicant]
US 11181844B2 · Nagaoka · 2021 [cited by applicant]
US 11181846B2 · Kinumatsu · 2021 [cited by applicant]
US 11333989B2 · Unno · 2022 [cited by applicant]
US 20020055052A1 · Komoto et al. · 2002 [cited by applicant]
US 20050209364A1 · Yamagishi · 2005 [cited by applicant]
US 20060121379A1 · Dojo · 2006 [cited by applicant]
US 20080124643A1 · Yoshiba et al. · 2008 [cited by examiner]
US 20080187856A1 · Broce et al. · 2008 [cited by applicant]
US 20090197192A1 · Hiroko · 2009 [cited by applicant]
US 20110229812A1 · Takahashi et al. · 2011 [cited by examiner]
US 20120107741A1 · Hiraoka et al. · 2012 [cited by applicant]
US 20120301160A1 · Shu · 2012 [cited by applicant]
US 20140147785A1 · Matsushita et al. · 2014 [cited by examiner]
US 20160266507A1 · Watanabe et al. · 2016 [cited by applicant]
US 20160378003A1 · Arimura · 2016 [cited by applicant]
US 20180059561A1 · Nakashima et al. · 2018 [cited by examiner]
US 20180329321A1 · Nakamura et al. · 2018 [cited by applicant]
US 20200117107A1 · Tsujihiro · 2020 [cited by applicant]
US 20200209771A1 · Hashimoto et al. · 2020 [cited by applicant]
US 20200285161A1 · Takatsuna · 2020 [cited by applicant]
US 20210080846A1 · Mizuguchi · 2021 [cited by applicant]
US 20210356878A1 · Mizuguchi · 2021 [cited by applicant]
US 20220026822A1 · Sato · 2022 [cited by applicant]
US 20220026823A1 · Sano · 2022 [cited by applicant]
US 20220146952A1 · Komiya · 2022 [cited by applicant]
US 20220146955A1 · Nozaki · 2022 [cited by applicant]
US 20220171301A1 · Suzumura · 2022 [cited by applicant]
US 20220171302A1 · Sato · 2022 [cited by applicant]
US 20220171303A1 · Hiramatsu · 2022 [cited by applicant]
US 20220365457A1 · Unno · 2022 [cited by applicant]
US 20230015518A1 · Nozaki · 2023 [cited by applicant]
US 20230037779A1 · Suzumura · 2023 [cited by applicant]
CN 104106007A · 2014 [cited by applicant]
CN 106842842A · 2017 [cited by applicant]
CN 106959594A · 2017 [cited by applicant]
JP 2003262978A · 2003 [cited by applicant]
JP 2004309517A · 2004 [cited by applicant]
JP 200517660A · 2005 [cited by applicant]
JP 200786458A · 2007 [cited by applicant]
JP 2007140368A · 2007 [cited by applicant]
JP 2007292981A · 2007 [cited by applicant]
JP 200942386A · 2009 [cited by applicant]
JP 201026185A · 2010 [cited by applicant]
JP 201139382A · 2011 [cited by applicant]
JP 2014139618A · 2014 [cited by applicant]
JP 201754001A · 2017 [cited by applicant]
JP 201912158A · 2019 [cited by applicant]
JP 2020091327A · 2020 [cited by examiner]
JP 2020144273A · 2020 [cited by applicant]
KR 1020100098786A · 2010 [cited by applicant]
Machine translation of JP 2020-091327, Kobori (Year: 2025). [cited by examiner]
Machine translation, JP2020-091327A, Kobori (Year: 2025). [cited by examiner]
SYLYSIA Industrial Use, Synthetic Silica Specialist Company Fuji Silysia Chemical. [cited by applicant]
Spherical silica “SANSIL TM” Advanced Materials Business Division | Products | Tokuyama pp. 1-4. [cited by applicant]
Spherical-Silica Fine Particles QSG Series | Shinetsu pp. 1-2. [cited by applicant]
Quarch et al., Mechanical fragmentation of precipitated silica aggregates, Chem. Eng. Res. Des., vol. 88, Iss. 12 (2010) 1639-47. [cited by applicant]