Polymerization method for preparing conductive polymer
An improved process for preparing a conductive polymer dispersion is provided as is an improved method for making capacitors using the conductive polymer. The process includes providing a monomer solution and shearing the monomer solution with a rotor-stator mixing system comprising a perforated stator screen having perforations thereby forming droplets of said monomer. The droplets of monomer are then polymerized during shearing to form the conductive polymer dispersion.
1. A method for preparing a dispersion of intrinsically conducting polymer comprising:
providing a solution comprising a monomer and a polyanion;
shearing said solution at a shear rate of at least 10,000 to no more than 800,000 sec −1 to form droplets;
mixing said droplets with at least one oxidizing agent;
polymerizing said monomer in said droplet to form said dispersion of said intrinsically conducting polymer.
2. The method for preparing a dispersion of intrinsically conducting polymer of claim 1 wherein said solution further comprises a steric stabilizer.
3. The method for preparing a dispersion of intrinsically conducting polymer of claim 1 wherein said shear rate is at least 40,000 to no more than 75,000 sec −1 .
4. The method for preparing a dispersion of intrinsically conducting polymer of claim 1 where said shearing is by a rotor stator.
5. The method for preparing a dispersion of intrinsically conducting polymer of claim 1 where rotor stator is selected from the group consisting of single stage batch mixer, single stage inline mixer, multiple stage and multi rowed rotor stator mixers.
6. The method for preparing a dispersion of intrinsically conducting polymer of claim 1 wherein said solution has a solids content of at least 1.0 wt % solid to no more than 5 wt % solid.
7. A capacitor made by the process of:
providing an anode with a dielectric thereon;
forming a dispersion of intrinsically conducting polymer by the method of claim 1 ;
applying said dispersion of intrinsically conducting polymer to said anode thereby forming a layer over said dielectric; and
drying said layer.
8. The capacitor of claim 7 wherein said process comprises providing said monomer with an anion.
9. The capacitor of claim 7 wherein said process comprises providing said monomer with a steric stabilizer.
10. A method of forming a capacitor comprising:
providing a solution comprising a monomer and a polyanion;
shearing said solution at a shear rate of 10,000 to 800,000 sec −1 to form droplets;
mixing said droplets with at least one oxidizing agent
polymerizing said droplets of said monomer to form a intrinsically conductive polymer;
providing an anode with a dielectric over said anode; and
forming a cathode of said intrinsically conductive polymer on said dielectric.
11. The method of forming a capacitor of claim 10 wherein said forming said cathode is after said forming said intrinsically conductive polymer.
12. The method of forming a capacitor of claim 10 wherein said solution further comprises a steric stabilizer.