Process of recycling mixed PET plastic articles
The invention relates to a method for recycling at least one mixed PET plastic article, the method comprising degrading at least PET of the mixed PET plastic article to monomers and/or oligomers using an enzyme and recovering the resulting monomers and/or oligomers. The method of the invention may be used for depolymerizing, simultaneously or sequentially at least two different polymers of the mixed PET plastic article, and/or for recycling at least two mixed PET plastic articles.
1. A process of recycling at least one mixed polyethylene terephthalate (PET) plastic article containing a mix of crystallized and/or semi crystallized PET and at least one additional component different from PET, the method comprising the steps of
depolymerizing PET polymers of said mixed PET plastic article containing a mix of crystallized and/or semi crystallized PET and at least one additional component different from PET by contacting the mixed PET plastic article with a depolymerase, and
recovering products selected from monomers, oligomers and mixtures thereof:
wherein the additional component is selected from polyolefins, vinyl polymers, ortho-phthalaldehyde polymer (OPA), polychlorotrifluoroethylene (PCTFE), rubbery metal compounds, mineral compounds, glass compounds, natural or synthetic fibers, paper, wood, lignin, cellulose, hemi-cellulose, starch, and derivatives thereof.
2. The process of claim 1 , wherein the mixed PET plastic article is a packaging.
3. The process of claim 2 , wherein the packaging is selected from food packaging and beverage packaging.
4. The process of claim 1 , wherein the mixed PET plastic article is selected from fibers.
5. The process of claim 4 , wherein the fibers are selected from carpets, rugs, fabrics and textiles.
6. The process of claim 1 , wherein the depolymerase is selected from the group consisting of cutinases, lipases and esterases.
7. The process of claim 1 , wherein the depolymerase is a cutinase selected from a metagenomic library or from a microorganism synthesizing a cutinase.
8. The process of claim 7 , wherein the microorganism synthesizing a cutinase is selected from Thermobifida cellulosityca, Thermobifida halotolerans, Thermobifida fusca, Thermobifida alba, Bacillus subtilis, Fusarium solani pisi, Humicola insolens , and Thielavia terrestris.
9. The process of claim 1 , wherein the combination of PET and said additional component is selected from layers of each component, a mixture of PET and the additional component and a PET composite.
10. The process of claim 1 , wherein the additional component is selected from the group consisting of polytrimethylene terephthalate (PTT), polylactic acid (PLA), polyamide-6 (PA6), polyamide-6,6 (PA6,6), poly(m-xylylene adipamide) (MXD6), polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), ethylene vinyl alcohol (EVOH), ortho-phthalaldehyde polymer (OPA), polystyrene (PS), polychlorotrifluoroethylene (PCTFE), rubber, and derivatives thereof.
11. The process of claim 1 , wherein the fibers are selected from cotton fibers, viscose fibers and nylon fibers.
12. The process of claim 1 , wherein the plastic article contains a metal compound selected from aluminum, aluminum oxide, titanium, titanium oxide, nickel and chrome.
13. The process of claim 1 , wherein the plastic article contains a mineral compound selected from silica, silicon dioxide and mica.
14. The process of claim 1 , wherein the depolymerizing step comprises contacting the mixed PET plastic article with at least one microorganism expressing and excreting the depolymerase.
15. The process of claim 1 , said method comprising a pretreatment step of the mixed PET plastic article, prior to exposure to the depolymerase, wherein the pretreatment step leads to a modified mixed PET plastic article selected from a mechanically mixed PET plastic article, a physically mixed PET plastic article, a chemically mixed PET plastic article, a biologically mixed PET plastic article, and mixtures thereof.
16. The process of claim 1 , wherein the process comprises a step of recovering monoethylene glycol (MEG), terephthalic acid (PTA), methyl-2-hydroxyethyl terephthalate (MHET), bis(2-hydroxyethyl) terephthalate (BHET), 2-hydroxyethyl benzoate (HEB), dimethyl terephthalate (DMT), and mixtures thereof, and a step of reprocessing said recovered products further to produce polymers.
17. The process of claim 1 , wherein at least two different polymers of the mixed PET plastic article are degraded sequentially.
18. The process of claim 1 , wherein at least two different polymers of the mixed PET plastic article are degraded simultaneously.
19. The process of claim 1 , wherein at least two mixed PET plastic articles are recycled sequentially.
20. The process of claim 1 , wherein at least two mixed PET plastic articles are recycled simultaneously.
21. A method of producing products selected from monomers, oligomers and mixtures thereof from a mixed polyethylene terephthalate (PET) plastic article containing PET and at least one additional component, comprising exposing the mixed PET plastic article to a depolymerase able to depolymerize PET, and recovering products selected from monomers, oligomers and mixtures thereof, wherein the additional component is selected from polyolefins, vinyl polymers, ortho-phthalaldehyde polymer (OPA), polychlorotrifluoroethylene (PCTFE), rubber, metal compounds, mineral compounds, glass compounds, natural or synthetic fibers, paper, wood, lignin, cellulose, hemi-cellulose, starch, and derivatives thereof.
22. The process of claim 1 , wherein the content of PET in the mixed PET plastic article represents more than 50% by weight of the total weight of the PET mixed plastic article.