Tobacco-derived nanocellulose material
The present disclosure relates to cellulose nanomaterials made or derived from tobacco and methods for the production thereof. The tobacco-derived cellulose nanomaterials can be employed in various industrial applications such as film forming applications and solution thickening technologies. In particular, the disclosure is directed to methods for preparing tobacco-derived cellulose nanomaterials using less fibrillation cycles than in the production of wood pulp. The invention includes a method for preparing tobacco derived nanocellulose material comprising receiving a tobacco pulp in a dilute form such that the tobacco pulp is a tobacco pulp suspension with a consistency of less than about 5%; and mechanically fibrillating the tobacco pulp suspension to generate a tobacco derived nanocellulose material having at least one average particle size dimension in the range of about 1 nm to about 100 nm.
1. A method for preparing tobacco derived nanocellulose material comprising:
receiving a tobacco pulp in a dilute form such that the tobacco pulp is a tobacco pulp suspension with a consistency of less than about 5%; and
mechanically fibrillating the tobacco pulp suspension to generate a tobacco derived nanocellulose material having at least one average particle size dimension in the range of about 1 nm to about 100 nm.
2. The method of claim 1 , wherein the tobacco pulp is derived from tobacco root, tobacco stalk, tobacco fiber or a combination thereof.
3. The method of claim 1 , wherein the tobacco derived nanocellulose material comprises cellulose microfibrils, cellulose nanofibrils, or cellulose nanocrystals.
4. The method of claim 1 , wherein the tobacco derived nanocellulose material has an apparent viscosity of at least about 20,000 mPa*s at a consistency of 1.5%.
5. The method of claim 4 , wherein the tobacco derived nanocellulose material has an apparent viscosity of at least about 25,000 mPa*s at a consistency of 1.5%.
6. The method of claim 1 , wherein the mechanically fibrillating step comprises one or more of homogenization, microfluidization, grinding, and cryocrushing.
7. The method of claim 1 , wherein the mechanically fibrillating step comprises passing the tobacco pulp suspension through a homogenizer or microfluidizer at elevated pressure of at least 100 bar.
8. The method of claim 7 , wherein the elevated pressure is of at least 1000 bar.
9. The method of claim 7 , wherein the tobacco pulp suspension passes through the homogenizer or microfluidizer no more than 5 passes.
10. The method of claim 9 , wherein the tobacco pulp suspension passes through the homogenizer or microfluidizer no more than 3 passes.
11. The method of claim 10 , wherein the tobacco pulp suspension passes through the homogenizer or microfluidizer in only one pass.
12. The method of claim 1 , further comprising pre-treating the tobacco pulp, either before or after formation of the tobacco pulp suspension, by subjecting the tobacco pulp to one or more mechanical, chemical or enzymatic treatment steps.
13. The method of claim 12 , wherein the pre-treatment step is a mechanical grinding step.
14. The method of claim 12 , wherein the pre-treatment step comprises a chemical treatment step selected from TEMPO oxidation, peroxide oxidation, carboxymethylation, acetylation, acid hydrolysis, and combinations thereof.
15. The method of claim 12 , wherein the pre-treatment step comprises an enzymatic treatment selected from treatment with an endoglucanase, treatment with a hemicellulase, and combinations thereof.
16. A film formed of a tobacco-derived nanocellulose material having at least one average particle size dimension in the range of about 1 nm to about 100 nm, wherein the tobacco-derived nanocellulose material comprises cellulose nanofibrils having a surface modified by addition of hydrophobic, hydrophilic, or polar functional groups.
17. The film of claim 16 , wherein the tobacco-derived nanocellulose material is derived from tobacco root, tobacco stalk, tobacco fiber or a combination thereof.
18. The film of claim 16 , wherein the tensile strength of the film is greater than about 120 Mpa.
19. The film of claim 18 , wherein the tensile strength of the film is greater than about 130 Mpa.
20. The film of claim 19 , wherein the tensile strength of the film is or greater than about 140 Mpa.
21. The film of claim 16 , having one or more of:
a. a strain of at least about 11%; and
b. tensile modulus of at least about 4 Gpa.
22. The film of claim 16 , wherein the oxygen permeability of the film is at least one of:
a. less than 0.2 cc×mm/m 2 ×day at a temperature of 23° C. and at a relative humidity (RH) of 0%; and
b. less than about 20 cc×mm/m 2 ×day at a temperature of 23° C. and at a relative humidity (RH) of 80%.
23. The film of claim 16 , wherein the water vapor permeability of the film is less than about 30 g×mm/m 2 ×day at a temperature of 23° C. and at a relative humidity (RH) of 50%.
24. The film of claim 16 , wherein the tobacco-derived nanocellulose material is cellulose nanofibrils having a surface chemically modified by one or more of acetylation, silylation, oxidation, or carboxymethylation.