Polishing composition, method for producing polishing composition and polishing composition preparation kit
Provided are a polishing composition comprising a water-soluble polymer that has a molecular structure comprising a plurality of repeat unit species having different SP values and a polishing composition exhibiting an etching rate and an abrasive adsorption in prescribed ranges when determined by prescribed methods. Also provided is a method for producing a polishing composition, using an abrasive, a basic compound, a water-soluble polymer having an alkaline-hydrolytic functional group, and water. The method comprises a step of obtaining an agent A comprising at least the basic compound and a step of obtaining an agent B comprising at least the water-soluble polymer H.
1. A method for producing a polishing composition, using an abrasive, a basic compound and a water-soluble polymer H having a functional group that is hydrolytic under basic conditions, and water; the method comprising:
a step of obtaining an agent A that comprises at least the basic compound;
a step of obtaining an agent B that comprises at least the water-soluble polymer H; and
a step of mixing a first composition comprising at least the agent A and a second composition comprising at least the agent B to prepare a mixture that comprises the abrasive, the basic compound, the water-soluble polymer H and water at a concentration of the basic compound of 0.1 mol/L or lower;
wherein
the abrasive consists of silica grains,
the agent A has a pH of 9 or higher, and the content of the basic compound in the agent A is 0.001% by mass or greater,
the water-soluble polymer H has a molecular structure comprising both of a vinyl alcohol unit and a vinyl acetate unit as the repeat units, and
in the step of obtaining the agent B, the agent B is prepared to have a pH of 4 or higher and 7.5 or low to inhibit the hydrolysis of the water-soluble polymer H.
2. The method according to claim 1 , wherein
the agent A is an abrasive dispersion C comprising the abrasive, the basic compound and water, and
the abrasive dispersion C is diluted to prepare the first composition; and then, the first composition is mixed with the second composition to prepare the mixture.
3. A polishing composition preparation kit used in the method according to claim 1 , comprising the agent A and the agent B that are stored separately.
4. A method for producing a polishing composition, using an abrasive, a basic compound, a water-soluble polymer H having a functional group that is hydrolytic under basic conditions, and water; the method comprising
a step of obtaining an agent A comprising at least the basic compound;
a step of obtaining an agent B comprising at least the water-soluble polymer H; and
a step of mixing a first composition comprising at least the agent A and a second composition comprising at least the agent B to prepare a mixture that comprises the abrasive, the basic compound, the water-soluble polymer H and water at a concentration of the abrasive of lower than 3% by mass;
wherein
the abrasive consists of silica grains,
the agent A has a pH of 9 or higher, and the content of the basic compound in the agent A is 0.001% by mass or greater,
the water-soluble polymer H has a molecular structure comprising both of a vinyl alcohol unit and a vinyl acetate unit as the repeat units, and
in the step of obtaining the agent B, the agent B is prepared to have a pH of 4 or higher and 7.5 or lower to inhibit the hydrolysis of the water-soluble polymer H.
5. The method according to claim 4 , wherein
the agent A is an abrasive dispersion C comprising the abrasive, the basic compound and water, and
the abrasive dispersion C is diluted to prepare the first composition; and then, the first composition is mixed with the second composition to prepare the mixture.
6. A polishing composition preparation kit used in the method according to claim 4 , comprising the agent A and the agent B that are stored separately.
7. A method for producing a polishing composition, using an abrasive, a basic compound and a water-soluble polymer H having a functional group that is hydrolytic under basic conditions, and water; the method comprising:
a step of obtaining an agent A that comprises at least the basic compound;
a step of obtaining an agent B that comprises at least the water-soluble polymer H;
a step of mixing at least the agent A and the agent B to prepare a polishing composition stock solution having a concentration of the basic compound of higher than 0.02 mol/L; and
a step of diluting the polishing composition stock solution to a concentration of the basic composition of 0.02 mol/L or lower within 24 hours after the agent A and the agent B are mixed;
wherein
the abrasive consists of silica grains,
the agent A has a pH of 9 or higher, and the content of the basic compound in the agent A is 0.001% by mass or greater,
the water-soluble polymer H has a molecular structure comprising both of a vinyl alcohol unit and a vinyl acetate unit as the repeat units, and
in the step of obtaining the agent B, the agent B is prepared to have a pH of 4 or higher and 7.5 or lower to inhibit the hydrolysis of the water-soluble polymer H.
8. The method according to claim 7 , wherein the stock solution is diluted by a factor of 10 or greater by volume in the step of diluting the polishing composition stock solution.
9. A polishing composition preparation kit used in the method according to claim 7 , comprising the agent A and the agent B that are stored separately.
10. A method for producing a polishing composition, using an abrasive, a basic compound, a water-soluble polymer H having a functional group that is hydrolytic under basic conditions, and water; the method comprising:
a step of obtaining an agent A that comprises at least the basic compound;
a step of obtaining an agent B that comprises at least the water-soluble polymer H;
a step of mixing at least the agent A and the agent B to prepare a polishing composition stock solution having an abrasive content of 1% by mass or greater; and
a step of diluting the polishing composition stock solution to an abrasive content of less than 1% by mass within 24 hours after the agent A and the agent B are mixed;
wherein
the abrasive consists of silica grains,
the agent A has a pH of 9 or higher, and the content of the basic compound in the agent A is 0.001% by mass or greater,
the water-soluble polymer H has a molecular structure comprising both of a vinyl alcohol unit and a vinyl acetate unit as the repeat units, and
in the step of obtaining the agent B, the agent B is prepared to have a pH of 4 or higher and 7.5 or lower to inhibit the hydrolysis of the water-soluble polymer H.
11. The method according to claim 10 , wherein the stock solution is diluted by a factor of 10 or greater by volume in the step of diluting the polishing composition stock solution.
12. A polishing composition preparation kit used in the method according to claim 10 , comprising the agent A and the agent B that are stored separately.