IP Library › Granted Patent US 10,303,075
Granted Patent B2
US 10,303,075 · App. 15/903,241 · Granted May 28, 2019

Toner

Inventors: Keisuke Tanaka (Yokohama, JP); Yojiro Hotta (Mishima, JP); Kazuo Terauchi (Numazu, JP); Koji Nishikawa (Susono, JP); Takaaki Furui (Tokyo, JP); Ryo Nagata (Mishima, JP); Kazuyuki Sato (Yokohama, JP); Yu Yoshida (Mishima, JP); Yusuke Kosaki (Susono, JP); Masami Fujimoto (Suntou-gun, JP)
Assignee: CANON KABUSHIKI KAISHA
G03G9/09725G03G9/0819G03G9/0821G03G9/0825G03G9/0827G03G9/09708G03G9/09716
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 10,303,075
App. No.
15/903,241
Granted
May 28, 2019
Kind
B2
Abstract

A toner including a toner particle and an external additive, wherein the external additive contains an inorganic fine particle A and a silica fine particle; in a surface of the toner observed using a scanning electron microscope, a number-average particle diameter of primary particle of the silica fine particle is from 5 nm to 50 nm, a number-average particle diameter of primary particle of the inorganic fine particle A is at least 10 nm and less than 60 nm, a coverage ratio X1 of the toner surface covered by the silica fine particle is from 60 area % to 95 area %, the inorganic fine particle A is a fine particle of a titanate having a Group 2 element, and a coverage ratio X2 of the toner surface covered by the inorganic fine particle A is from 5 area % to 40 area %.

Claims (26)

1. A toner, comprising:

a toner particle; and

an external additive comprising an inorganic fine particle A and a silica fine particle, the inorganic fine particle A being a strontium titanate fine particle having a peak at in a range of 39.700°±0.150° and a peak at in a range of 46.200°±0.150° in a CuKα x-ray diffraction spectrum obtained in a range of 2θ of from 10° to 90°, where θ is a Bragg angle, wherein

in a surface of the toner observed using a scanning electron microscope (i) a number-average particle diameter of primary particle of the silica fine particle is 5 to 50 nm, and (ii) a number-average particle diameter of primary particle of the inorganic fine particle A is 10 to less than 60 nm,

a coverage ratio X1 of the toner surface covered by the silica fine particle is 60 to 95 area % as determined using an x-ray photoelectron spectrometer, and

a coverage ratio X2 of the toner surface covered by the inorganic fine particle A is 5 to 40 area % as determined using an x-ray photoelectron spectrometer.

2. The toner according to claim 1 , wherein a fixing ratio of the inorganic fine particle A to the toner particle is from 40 to 100%, the fixing ratio being calculated by (intensity of element Sr of post water-wash toner)/(intensity of element Sr of pre water-wash toner)×100.

3. The toner according to claim 1 , wherein a content of the inorganic fine particle A is 0.5 to 3.5 mass parts per 100 mass parts of the toner particle.

4. The toner according to claim 1 , wherein an average circularity of primary particle of the inorganic fine particle A is from 0.700 to 0.920.

5. The toner according to claim 1 , wherein a methanol concentration at a 50% transmittance of light having a wavelength of 780 nm is 60 to 95 volume % in a test of wettability of the inorganic fine particle A relative to a methanol/water mixed solvent.

6. The toner according to claim 1 , wherein a number-average particle diameter of primary particle of the inorganic fine particle A in a surface of the toner is 10 to 50 nm observed using a scanning electron microscope.

7. The toner according to claim 1 , wherein a Sr/Ti molar ratio for the strontium titanate fine particle is 0.70 to 0.95.

8. A toner, comprising:

a toner particle; and

an external additive comprising an inorganic fine particle A and a silica fine particle, the inorganic fine particle A being a fine particle of a titanate having a Group 2 element, wherein

in a surface of the toner observed using a scanning electron microscope (i) a number-average particle diameter of primary particle of the silica fine particle is 5 to 50 nm, and (ii) a number-average particle diameter of primary particle of the inorganic fine particle A is 10 to less than 60 nm,

a coverage ratio X1 of the toner surface covered by the silica fine particle is 60 to 95 area % as determined using an x-ray photoelectron spectrometer,

a coverage ratio X2 of the toner surface covered by the inorganic fine particle A is 5 to 40 area % as determined using an x-ray photoelectron spectrometer, and

a content of the inorganic fine particle A is 0.5 to 3.5 mass parts per 100 mass parts of the toner particle.

9. A toner, comprising:

a toner particle; and

an external additive comprising an inorganic fine particle A and a silica fine particle, the inorganic fine particle A being a fine particle of a titanate having a Group 2 element, wherein

in a surface of the toner observed using a scanning electron microscope (i) a number-average particle diameter of primary particle of the silica fine particle is 5 to 50 nm, and (ii) a number-average particle diameter of primary particle of the inorganic fine particle A is 10 to less than 60 nm,

a coverage ratio X1 of the toner surface covered by the silica fine particle is 60 to 95 area % as determined using an x-ray photoelectron spectrometer,

a coverage ratio X2 of the toner surface covered by the inorganic fine particle A is 5 to 40 area % as determined using an x-ray photoelectron spectrometer, and

an average circularity of primary particle of the inorganic fine particle A is from 0.700 to 0.920.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 9, 2018
From: TANAKA, KEISUKE; HOTTA, YOJIRO; TERAUCHI, KAZUO; NISHIKAWA, KOJI; FURUI, TAKAAKI; NAGATA, RYO; SATO, KAZUYUKI; YOSHIDA, YU; KOSAKI, YUSUKE; FUJIMOTO, MASAMI
To: CANON KABUSHIKI KAISHA
Reel/Frame 046105/0757 →
Priority Claims (2)
JP 2017-036331 · Feb 28, 2017 · national
JP 2018-006077 · Jan 18, 2018 · national
Continuity (1)
Related Publication 20180246430A1 · Aug 30, 2018
Cited By (16)
US 12,210,317 US 12,306,579 US 12,314,005 US 12,346,064 US 12,405,546 US 12,449,742 US 12,529,972 US 12,578,664 US 12,613,478 US 12,638,789 US 12,663,734 US 12,663,736 US 12,675,060 US 12,687,796 US 12,687,797 US 12,748,359